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5.1 This test method allows the determination of the chemical composition of powdered and sintered tungsten-based hardmetals. This test method is not applicable to material which will not oxidize readily at high temperatures in air, such as tungsten/copper, tungsten/silver alloys, or tungsten/cobalt-ruthenium alloys.5.2 This test method specified lithium-borate compounds for the glass fusion material. However, numerous other choices are available. These include other lithium-borate compounds, sodium carbonate and borate mixtures, and others. The methodology specified here is still applicable as long as the same fusion mixture is used for both standards and specimens.1.1 This test method describes a procedure for the determination of the concentration, generally reported as mass percent, of the metallic constituents of tungsten-based alloys and hardmetals utilizing wavelength dispersive X-ray fluorescence spectrometry (XRF). This test method incorporates the preparation of standards using reagent grade metallic oxides, lithium-borate compounds, and fusion techniques. This test method details techniques for preparing representative specimens of both powder and sintered tungsten-based material. This test method is accurate for a wide range of compositions, and can be used for acceptance of material to grade specifications.1.2 This test method is applicable to mixtures of tungsten or tungsten carbide with additions of refractory metal carbides and binder metals. Table 1 lists the most common elemental constituents and their concentration range. Note that many of these occur as metallic carbides.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers standard requirements for chromium-tungsten-molybdenum-vanadium, with or without tantalum, alloy steel plates intended primarily for welded boilers and pressure vessels designed for elevated temperature service. The steel shall be killed and shall conform to the fine austenitic grain size requirements. Heat and product analyses shall conform to the required chemical composition for carbon, manganese, phosphorus, sulfur, silicon, nickel, chromium, molybdenum, vanadium, boron, tantalum, and tungsten. The material shall undergo tensile test and shall conform to the required tensile properties such as tensile strength, yield strength, and elongation.1.1 This specification covers chromium-tungsten-molybdenum-vanadium, with or without tantalum, alloy steel plates intended primarily for welded boilers and pressure vessels designed for elevated temperature service.1.2 Plates are available under this specification in two grades having different alloy contents as follows:Grade NominalChromiumContent, % NominalTungstenContent, % NominalMolybdenumContent, % NominalVanadiumContent, % NominalTantalumContent, %315 3.00 1.50 0.75 0.25 315T 3.00 1.50 0.75 0.25 0.101.3 The maximum thickness of plates is limited only by the capacity of the composition to meet the specified mechanical property requirements.1.4 The specification is expressed in both inch-pound units and in SI units; however, unless the order specifies the applicable “M” specification designation (SI units), the plates are furnished to inch-pound units.1.5 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.

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This specification covers higher strength chromium-molybdenum-tungsten alloy steel forgings intended primarily for use in boilers and pressure vessels for elevated temperature service. Materials shall be manufactured by melting processes, except that the open hearth process shall not be used, and that the molten steel shall be vacuum degassed prior to or during teeming of the ingot. The alloy steels may then be given an intermediate heat treatment such as normalizing and tempering or a subcrititcal anneal prior to rough machining. Heat analysis shall be obtained from samples to ensure chemical composition requirements are met. The steel forgings shall also undergo tension and Charpy impact tests and shall conform to the following required mechanical properties: tensile strength, yield strength, elongation, reduction of area, lateral expansion, minimum average absorbed energy, and minimum single value. Nondestructive examination procedures, such as straight-beam and angle-beam ultrasonic examination, and magnetic particle examination, shall also be executed.1.1 This specification covers chromium-molybdenum-tungsten alloy steel forgings intended primarily for use in boilers and pressure vessels for elevated temperature service.1.1.1 Elevated temperatures are temperatures in the range where creep and stress rupture properties are important for the alloy steels in this specification.1.2 Supplementary requirements are provided both in this specification and in the General Requirements Specification A788/A788M for use when additional testing or inspection is desired. These shall apply only when specified individually by the purchaser in the purchase order or contract.1.3 Unless the order specifies the applicable “M” specification designation, the forgings shall be supplied to the inch-pound units.1.4 The values stated in either inch-pound or SI (metric) units are to be regarded separately as standard. Within the text and tables, the SI units are shown in brackets. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the specification.

