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5.1 This field test method determines the mass concentration of VOHAPs (or any subset) listed in Section 1.5.2 Multiplying the mass concentration by the effluent volumetric flow rate (see 2.2) yields mass emission rates.5.3 This field test method employs laboratory GCMS techniques and QA/quality control (QC) procedures in common application.5.4 This field test method provides data with accuracy and precision similar to most laboratory GCMS instrumentation.1.1 This test method employs a direct interface gas chromatograph/mass spectrometer (GCMS) to identify and quantify the 36 volatile organic compounds (or sub-set of these compounds) listed as follows. The individual Chemical Abstract Service (CAS) numbers are listed after each compound.Benzene-71432 Methylene chloride-75092Bromodichloromethane-75274 1,1,2,2-Tetrachloroethane-79349Carbon disulfide-75150 1,1,1-Trichloroethane-71556Chloroform-67663 1,1,2-Trichloroethane-79005Methyl iso-Butyl ketone-108101 p-Xylene-106423Styrene-100425 Bromomethane-74839Tetrachloroethylene-127184 Carbon tetrachloride-56235Toluene-108883 Chlorobenzene-108907Bromoform-75252 c-1,3-Dichloropropene-10061015Vinyl acetate-108054 1,2-Dichloroethane-156592Vinyl chloride-75014 1,1-Dichloroethene-75354Chloromethane-74873 t-1,2-Dichloroethene-156605cis-1,2-Dichloroethene-156592 Methyl ethyl ketone-78933Dibromochloromethane-124481 2-Hexanone-5917861,1-Dichloroethane-107062 t-1,3-Dichloropropene-5427561,2-Dichloropropane-78875 Trichloroethene-79016Ethylbenzene-100414 m-Xylene-108383Ethyl chloride-75003 o-Xylene-954761.2 The test method incorporates a performance-based approach, which validates each GCMS analysis by placing boundaries on the instrument response to gaseous internal standards and their specific mass spectral relative abundance. Using this approach, the test method may be extended to analyze other compounds.1.3 The test method provides on-site analysis of extracted, unconditioned, and unsaturated (at the instrument) gas samples from stationary sources. Gas streams with high moisture content may require conditioning to prevent moisture condensation within the instrument. For these samples, quality assurance (QA) requirements are provided in the test method to validate the analysis of polar, water-soluble compounds.1.4 The instrument range should be sufficient to measure the listed volatile organic compounds from 150 ppb(v) to 100 ppm(v), using a full scan operation (between 45 and 300 atomic mass units). The range may be extended to higher or lower concentrations using either of the following procedures:1.4.1 The initial three-point calibration concentrations and the continuing calibration checks are adjusted to match the stack concentrations, or1.4.2 The three-point calibration is extended to include additional concentrations to cover the measurement range.1.5 The minimum quantification level is 50 % of the lowest calibration concentration. Responses below this level are considered to be estimated concentrations, unless a calibration standard check is conducted at a lower concentration to demonstrate linearity. The sensitivity of the GCMS measurement system for the individual target analytes depends upon:1.5.1 The specific instrument response for each target analyte and the number of mass spectral quantification ions available.1.5.2 The amount of instrument noise, and1.5.3 The percent moisture content of the sample gas.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Additional safety precautions are described in Section 9.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 In using the methods of Practice D3960 to measure the VOC content of coatings, precision tends to be poor for waterborne coatings because the VOC weight fraction is determined indirectly. The present method first identifies and then quantifies the individual VOCs directly. The total VOC weight fraction is obtained by adding the individual weight fraction values.1.1 This test method is for the determination of the individual organic volatile compounds of waterborne multi-component coatings using gas chromatography (see Note 1).1.2 The method has also been used successfully to determine the speciated volatile organic content of solvent-borne multi-component coatings. Work is continuing to develop this aspect of the method and will be added to the method at a later date.NOTE 1: Currently there are no methods for the direct analysis of the VOC content of waterborne multi-component coatings. The VOC content of solvent-borne multi-component coatings is determined directly by a simple weight loss determination of the mixed components (Test Method D2369).1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Compliance with national and local air emission regulations create the need to determine volatile organic compound (VOC) emissions from adhesive-bonded structural wood products.5.2 This method has been used to estimate the types and amounts of certain VOC that are emitted during production operations.5.3 The method was originally developed to measure the methanol, formaldehyde, and phenol emitted in a laboratory setting that is designed to simulate the hot pressing, and post pressing conditions of hot stacking and cool down period for exterior plywood and laminated veneer lumber (LVL) processes. This current method generalizes the concept for adhesive-bonded wood products.1.1 This test method provides a method for the collection of volatile organic compounds (VOC) that are emitted during the manufacture of engineered wood products using a laboratory environment designed to