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AS 1683.1-2002 Methods of test for elastomers Rubber latex - Sampling 被代替 发布日期 :  2002-10-15 实施日期 : 

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AS 1683.2-1974 Methods of test for rubber Solids content of latex 现行 发布日期 :  1974-10-01 实施日期 : 

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1.1 This specification covers the types, grades, and physical properties of aerosol polyurethane and aerosol latex foams extruded from pressurized containers and intended for building envelope air barrier sealant applications in building construction.1.2 For specific aerosol foam sealant applications, operational temperature limit criteria shall be as agreed upon between the aerosol sealant manufacturer and the purchaser.1.3 The values in SI units are to be regarded as standard. The values shown in parentheses are for information and approximation only.1.4 The committee with jurisdiction over this standard is not aware of any comparable standards published by other organizations.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Interior flat paints may become burnished in areas where clothing or upholstered furniture rub against a wall. This rubbing may cause a smoother, glossier surface at the contacted area, depending on the level or type of pigments in the paint and binder hardness. This method permits a more quantitative estimate of burnish resistance than those using manual rubbing techniques.1.1 This test method covers a procedure for measuring the resistance of latex paints to burnishing under dry conditions.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1  Dialkyldithiocarbamates (DTCs), benzothiazoles, and thiurams are often used as vulcanization accelerators in NRL products. Zinc DTC accelerators are added either directly or are formed in situ during the vulcanization process via reaction between a thiuram(s) and zinc oxide. DTCs, benzothiazoles, and thiurams have been detected in leachates from medical devices made of rubber such as gloves. Studies have shown these chemicals can cause allergic contact dermatitis. A simple selective method to monitor rubber accelerator levels in rubber extracts would be useful for quality control, product screening and research.5.2 This colorimetric assay measures dialkyldithiocarbamates, including zinc dialkyldithiocarbamates (ZDTC), mercaptobenzothiazole (MBT) and thiurams as a total thiol vulcanization accelerator level in rubber products. A UV spectrophotometer with detection at 320 nm is used to measure the ZDTC, mercaptobenzothiazole and thiurams. Sample extracts diluted at 1:20 prior to measurement on the spectrophotometer is usually sufficient to quantify the residual accelerator level from most commercially available rubber gloves; however, sample dilution can be adjusted (from neat extract to > 1:20 dilution) based on analytical needs. Thiurams and ZDTCs complex with cobalt turning the extract to a concentration-dependent shade of green. ZDTCs reacts quickly while thiurams react very slowly (requiring a heat catalyst). Mercaptobenzothiazole does not complex to Co(III), however, it absorbs strongly at 320 nm. It can be distinguished from both ZDTCs and thiurams by its strong absorbance at 320 nm without the cobalt dependent visible green color. Cobalt complexed thiurams and ZDTCs, but not MBT, also have and absorbance at 370 nm (2).1.1 This test method is designed to quantify the amount of total extractable accelerators in natural rubber latex (NRL) and nitrile gloves. Three common classes of rubber accelerators, the mercaptobenzothiazole (MBT), thiuram, and thiocarbamate type compounds can be detected and quantified by this method. If the specific rubber accelerator(s) present in the glove material is not known, quantification is based on zinc dibutyldithiocarbamate (ZDBC) equivalents. This method will not detect all potential rubber accelerators, including mercaptobenzothiazole disulfide, dimorpholine, thioureas and diphenyl diamine.1.2 For the purpose of this test method, the range of chemical accelerator measurement is based on the limit of detection (LOD) established in the performing laboratory.1.3 This test method should be performed by experienced analysts or under the supervision of those experienced in the use of spectroscopy and working with organic solvents.1.4 This test method has not been validated for measurement of long chain dithiocarbamates or accelerators from other rubber products, such as lubricated condoms (1).2 Although this assay has been reported in the literature for the evaluation of accelerator levels in condoms, further validation for accelerator measurement from other rubber products is required by the testing laboratory prior to use.1.5 This test method is not designed to evaluate the potential of rubber materials to induce or elicit Type IV skin sensitization reactions (for Type IV skin sensitization reactions see Test Method D6355). Total extractable accelerator content does not reflect bioavailablity of individual accelerators that are detected and measured by this method. This test method should be used to test and measure the total residual chemical accelerator level in NRL and nitrile gloves under controlled laboratory conditions, and should not be used to describe, appraise, or assess the hazard or risk of these materials or products under actual in-use conditions.