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This specification covers electrical contact components made from silver-tungsten carbide by powder metallurgical procedures. This specification covers compositions within the silver-tungsten carbide system. The material shall conform to composition limits. Chemical analysis shall be performed to deteremine material conformance to specified composition requirements. The contact components shall agree on qualification tests for determination of physical properties. The tests shall be performed on production parts wherever practical or applicable. The test shall be determined after consideration of the function of the part.1.1 This specification covers electrical contact components made from silver-tungsten carbide materials by powder metallurgical processes.1.2 This specification covers compositions within the silver-tungsten carbide system normally specified by users of contacts.NOTE 1: Table X1.1 and Table X1.2 in Appendix X1 provide a list of typical compositions used for various applications.1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The microstructure and grain growth of cemented tungsten carbides affect the material's mechanical and physical properties. The grain size and distribution will affect the material's wear resistance and fracture toughness. Abnormally large grains as compared to the background may introduce an area of weakness in a sintered part.5.2 This test method may be used in acceptance testing of cemented tungsten carbide materials or the tungsten carbide powder used in their manufacture. The specified grain size used for the E-Rating is to be agreed upon between purchaser and supplier.1.1 This test method describes a procedure for measuring abnormally large grains and the frequency of those grains in cemented tungsten carbides (hardmetals).1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 This sample preparation procedure may be used to prepare metallographic samples for Guide B657. It does not include all variations of sample preparation.1.1 This guide prescribes a method for preparing cemented carbides for metallographic examination.1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers chromium-molybdenum-tungsten alloy steel plates intended primarily for welded boilers and pressure vessels designed for elevated temperature service. The plates shall be available in three grades, namely Grades 23, 911, and 122, having different alloy contents. The maximum thickness of plates is limited only by the capacity of the composition to meet the specified mechanical requirements. The steel shall be killed and the plates shall undergo heat treatment. In order to determine mechanical properties such as yield strength and elongation, the plates shall be subjected to tension and hardness tests.1.1 This specification covers Chromium-Molybdenum-Tungsten alloy steel plates intended primarily for welded boilers and pressure vessels designed for elevated temperature service.1.2 Plates are available under this specification in grades having different alloy contents as follows:Grade NominalChromiumContent, % NominalMolybdenumContent, % NominalTungstenContent, %       23 2.25 0.20 1.60911 9.00 1.00 1.0092 9.00 0.45 1.75122 12.00 0.40 2.001.3 The maximum thickness of plates is limited only by the capacity of the composition to meet the specified mechanical property requirements.1.4 The specification is expressed in both inch-pound units and in SI units. However, unless the order specifies the applicable “M” specification designation (SI units), the material shall be furnished to inch-pound units.1.5 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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The apparent size and distribution of tungsten carbide grains in cemented carbides affects the material’wear resistance and fracture. For a given chemical composition, an increase in the average grain size will result in increased toughness and decreased wear resistance. This practice illustrates representative micro-structures for a wide range of tungsten carbide-cobalt grades. This is not intended to be used as a specification for carbide grades; producers and users may use the micrographs and the grain size chart as a guide in developing their own specifications.1.1 This practice for the visual comparison and classification of the apparent grain size and distribution of cemented tungsten carbides is limited to cemented tungsten carbides that contain approximately 6, 10, and 18 % cobalt.This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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This specification covers the standard for cobalt-chromium-nickelmolybdenum-tungsten alloy UNS R31233 in the form of rolled plate, sheet, and strip proposed for use in