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ASTM D1199-86(2020) Standard Specification for Calcium Carbonate Pigments Active 发布日期 :  1970-01-01 实施日期 : 

This specification covers two types of high-content calcium carbonate pigments, Type PC and Type GC. Pigments shall be classified into six grades based on particle size, namely: Grade I (fine paint grade); Grade II (coarse paint grade); Grade III (filler grade); Grade IV (putty powder grade); Grade V (superfine grade); and Grade VI (ultrafine grade). Tests shall be conducted in accordance with the following test methods: calcium and magnesium reported as carbonate; moisture and other volatile matter; oil absorption; coarse particles; and dispersed color.1.1 This specification covers two types of high-content calcium carbonate pigments, as follows:1.1.1 Type PC—Calcium carbonate precipitate, prepared either by complete solution or by carbonation of lime.1.1.2 Type GC—Ground mineral product.1.2 Six grades of pigments, based on particle size (see 3.3) are covered.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is used to determine the presence and quantity of carbonate in a soil or soft rock specimen in terms of the calcite equivalent. The method is generally intended for use as an index of approximate carbonate content to assist with characterizing marine soils, but can be used for other soils and soft rock. Other test methods exist (such as Method C25 and Test Method D3042) to evaluate calcium carbonate equivalency for purposes of characterizing use of calcareous materials as soil modifiers or agricultural lining materials.5.1.1 Calcium carbonates (CaCO3) are known cementing agents, are water soluble at pH < 7, and are soft on the Mohs' scale compared to other soil minerals.5.2 This test method has limitations as follows:5.2.1 If low carbonate contents (calcite equivalents) are measured, the user does not know whether the soil is low in carbonate content or contains cerrusite, witherite, and the like, which are carbonate species whose reactions with hydrochloric acid are either very slow or limited.5.2.2 Testing times may be extensive (longer than 1 hour) for some carbonate species (such as dolomite) if calcite equivalents within about 1 % are required.5.2.3 The effects of specimen grain size, duration of testing, pH and specimen mass are discussed in the literature.3NOTE 1: The quality of the result produced by this standard is dependent on the competence of the personnel performing it, and the suitability of the equipment and facilities used. Agencies that meet the criteria of Practice D3740 are generally considered capable of competent and objective testing/sampling/inspection, etc. Users of this standard are cautioned that compliance with Practice D3740 does not in itself assure reliable results. Reliable results depend on many factors; Practice D3740 provides a means of evaluating some of those factors.1.1 This test method covers the determination of carbonate content of soils and soft rock which can be readily broken down by mechanical effort. It is a gasometric method that uses a simple portable apparatus. Results should be clearly stated as the calcite equivalent in percent because different carbonate species cover a wide range of percent calcite equivalent as shown below for a number of carbonates:Species Cation CalciteEquivalent, %Magnesite Mg 117.0Dolomite Ca, Mg 108.6Calcite Ca 100.0Aragonite Ca 100.0Rhodocrosite Mn 87.1Siderite Fe 86.4Smithsonite Zn 79.8Witherite Ba 50.7Cerrusite Pb 37.5For example, a 100 % dolomite would be expected to yield 108.6 % calcite equivalent while 100 % siderite would yield only 86.4 % calcite equivalent. Calcite and aragonite reactions will typically complete within about 10 minutes. This method does not distinguish between the carbonate species and such determination must be made using quantitative chemical analysis methods such as atomic absorption.1.2 Units—The values stated in SI units are to be regarded as standard. The values given in parentheses are provided for information only and are not considered standard. Reporting of test results in units other than SI shall not be regarded as nonconformance with this standard1.3 All observed and calculated values shall conform to the guidelines for significant digits and rounding established in Practice D6026.1.3.1 The procedures used to specify how data are collected/recorded or calculated, in this standard are regarded as the industry standard. In addition, they are representative of the significant digits that generally should be retained. The procedures used do not consider material variation, purpose for obtaining the data, special purpose studies, or any considerations for the user's objectives; and it is common practice to increase or reduce significant digits of reported data to be commensurate with these considerations. It is beyond the scope of this standard to consider significant digits used in analytical methods for engineering design.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 Soda ash is used in a number of manufacturing processes. The procedures listed in 1.2 are suitable for specification acceptance and manufacturing control of commercial soda ash.1.1 These test methods cover the analyses usually required on commercial soda ash (sodium carbonate).1.2 The analytical procedures appear in the following sections:  Sections Total Alkalinity, Titrimetric  8 – 15Sodium Bicarbonate, Titrimetric 17 – 24Loss on Heating, Gravimetric 26 – 32Moisture, Calculation 34 – 38Sodium Chloride, Titrimetric 40 – 46Sodium Sulfate, Gravimetric 48 – 54Iron, Photometric 56 – 64Sieve Analysis 66 – 721.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.1.5 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first aid procedures, handling and safety precautions.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 6.