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method, for the determination of protein levels in latex, is primarily intended to test NR, latex, and elastomeric materials for residual protein content. It is assumed that all who use this test method will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.1.1 This test method covers an analytical test for determining the amount of total aqueous extractable protein associated with NR, latex, and elastomeric products. Water soluble proteins are extracted in a buffer solution and then precipitated to concentrate them and also to separate them from water soluble substances that may interfere with the determination. The extracted protein is redissolved and quantified colorimetrically by the modified Lowry method using a protein standard.1.2 For the purpose of this test method, the range of protein measurement will be based on the limit of detection and quantitation and recorded in micrograms per dm2 test specimen.1.3 The test method is designed to be accurate and compatible with the industrial environment.1.4 Steps are included in this test method to minimize the effects of interfering substances.1.5 It is recognized that other methods for the analysis of leachable proteins exist and these may be used for routine quality control purposes provided they have been validated and a correlation established against the reference method specified by this test method.1.6 This test method has not been validated for use with lubricated products such as condoms. Condoms with different lubricants as typically marketed, have not been tested in an ASTM ILS to determine if, and if so to what degree, the lubricant interferes with the assay.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This practice can be used by paint formulators to determine if a given paint has the ability to form a film at low temperatures. This practice can be used as an aid for determining coalescing solvent level required to form a good film. Test Method D3793 compares the porosity of a film drawn down at room temperature to another film drawn down and cured at low temperature.5.2 This practice provides no absolute information, rather ranking only of the selected series of paints.5.3 This practice can provide a pass-fail situation if known acceptable and unacceptable paints are included in the test.1.1 This practice specifies a laboratory procedure for evaluating the ability of a latex paint to form a uniform film free of visible defects at low temperatures.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 As the brush drag of a paint increases, any natural tendency on the part of the painter to overspread the paint is reduced. When all other factors are held constant, increased brush drag will result in greater film thickness with consequent improvement in durability and hiding. Conversely, sometimes it might be preferred to have a lesser degree of brush drag for easier application (that is, the amount of time and effort in applying a paint to a specific area is reduced with a lesser degree of brush drag).5.2 This test method provides a standardized brushout procedure for the evaluation of brush drag as an alternative to customary informal ad hoc procedures. Its objective is to maximize the reliability and precision with which this characteristic may be determined.NOTE 1: The brush drag of paints is directly related to their high-shear viscosity. There is generally good rank order agreement between results obtained by this method and Test Method D4287. The sensitivity of this brushout method has been found sufficient to distinguish between brushability corresponding to high-shear viscosity differences not lower than 0.3 poise (0.03 Pa.s). Round robin data show that rank order agreement between the brushout and viscometric methods is poor when both latex and solvent-borne paints are part of the same comparison group. This is the result of these two paint types having markedly different rheological properties that affect the relative perception of brush drag.31.1 This test method is a standardized brushout procedure for comparing the brush drag of architectural type solvent-borne paints.1.2 With slight modifications this test method is also applicable to solvent-borne paints.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D4143-16(2022) Standard Guide for Testing Latex Vehicles Active 发布日期 :  1970-01-01 实施日期 : 

This guide details the standard methods suitable for testing latex vehicles. Included here are methods for latex sampling, nonvolatile content, minimum film formation temperature, qualitative polymeric analysis, density, viscosity, consistency, water content, pH, and surface tension.1.1 This guide covers methods suitable for testing latex vehicles. Certain of these methods were developed expressly for testing latex vehicles (Table 1). Others were developed for testing or analyzing formulated water- or solvent-based coatings but would be equally applicable for testing latices.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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