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3.1 These test methods are suitable for determining if impurities are present and establishing that the required pigments are present. These test methods may be used for manufacturing and purchasing quality control.1.1 These test methods cover procedures for the qualitative chemical analysis of pigments known commercially as copper phthalocyanine blue and green.1.2 The procedures appear in the following order:  SectionIdentification 5Moisture and Other Volatile Matter 6Detection of Basic Dye Derivatives 7Detection of Other Organic Coloring Matter 8Detection of Ultramarine Blue 9Detection of Iron Blue or Chrome Green 101.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The procedure described is specific for chromium in Wet Blue. Vanadium is the only common interfering element and this is rarely present in quantity. The precision and accuracy of the methods are usually at least as good as the sampling of the Wet Blue itself, and the accuracy of previously performed test methods.5.2 The chromium content of Wet Blue is related to the degree of tannage obtained, and hence may be a matter for specification in the purchase of Wet Blue. The procedure described provides adequate accuracy for this purpose.1.1 This test method covers the determination of chromic oxide in Wet Blue that has been partly or completely tanned with chromium compounds. In general the samples will contain chromium content between 1 and 5 %, calculated as chromic oxide expressed upon a dry basis otherwise referred to as moisture-free basis (mfb).1.2 This test method is specific in that it applies to a sample or samples that are the resultant ash following the execution of Test Method D6716.1.3 This test method does not apply to Wet White.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards are given in Section 8.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM C837-09(2019) Standard Test Method for Methylene Blue Index of Clay Active 发布日期 :  1970-01-01 实施日期 : 

3.1 Tests run on many clays generally indicate that a straight-line relationship exists between the methylene blue index (MBI) and such fundamental clay properties as cation exchange capacity, dry bond strength, and casting rate. Where the colloidal portion of the clay is kaolinite, there is also a direct correlation with specific surface (as determined by nitrogen adsorption). Where the colloidal portion contains significant amounts of illite or montmorillonite, the same close correlation does not exist. The MBI better correlates with the ceramic-forming properties than does the specific surface.3.2 That portion of a clay lying within the colloidal range (generally defined as the 0.5- to 0.001-μm range), determines the strictly colloidal properties of the clay and, together with the amount and type of organic material associated with the clay and the 2- to 0.2-μm fraction, largely determines the properties of the clay when used in ceramic-forming processes. While the specific surface of a clay is a function of the particle size and morphology and a relationship exists between dye adsorption and specific surface, the MBI should not be considered to be a particle size analysis since the value obtained is dominated by the character of only the very fine end of the particle size distribution. This procedure describes the determination of the dye adsorption (in this case, methylene blue) of a clay.1.1 This test method covers the measurement of the adsorption of methylene blue dye by a clay, which is calculated as a methylene blue index for a clay.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is useful in determining the approximate amount of nonvolatile inorganic material in wet blue. This may be in the form of salts or oxides of the elements. In a mixed-chrome tannage, the approximate percentage of other elements in the wet blue may be determined by subtracting the chromic oxide that may be conveniently determined on the ash. (See Test Method D6714.)5.2 The specified temperature of 600°C is high enough to produce a reproducible result but it does not completely dehydrate such oxides as aluminum oxide (Al2O3) and chromic oxide (Cr2O3). Likewise, such salts as sulfates and phosphates may be incompletely dehydrated, and if alkalis and chromium are present simultaneously, oxidation to chromate may occur. Therefore, caution is advised in drawing conclusions based on quantitative relations of the elements.1.1 This test method covers the determination of total ash in wet blue and wet white.1.2 For total ash in wet white, the procedure is identical; substitute wet white for wet blue in the standard.1.3 Total ash in wet blue may be reported upon a number of different bases (for example, fat-free, moisture-free, as received, excluding chromium, and so forth). Before proceeding with any tests, it is very important to determine upon which basis that the total ash is to be reported and to identify all other test methods that will be required to be executed in order to achieve the determined reporting method.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method measures the amount of unfixed chrome in Wet Blue. Results may vary according to the age of the Wet Blue.1.1 This test method covers the procedures to analyze and calculate unfixed chrome concentrations in Wet Blue.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 The nitrogen content as determined by this test method is normally considered to be related to the amount of hide substance (protein fiber) present in the leather sample. A factor of 5.62 is normally used to calculate the hide substance from the nitrogen content.4.1.1 The 5.62 factor represents the average result of many analyses of animal hides, but it cannot be considered to be accurate since it varies somewhat from hide to hide of the same type, from type of hide to type of hide, and also with the thickness of hide retained in the final leather (split thickness as compared to original hide thickness). As a result of these variations, the true factor for any given leather may be expected to vary from 5.44 to 5.80 or about ±3 %.34.2 A given leather sample may contain nitrogenous substances other than hide substance (protein fiber) which will be analyzed for by this test method, such as resins, dyestuffs, etc., that contain nitrogen. Therefore, although this test method is fairly accurate for determining the nitrogen content of leather, its use for determining hide substance may result in large errors.4.3 The hide substance value derived from this determination has a large bearing on other chemical determinations of a given leather. Any errors, such as those described in 4.1.1 and 4.2, will be carried over into these other analytical calculations.1.1 This test method covers the determination of the nitrogen content of all types of leather, wet blue and wet white. The nitrogen content is used to calculate the hide substance (protein fiber) content of leather, wet blue and wet white.NOTE 1: The original test method for leather was essentially a composite of Method 6441 of Federal Test Method Standard No. 311 and Method B5 of the American Leather Chemists Association.NOTE 2: Melamine, if present in bonded leather, could give an artificially high value for the calculation of protein fiber.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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6.1 The environmental chamber method is an accelerated test for determining the resistance of Wet Blue and Wet White to the growth of fungi, the causal agent of mold. See Test Method D3273.3,46.2 The environmental chamber method is useful in estimating the performance of fungicides and should assist in the prediction of storage time before fungal growth begins.6.3 The environmental chamber method duplicates the natural environment in which Wet Blue or Wet White is inoculated with fungal spores and subsequently disfigured or discolored by fungi.6.4 The environmental chamber method measures the resistance of the treated Wet Blue or Wet White to the germination of spores and subsequent vegetative growth that spreads over the surface of a comparatively large Wet Blue or Wet White specimen over a period of four weeks.6.5 The environmental chamber can be kept inoculated with fungi representative of those found in tanneries by adding samples of Wet Blue and Wet White with fungal growth from currently operating tanneries.6.6 Control specimens of Wet Blue and Wet White without fungicide treatment can be added to the chamber periodically to increase levels of fungal growth in the chamber.6.7 Leaching of fungicide from the test specimen into the agar often causes a zone of inhibition of fungal growth in the Petri dish test, but in the environmental chamber any leaching of fungicide from the test specimen drips into the water contained in the chamber and thus does not cause the types of false readings observed in the Petri dish test.1.1 This environmental chamber method measures the resistance of the treated Wet Blue and Wet White to the germination of spores and subsequent vegetative growth over a period of four weeks. The test method is useful in estimating the performance of fungicides and should assist in the prediction of storage time of Wet Blue and Wet White before fungal growth begins. The apparatus is designed so it can be easily built or obtained by any interested party and duplicate the natural environment in which Wet Blue and Wet White is inoculated with fungal spores. Spores that germinate on untreated or treated Wet Blue and Wet White can produce fungal growth, resulting in disfigurement or discoloration, or both, of the Wet Blue and Wet White.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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