wear applications and general corrosion service. Materials should conform to mechanical properties such as tensile strength, yield strength, and elongation.1.1 This specification covers cobalt-chromium-nickel-molybdenum-tungsten alloy UNS R31233 in the form of rolled plate, sheet, and strip for wear applications and general corrosion service.1.2 The following products are covered under this specification:1.2.1 Sheet and Strip—Hot or cold rolled, annealed and descaled unless solution-annealing is performed in an atmosphere yielding a bright finish.1.2.2 Plate—Hot rolled, solution-annealed, and descaled.1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This test method can be used to ensure absolute reproducibility of WSix film deposition systems over the course of many months. The time span of measurements is essentially the life of many process deposition systems.This test method can be used to qualify new WSix deposition systems to ensure duplicability of existing systems. This test method is essential for the coordination of global semiconductor fabrication operations using different analytical services. This test method allows samples from various deposition systems to be analyzed at different sites and times.This test method is the chosen calibration technique for a variety of analytical techniques, including, but not limited to:Electron spectroscopy for chemical analysis (ESCA or XPS),Auger electron spectroscopy (AES),Fourier transform infrared red spectroscopy (FTIR),Secondary ion mass spectrometry (SIMS), andElectron dispersive spectrometry (EDS) and particle induced x-ray emission (PIXE).1.1 This test method covers the quantitative determination of tungsten and silicon concentrations in tungsten/silicon (WSix) semiconductor process films using Rutherford Backscattering Spectrometry (RBS). (1) This test method also covers the detection and quantification of impurities in the mass range from phosphorus Å (31 atomic mass units (amu) to antimony (122 amu).1.2 This test method can be used for tungsten silicide films prepared by any deposition or annealing processes, or both. The film must be a uniform film with an areal coverage greater than the incident ion beam (∼2.5 mm).1.3 This test method accurately measures the following film properties: silicon/tungsten ratio and variations with depth, tungsten depth profile throughout film, WSix film thickness, argon concentrations (if present), presence of oxide on surface of WSix films, and transition metal impurities to detection limits of 1×1014 atoms/cm2.1.4 This test method can detect absolute differences in silicon and tungsten concentrations of ±3 and ±1 atomic percent, respectively, measured from different samples in separate analyses. Relative variations in the tungsten concentration in depth can be detected to ±0.2 atomic percent with a depth resolution of ±70Å.1.5 This test method supports and assists in qualifying WSix films by electrical resistivity techniques.1.6 This test method can be performed for WSix films deposited on conducting or insulating substrates.1.7 This test method is useful for WSix films between 20 and 400 nm with an areal coverage of greater than 1 by 1 mm2.1.8 This test method is non-destructive to the film to the extent of sputtering.1.9 A statistical process control (SPC) of WSix films has been monitored since 1993 with reproducibility to ±4 %.1.10 This test method produces accurate film thicknesses by modeling the film density of the WSix film as WSi2 (hexagonal) plus excess elemental Si2. The measured film thickness is a lower limit to the actual film thickness with an accuracy less than 10 % compared to SEM cross-section measurements (see 13.4).1.11 This test method can be used to analyze films on whole wafers up to 300 mm without breaking the wafers. The sites that can be analyzed may be restricted to concentric rings near the wafer edges for 200-mm and 300-mm wafers, depending on system capabilities.1.12 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.13 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. The reader is referenced to Section 8 of this test method for references to some of the regulatory, radiation, and safety considerations involved with accelerator operation.