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Two types of alkali reactivity of aggregates have been described in the literature: the alkali-silica reaction involving certain siliceous rocks, minerals, and artificial glasses (1),3 and the alkali-carbonate reaction involving dolomite in certain calcitic dolomites and dolomitic limestones (2). This test method is not recommended as a means to detect combinations susceptible to expansion due to alkali-silica reaction since it was not evaluated for this use in the work reported by Buck (2). This test method is not applicable to aggregates that do not contain or consist of carbonate rock (see Descriptive Nomenclature C294).4.2 This test method is intended for evaluating the behavior of specific combinations of concrete-making materials to be used in the work. However, provisions are made for the use of substitute materials when required. This test method assesses the potential for expansion of concrete caused by alkali-carbonate rock reaction from tests performed under prescribed laboratory curing conditions that will probably differ from field conditions. Thus, actual field performance will not be duplicated due to differences in wetting and drying, temperature, other factors, or combinations of these (see Appendix X1).4.3 Use of this test method is of particular value when samples of aggregate from a source have been determined to contain constituents that are regarded as capable of participation in a potentially deleterious alkali-carbonate rock reaction either by petrographic examination, Guide C295/C295M, by the rock cylinder test, Test Method C586, by service record; or by a combination of these.4.4 Results of tests conducted as described herein should form a part of the basis for a decision as to whether precautions be taken against excessive expansion due to alkali-carbonate rock reaction. This decision should be made before a particular cement-aggregate combination is used in concrete construction (see Note 1).NOTE 1: Other elements that may be included in the decision-making process for categorizing an aggregate or a cement-aggregate combination with respect to whether precautions are needed, and examples of precautions that may be taken, are described in Appendix X1.4.5 While the basic intent of this test method is to develop information on a particular cement-aggregate combination, it will usually be very useful to conduct control tests in parallel using the aggregate of interest with other cements or the cement of interest with other aggregates.1.1 This test method covers the determination, by measurement of length change of concrete prisms, the susceptibility of cement-aggregate combinations to expansive alkali-carbonate reaction involving hydroxide ions associated with alkalies (sodium and potassium) and certain calcitic dolomites and dolomitic limestones.1.2 The text of this standard refers to notes and footnotes that provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.1.3 Units—The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this standard. When combined standards are cited, the selection of measurement system is at the user's discretion subject to the requirements of the referenced standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is intended to give a relatively rapid indication of the potential expansive reactivity of certain carbonate rocks that may be used as concrete aggregates. The test method has been successfully used in (1) research and (2) preliminary screening of aggregate sources to indicate the presence of material with a potential for deleterious expansion when used in concrete.5.2 The test method is intended as a research and screening method rather than as the basis of a specification requirement. It is intended to supplement data from field service records, petrographic examinations according to Guide C295/C295M, and tests of aggregate in concrete according to Test Method C1105.5.3 Alkalies participating in the expansive reactions with aggregate constituents in concrete usually are derived from the hydraulic cement; under certain circumstances they may be derived from other constituents of concrete or from external sources. Two types of alkali reactivity of aggregates are recognized: (1) alkali-silica reaction involving certain siliceous rocks, minerals, and artificial glasses, and (2) alkali carbonate reaction involving dolomite in certain calcitic dolomites, dolomitic limestones, and dolostones. This test method is not suitable as a means to detect alkali-silica reaction.1.1 This test method covers the determination of the expansion of a specimen of carbonate rock while immersed in a solution of sodium hydroxide (NaOH) at room temperature. The length changes occurring during such immersion indicate the general level of reactivity of the rock and whether tests should be made to determine the effect of aggregate prepared from the rock upon the volume change in concrete.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 The text of this standard refers to notes and footnotes that provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Small amounts of mineral carbonates occur in many coals and comparatively large amounts in some coals. The determination of these carbonates is the purpose of this test method. The value found for carbon dioxide is used to estimate the mineral matter content, particularly CaCO3 and MgCO3, of high-carbonate coals.FIG. 1 Apparatus for the Determination of Carbon Dioxide1.1 This test method covers the determination of carbon dioxide in coal in any form, such as mineral carbonate, from which carbon dioxide is released by action of mineral acids. It applies to high-carbonate and low-carbonate coals.1.2 The values stated in SI units are to be regarded as the standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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This specification covers basic carbonate white lead used as a pigment and in putty. The pigments may be in dry form or a paste in oil. Dry pigment shall conform to the required contents of lead carbonate, moisture and other volatile matter, impurities, and coarse particles. Paste in oil and semipaste containing volatile thinner shall also conform to the requirements of pigment, linseed oil, moisture and other volatile matter, and coarse particles and skins of dry pigment. Tests for the following shall be done: coarse particles; moisture in pigment; lead carbonate and total other impurities; and pigment, linseed oil, and moisture and other volatile matter in