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4.1 This guide covers procedures for crevice-corrosion testing of iron-base and nickel-base stainless alloys in seawater. The guidance provided may also be applicable to crevice corrosion testing in other chloride containing natural waters and various laboratory prepared aqueous chloride environments.4.1.1 While this guide focuses on testing of iron-base and nickel-base stainless alloys, the procedures and evaluations methods described herein have been successfully applied to characterize the crevice corrosion performance of other alloy systems (see, for example, Aylor et al.3).NOTE 1: In the case of copper alloys, the occurrence of crevice-related corrosion associated with different corrosion mechanisms takes place immediately adjacent to the crevice former rather than within the occlusion.4.2 This guide describes the use of a variety of crevice formers including the nonmetallic, segmented washer design referred to as the multiple crevice assembly (MCA) as described in 9.2.2.4.3 In-service performance data provide the most reliable determination of whether a material would be satisfactory for a particular end use. Translation of laboratory data from a single test program to predict service performance under a variety of conditions should be avoided. Terms, such as immunity, superior resistance, etc., provide only a general and relatively qualitative description of an alloy's corrosion performance. The limitations of such terms in describing resistance to crevice corrosion should be recognized.4.4 While the guidance provided is generally for the purpose of evaluating sheet and plate materials, it is also applicable for crevice-corrosion testing of other product forms, such as tubing and bars.4.5 The presence or absence of crevice corrosion under one set of conditions is no guarantee that it will or will not occur under other conditions. Because of the many interrelated metallurgical, environmental, and geometric factors known to affect crevice corrosion, results from any given test may or may not be indicative of actual performance in service applications where the conditions may be different from those of the test.1.1 This guide covers information for conducting crevice-corrosion tests and identifies factors that may affect results and influence conclusions.1.2 These procedures can be used to identify conditions most likely to result in crevice corrosion and provide a basis for assessing the relative resistance of various alloys to crevice corrosion under certain specified conditions.1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific warning statement, see 7.1.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 This test method is designed solely for determining comparative laboratory indices of performance. The results may be used for ranking alloys in order of increasing resistance to pitting and crevice corrosion under the specific conditions of this method. It should be noted that the method is intentionally designed to reach conditions that are sufficiently severe to cause breakdown of at least one alloy (Type 316 L stainless steel) currently considered acceptable for surgical implant use, and that those alloys which suffer pitting or crevice corrosion during the more severe portions of the test do not necessarily suffer localized corrosion when placed within the human body as a surgical implant.1.1 This test method covers the determination of resistance to either pitting or crevice corrosion of metals and alloys from which surgical implants will be produced. It is a modified version of an established test2 and is used as a screening test to rank surgical implant alloys in order of their resistance to localized corrosion.1.2 This test method applies only to passive metals and alloys. Nonpassive alloys (other than noble alloys) are susceptible to general corrosion and are not normally suitable for implant use.1.3 This test method is intended for use as a laboratory screening test for metals and alloys which undergo pitting or crevice corrosion, or both.1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The THE test method is designed to provide highly reproducible crevice repassivation potentials for corrosion–resistant alloys (for example, Alloy 22) in a wide range of environments from non-aggressive to highly aggressive. In conditions of low environmental aggressiveness (such as low temperature or low chloride concentration), corrosion–resistant alloys such as Alloy 22 will resist crevice corrosion initiation and the cyclic potentiodynamic polarization test (Test Method G61) may fail to promote crevice corrosion mainly because it drives the alloy into transpassive dissolution instead of nucleating crevice corrosion. The THE test method provides a more controlled way of applying the electrical charge to the test electrode, which may induce crevice corrosion without moving it into transpassive potentials.5.2 The more noble this crevice corrosion repassivation potential (ER,CREV) value, the more resistant the alloy is to crevice corrosion in the tested electrolyte. This is similar to other test methods to measure localized corrosion resistance such as Test Method G61 and Test Methods G48. The results