simulate a defined production process. The method is used for the determination of the amounts of methanol, formaldehyde, phenol and other VOC that may be emitted during conditions designed to simulate production such as hot pressing, the conditions of ‘hot stacking’ and ‘cool-down’ that occurs post-press.1.2 The test method was originally developed to measure certain VOC from exterior plywood meeting Voluntary Product Standard PS 1–09 and structural composite lumber products such as laminated veneer lumber (LVL) meeting Specification D5456. Both of these product types are typically manufactured using phenol-formaldehyde resin based adhesives that meet Specification D2559.1.3 The test method is suitable for many types of wood products bonded with adhesives.1.4 This test method is specific for collecting VOC during simulated production of wood products and is not designed to determine general organic emissions from all indoor materials or sources.1.5 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Some specific hazards statements are given in Section 7 on Hazards.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers the design requirements of each component and basic equipment comprising the apparatus used for the microdetermination of carbon and hydrogen in organic and organometallic compounds along the lines of the conventional method of Pregl, but with modifications more in line with modern practice. Due to the diversity of this apparatus by which correct results can be obtained, this specification is intended to indicate what is acceptable rather than what is mandatory. The components covered here are the oxygen supply, pressure, regulator, drying and purifying tube, flowmeter, combustion unit, absorption tubes, guard tube, Mariotte bottle, and weighing accessories.1.1 This specification covers apparatus and basic equipment for the determination of carbon and hydrogen in organic and organometallic compounds along the lines of the conventional method of Pregl, but with modifications more in line with modern practice. Owing to the diversity of apparatus by which correct results can be obtained, this specification is intended to indicate what is acceptable rather than what is mandatory.NOTE 1: Specifications for several items subsequently listed were developed by the Committee for the Standardization of Microchemical Apparatus, Division of Analytical Chemistry, American Chemical Society.21.2 The values stated in inch-pound units are to be regarded as the standard. The metric equivalents of inch-pound units may be approximate.

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ASTM D3447-01 Standard Test Method for Purity of Halogenated Organic Solvents (Withdrawn 2004) Withdrawn, Replaced 发布日期 :  1970-01-01 实施日期 : 

1.1 This test method covers the determination of common impurities found in halogenated organic solvents introduced during the manufacturing of the solvent. Although the absolute sensitivity may vary, sensitivity in the parts per million range may be achieved under the chromatographic conditions specified in this method.1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 The objective of this practice is to provide procedures for estimating emission profiles of VOCs from bedding sets. These profiles can then be used to estimate human inhalation exposures to VOCs emitted from bedding sets. The estimated inhalation exposures ultimately can be used as an input to characterization of health risks from short–term VOC exposures.5.2 The results of emissions testing for specific raw materials and components, or processes used in manufacturing different bedding sets, can be used to compare their relative impacts on airborne concentrations.1.1 This practice covers the procedures for estimating emission profiles of volatile organic chemicals (VOCs) from bedding sets when a new bedding set is first brought into a house, based on emissions testing in environmental chambers.1.2 Emission profiles from bedding sets are determined from air concentrations measured in environmental chambers.1.3 VOC emissions from bedding sets, as in the case of other household furnishings, usually are highest when the products are new. Procedures described in this practice also are applicable to used bedding sets.1.4 The practice is applicable to VOCs and not to semi-volatile organic chemicals or nonvolatile organic chemicals.1.5 This practice summarizes procedures for sample selection and handling. This practice also refers to pertinent sampling procedures and analytical methods for emission testing, but does not include technical details on selection of appropriate collection media and analytical methods or on sampling and analytical equipment and associated procedures.1.6 Emission profiles based on this practice may be used for estimating human exposures to VOCs.1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is used for determination of the carbon content of water from a variety of natural, domestic, and industrial sources. In its most common form, this test method is used to measure organic carbon as a means of monitoring organic pollutants in industrial wastewater. These measurements are also used in monitoring waste treatment processes.5.2 The relationship of TOC to other water quality parameters such as chemical oxygen demand (COD) and total oxygen demand (TOD) is described in the literature (5).1.1 This test method covers the catalyzed hydroxyl radical oxidation system for the in-stream, online (Guide D5173) or laboratory analysis of total organic carbon, total carbon and total inorganic carbon in drinking