paste in oil.1.1 This specification covers the material commercially known as basic carbonate white lead, used as a pigment and in putty. The pigment may be purchased in the dry form or as a paste in oil.1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The combustible carbon content of solid residues is used to calculate efficiency of fuel combustion in boiler furnaces and similar combustors.5.2 Combustible carbon values are also used to determine the residual fuel value of incompletely combusted/reacted coal and coke in other reactors that consume carbonaceous fuels (examples include fluidized bed furnaces and liquefaction, gasification and pyrolysis reactors).5.3 The combustible carbon content of flyash is an important parameter in the use of flyash as a cement additive.1.1 This test method covers the determination of total, combustible, and carbonate carbon remaining in the solid byproducts of combustion from boiler furnaces and similar reactors, including ash, flyash, char, slag, and similar materials.1.2 This test method is intended for the use of industry to determine the performance of boiler furnaces and similar combustion reactors and aid in determining the quality of the solid residue from combustion.1.3 This test method comprises the use of any of several methods to determine total carbon content combined with any of several methods to determine carbonate carbon, and the calculation, by difference, of the combustible carbon remaining in a sample.1.4 Alternatively, this test method applies to the determination of total carbon remaining in a material after acidification with strong acid to evolve carbonate carbon. In this case, the combustible carbon is the total carbon measured in the sample after acidification.1.5 The values stated in SI units are to be regarded as standard. Non-SI units, if provided, are for information only and are contained within parentheses.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and to determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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A1.3 A1.3.1 This test method provides analytical procedures to determine the major chemical constituents of limestone (see Note 1). The percentages of specific constituents that determine a material’s quality or fitness for use are of significance depending upon the purpose or end use of the material. Results obtained may be used in relation to specification requirements.NOTE A1.1: This test method can be applied to other calcareous materials if provisions are made to compensate for known interferences.AbstractThis specification covers ground calcium carbonate (GCC, a type of ground limestone) and other finely divided aggregate mineral filler (AMF) materials for use in concrete mixtures. It defines the types of GCC and AMF materials for use in concrete. If concrete in service is subject to sulfate exposure, fillers derived from ground limestone should not be used unless mitigation methods are used.1.1 This specification applies to ground calcium carbonate (GCC is a type of ground limestone) and other finely divided aggregate mineral filler (AMF) materials for use in concrete mixtures. The specification defines the types of GCC and AMF materials for use in concrete.1.2 If concrete in service is subject to sulfate exposure, fillers derived from ground limestone should not be used unless mitigation methods are used.NOTE 1: American Concrete Institute (ACI) technical documents 201.2R, 318, 332, and 350 contain useful information and code requirements dealing with sulfate exposure in service. Soluble sulfate in water can be determined in accordance with Test Method D516 or Test Method D4130. Percent sulfate by mass in soil can be determined by Test Method C1580.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.NOTE 2: Sieve size is identified by its standard designation in Specification E11. The alternative designation given in parentheses is for information only and does not represent a different standard sieve size.1.4 The text of this standard references notes and footnotes, which provide explanatory information. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 The amount and size distribution of noncarbonate (insoluble) material in carbonate aggregates is of interest to those conducting research on the polish susceptibility of stone used in pavements or on the friction properties of pavement surfaces. In addition, some agencies utilize the test for acceptance purposes to delineate carbonate aggregates that polish excessively and become slippery and those that will not.NOTE 1: The quality of the results produced by this standard are dependent upon the competence of the personnel performing the procedure and the capability, calibration, and the maintenance of the equipment used. Agencies that meet the criteria of Specification D3666 are generally considered capable of competent and objective testing/sampling/inspection, etc. Users of this standard are cautioned that compliance with Specification D3666 alone does not completely ensure reliable results. Reliable results depend on many factors: following the suggestions of Specification D3666 or similar acceptable guideline provides a means of evaluating and controlling some of those factors.1.1 This test method covers determination of the percentage of insoluble residue in carbonate aggregates using hydrochloric acid solution to react the carbonates.1.2 The values stated in SI units are to be regarded as standard. Regarding sieves, per Specification E11, “The values stated in SI units shall be considered standard for the dimensions of the wire cloth openings and the diameter of the wires used in the wire cloth. The values stated in inch-pound units shall be considered standard with regard to the sieve frames.” When sieve mesh sizes are referenced, the alternate inch-pound designations are provided for information purposes and enclosed in parentheses.1.3 The text of this standard references notes and footnotes which provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precaution statements are given in Section 7.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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