from this test method are not intended to correlate in a quantitative manner with the rate of propagation that one might observe in service when localized corrosion occurs.5.3 This test method may be used to rank several alloys by using the same testing electrolyte and temperature. It can also be used to determine the response of a given alloy when the environmental conditions (such as electrolyte composition and temperature) change.1.1 This test method covers a procedure for conducting anodic polarization studies to determine the crevice repassivation potential for corrosion–resistant alloys. The concept of the repassivation potential is similar to that of the protection potential given in Reference Test Method G5.1.2 The test method consists in applying successively potentiodynamic, galvanostatic, and potentiostatic treatments for the initial formation and afterward repassivation of crevice corrosion.1.3 This test method is a complement to Test Method G61.1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 These test methods describe laboratory tests for comparing the resistance of stainless steels and related alloys to the initiation of pitting and crevice corrosion. The results may be used for ranking alloys in order of increasing resistance to pitting and crevice corrosion initiation under the specific conditions of these methods. Methods A and B are designed to cause the breakdown of Type 304 at room temperature.4.2 The use of ferric chloride solutions is justified because it is related to, but not the same as, that within a pit or crevice site on a ferrous alloy in chloride bearing environments (1, 2).3 The presence of an inert crevice former of consistent dimension on a surface is regarded as sufficient specification of crevice geometry to assess relative crevice corrosion susceptibility.4.3 The relative performance of alloys in ferric chloride solution tests has been correlated to performance in certain real environments, such as natural seawater at ambient temperature (3) and strongly oxidizing, low pH, chloride containing environments (4), but several exceptions have been reported (4-7).4.4 Methods A, B, C, D, E, and F can be used to rank the relative resistance of stainless steels and nickel base alloys to pitting and crevice corrosion in chloride-containing environments. No statement can be made about resistance of alloys in environments that do not contain chlorides.4.4.1 Methods A, B, C, D, E, and F were designed to accelerate the time to initiate localized corrosion relative to most natural environments. Consequently, the degree of corrosion damage that occurs during testing will generally be greater than that in natural environments in any similar time period.4.4.2 No statement regarding localized corrosion propagation can be made based on the results of Methods A, B, C, D, E, or F.4.4.3 Surface preparation can significantly influence results. Therefore, grinding and pickling of the specimen will mean that the results may not be representative of the conditions of the actual piece from which the sample was taken.NOTE 1: Grinding or pickling on stainless steel surfaces may destroy the passive layer. A 24 h air passivation after grinding or pickling is sufficient to minimize these differences (8).4.4.4 The procedures in Methods C, D, E, and F for measuring critical pitting corrosion temperature and critical crevice corrosion temperature have no bias because the values are defined only in terms of these test methods.NOTE 2: When testing as-welded, cylindrical, or other non-flat samples, the standard crevice formers will not provide uniform contact. The use of contoured crevice formers may be considered in such situations, but the use of a pitting test (Practices A, C, or E) should be considered.1.1 These test methods cover procedures for the determination of the resistance of stainless steels and related alloys to pitting and crevice corrosion (see Terminology G193) when exposed to oxidizing chloride environments. Six procedures are described and identified as Methods A, B, C, D, E, and F.1.1.1 Method A—Ferric chloride pitting test.1.1.2 Method B—Ferric chloride crevice test.1.1.3 Method C—Critical pitting temperature test for nickel-base and chromium-bearing alloys.1.1.4 Method D—Critical crevice temperature test for nickel-base and chromium-bearing alloys.1.1.5 Method E—Critical pitting temperature test for stainless steels.1.1.6 Method F—Critical crevice temperature test for stainless steels.1.2 Method A is designed to determine the relative pitting resistance of stainless steels and nickel-base, chromium-bearing alloys, whereas Method B can be used for determining both the pitting and crevice corrosion resistance of these alloys. Methods C, D, E, and F allow for a ranking of alloys by minimum (critical) temperature to cause initiation of pitting corrosion and crevice corrosion, respectively, of stainless steels, nickel-base and chromium-bearing alloys in a standard ferric chloride solution.1.3 These tests may be used to determine the effects of alloying additives, heat treatment, and surface finishes on pitting and crevice corrosion resistance.1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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