water, wastewater, industrial process water, and effluent water. It is applicable to both dissolved and suspended materials. Suspended materials and particulates up to 2 mm in diameter can be analyzed.1.2 This test method allows for determination of TOC ≥ 1 mg/L, TC ≥ 1 mg/L, and TIC ≥ 1 mg/L. The lower and upper working ranges are restricted by instrument-dependent conditions (for example, sample volume, amount of each reactant) and can be adjusted for a wider range.1.3 This test method can be applied for the determination of total carbon (TC) and total inorganic carbon (TIC). Volatile or purgeable organic carbon (VOC, POC) can be determined separately by this test method (see Annex A1).1.4 This test method allows the measurement of organic and inorganic carbon concentration samples, and samples containing dissolved chlorides up to seawater chloride concentrations.1.5 The chemical oxidation process, applied in this test method, takes place at ambient pressure and temperature by using hydroxyl radicals. The advantage of catalytic hydroxyl radical oxidation is that it is free from seawater salinity interference.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.1.8 ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk of infringement of such rights, are entirely their own responsibility.1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers asphalt-saturated organic felt for use as an underlayment in steep slope roofing. The objective of this specification is to provide a finished product that will lie flat and resist wrinkling, puckering, and shrinking when left exposed to the sun, rain, frost, or dew for a period of two weeks after application. In the process of manufacture, a single thickness of organic dry felt shall be uniformly saturated with an asphaltic saturant and the felt shall be produced principally from organic fibers. The surface of the felt shall be uniform and relatively smooth and upon splitting or tearing on the bias, the felt shall appear free of lumps or particles of foreign substances. The material shall conform to the prescribed physical requirements such as tear strength, pliability, loss on heating, liquid water transmission, breaking strength, and dimensional stability, and to the specified dimension and mass requirements such as roll width, roll area, net mass of saturated felt, net mass of desaturated felt, saturation, moisture, and saturating efficiency. The finished product shall not crack nor be so sticky as to cause tearing or other damage upon being unrolled. The following tests shall be taken: (1) determination of saturation percent of felt, (2) determination of resistance to liquid water transmission using water shower exposure test, and (3) test for dimensional stability to low and high humidity. The water shower exposure test for underlayment is illustrated.1.1 This specification covers asphalt-saturated organic felt for use as an underlayment with steep slope roofing.1.2 The objective of this specification is to provide a finished product that will lie flat and resist wrinkling, puckering, and shrinking when left exposed to the sun, rain, frost, or dew for a period of two weeks after application.1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the standard.1.4 The following safety hazards caveat pertains only to the test method portion, Section 8, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The objective of this practice is to provide procedures for estimation of human inhalation exposure to VOCs emitted from bedding sets in homes. The estimated inhalation exposure can be used as an input for characterization of health risks from short-term VOC exposures.5.2 The results of exposure estimation for specific raw materials and components, or processes used in manufacturing different bedding sets, can be used to compare their relative impacts on exposures.1.1 This practice describes the procedures for estimation of short-term human inhalation exposure to volatile organic compounds (VOCs) emitted from bedding sets when a new bedding set is first brought into a bedroom.1.2 The estimated exposure is based on an estimated emission profile of VOCs from bedding sets.1.3 The VOC emission from bedding sets, as in the case of other household furnishings, usually are highest when the products are new. Procedures described in this practice are applicable to both new and used bedding sets.1.4 Exposure to airborne VOC emissions in a residence is estimated for a household member, based on location and activity patterns.1.5 The estimated exposure may be used for characterization of health risks that could result from short-term exposures to VOC emissions.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Tensile properties determined by this method are of value in studying the behavior of coatings subjected to environmental stresses, such as those produced by aging and weathering. (See Refs. (1-10).)45.2 Tensile properties may vary with specimen thickness, method of preparation, gage length, rate of load application, tensile tester response, and type of grips used. Consequently, where precise comparative results are desired, these factors must be carefully controlled.1.1 This test method covers the determination of the elongation, tensile strength, and stiffness (modulus of elasticity) of organic coatings when tested as free films.1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 MSW composting is considered an important component in the overall solid waste management strategy. The volume reduction achieved by composting, combined with the production of a usable end product (for example, compost