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This specification covers the requirements for bare solid conductors made of tungsten and rhenium alloy thermoelements supplied in matched pairs. These thermoelements shall be suitable for use in either bead-insulated, bare-wire thermocouples, or in compacted metal-sheathed, ceramic insulated thermocouple material or assemblies. Unless otherwise noted, all information in this specification applies to both thermocouple combinations of tungsten-3 % rhenium versus tungsten-25 % rhenium (W3Re/W25Re) and tungsten-5 % rhenium versus tungsten-26 % rhenium (W5Re/W26Re; Type C). Thermoelements should meet specified physical, mechanical, thermoelectric, and compositional requirements.1.1 This specification covers the requirements for bare, solid conductor, tungsten and rhenium alloy thermoelements having diameters of 0.127 mm (0.005 in.) to 0.508 mm (0.020 in.) supplied in matched pairs. These thermoelements shall be suitable for use either in bead-insulated, bare-wire thermocouples, or in compacted metal-sheathed, ceramic insulated thermocouple material or assemblies.1.2 This specification covers the thermocouple combinations of tungsten-3 % rhenium versus tungsten-25 % rhenium (W3Re/W25Re) and tungsten-5 % rhenium versus tungsten-26 % rhenium (W5Re/W26Re; Type C). All information applies to both combinations unless otherwise noted.1.3 It is recognized that the alloys described are refractory and are not suitable for use at high temperatures in oxidizing atmospheres. All tests and processes described herein must be performed under conditions that are non-reactive to tungsten-rhenium alloys.1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification2 covers rod of low-carbon nickel-chromium- molybdenum alloys (UNS N10276, N06022, N06035, N06455, N06058, and N06059), low-carbon nickel-molybdenum- chromium-tantalum (UNS N06210), low-carbon nickel-chromium-molybdenum-copper alloy (UNS N06200), and low-carbon nickel-chromium-molybdenum-tungsten (UNS N06686), for use in general corrosive service. Product and chemical analyses shall be performed on the materials and shall conform to the required chemical composition in molybdenum, chromium, iron, tungsten, cobalt, carbon, silicon, manganese, vanadium, phosphorus, sulfur, titanium, nickel, aluminum, copper, and tantalum. Tension test shall be performed and shall comply to required mechanical properties for hot or cold finished, solution annealed rods such as tensile strength, yield strength, and elongation. 1.1 This specification2 covers rod and bar of low-carbon nickel-chromium-molybdenum alloys (UNS N10276, N06022, N06035, N06044, N06455, N06058, and N06059), low-carbon nickel-molybdenum-chromium (USN N10362), low-carbon nickel-molybdenum-chromium-tantalum (UNS N06210), low-carbon nickel-chromium-molybdenum-copper alloy (UNS N06200), and low-carbon nickel-chromium-molybdenum-tungsten (UNS N06686) as shown in Table 1, for use in general corrosive service. 1.2 The following products are covered under this specification: 1.2.1 Rods and Bars 5/16 in. to 3/4 in. (7.94 mm to 19.05 mm), exclusive, in dimension3, solution annealed and pickled, or mechanically descaled. 1.2.2 Rods and Bars 3/4 in. to 31/2 in. (19.05 mm to 88.9 mm), inclusive, in dimension3, solution annealed, ground or turned. 1.2.3 Rods and Bars 1/4 in. to 3 1/2 in. (6.35 mm to 88.9 mm), inclusive, in dimension3, solution annealed, cold worked, ground or turned (N06022, N06059, N06686, and N10276, see Table 2 and Table 3). 1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers plate, sheet, and strip of low-carbon nickel-chromium-molybdenum alloys (UNS N10276, N06022, N06455, N06035, UNS N06058, UNS N06059), low carbon nickel-chromium-molybdenum-copper alloy (UNS N06200), low-carbon nickel-chromium-molybdenum-tantalum alloy (UNS N06210), and low-carbon nickel-chromium-molybdenum-tungsten alloy (UNS N06686) for use in general corrosive service. The materials shall conform to the required chemical composition for molybdenum, chromium, iorn, tungsten, cobalt, arbon, silicon, manganese, vanadium, phosphorus, sulfur, titanium, nickel, aluminum, copper, and tantalum. The alloys shall connform to the required tensile properties such as tensile strength, yield strength, elongation, and Rockwell hardness. Sheet and strip shall conform to the required grain sizes. Dimensions such as plate, sheet and strip thickness, width, length, straightness, squareness, flatness and edges shall be determined.1.1 This specification2 covers plate, sheet, and strip of low-carbon nickel-chromium-molybdenum alloys (UNS N10276, N06022, N06455, N06035, N06044, UNS N06058, UNS N06059),3 low-carbon nickel-chromium-molybdenum-copper alloy (UNS N06200), low-carbon nickel-molybdenum-chromium (UNS N10362), low-carbon nickel-chromium-molybdenum-tantalum alloy (UNS N06210), and low-carbon nickel-chromium-molybdenum-tungsten alloy (UNS N06686) as shown in Table 1, for use in general corrosive service.1.2 The following products are covered under this specification:1.2.1 Sheet and Strip—Hot or cold rolled, solution annealed, and descaled unless solution anneal is performed in an atmosphere yielding a bright finish.1.2.2 Plate—Hot or cold rolled, solution annealed, and descaled.1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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