as a soil amendment), has resulted in municipalities analyzing and selecting source-separated organic MSW composting as an alternative to landfill disposal of biodegradable organic materials. This standard provides a method to analyze and determine the effect of materials on the compost process and the performance, utility, and feasibility of the composting process as a method for managing organic solid waste material.5 Using this method, key parameters of process performance, including theoretical oxygen uptake (ThOU) and theoretical carbon dioxide production (ThCO2P) are determined.5.2 This test method provides a simulation of the overall compost process while maintaining reproducibility. Exposing the test material with several other types of organic materials that are typically in MSW provides an environment which provides the key characteristics of the composting process, including direct measurement of organism respiration.1.1 This test method covers the biodegradation properties of a material by reproducibly exposing materials to conditions typical of source-separated organic municipal solid waste (MSW) composting. A material is composted under controlled conditions using a synthetic compost matrix and determining the acclimation time, cumulative oxygen uptake, cumulative carbon dioxide production, and percent of theoretical biodegradation over the period of the test. This test method does not establish the suitability of the composted product for any use.1.2 This test is performed at mesophilic temperatures. Some municipal compost operations reach thermophilic temperatures during operation. Thermophilic temperatures can affect the biodegradation of some materials. This test is not intended to replicate conditions within municipal compost operations that reach thermophilic temperatures.1.3 The values stated in both inch-pound and SI units are to be regarded separately as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is useful for determining the quantity of fibers in a peat or organic soil specimen. Fiber content is one parameter used to classify the peat as determined in Classification D4427. It is also a significant parameter in predicting or defining the many end uses of these materials. In this regard, fiber content has been related to agricultural and horticultural end uses (such as mulching and soil enrichment), geotechnical measurements (such as strength, compressibility, and permeability), industrial chemical uses (such as production of waxes, activated carbon, and medicines), and energy uses (such as direct combustion, methanol production, and gas yields).NOTE 1: The quality of the result produced by this standard is dependent on the competence of the personnel performing it, and the suitability of the equipment and facilities used. Agencies that meet the criteria of Practice D3740 are generally considered capable of competent and objective testing/sampling/inspection/etc. Users of this standard are cautioned that compliance with Practice D3740 does not in itself assure reliable results. Reliable results depend on many factors; Practice D3740 provides a means of evaluating some of those factors.1.1 This test method covers the laboratory determination of the fiber content of peat and organic soils by dry mass. Classification D4427 provides the methodology to classify peat as it is used in this standard.1.2 Pieces of plant material such as roots or wood, larger than 20 mm in smallest dimension are not considered fibers.1.3 Because this test method is simple and does not need sophisticated equipment in order to be performed, it is especially recommended for routine reconnaissance work where large numbers of samples need to be tested and mineral contents are low.1.4 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. Alternate sieve designations in parentheses are as provided in Specification E11.1.5 All observed and calculated values shall conform to the guidelines for significant digits and rounding established in Practice D6026.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 The coulometric technique is especially suited for determining low concentrations of water in organic liquids that would yield small titers by the Karl Fischer volumetric procedure. The precision and accuracy of the coulometric technique decreases for concentrations of water much greater than 2.0 % because of the difficulty in measuring the small size of sample required. The test method assumes 100 % efficiency of coulombs in iodine production. Provision is made for verifying this efficiency. (See Table 1 and Note 5.)1.1 This test method covers the determination of water from 0 % to 2.0 % mass in most liquid organic chemicals, with Karl Fischer reagent, using an automated coulometric titration procedure. Use of this test method is not applicable for liquefied gas products such as Liquid Petroleum Gas (LPG), Butane, Propane, Liquid Natural Gas (LNG), etc.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first-aid procedures, handling, and safety precautions.1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 8.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Old coatings, such as paint or related coatings, may have to be removed from a surface before successful recoating can occur. This practice can be used to test the coatings removal efficiency of products designed for such use.1.1 The practice evaluates the effectiveness of coatings removers used on clear or pigmented coatings as applied to wood and metal.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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