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5.1 Methanol is used in blends with gasoline at levels of 70 % to 85 % by volume, as specified in Specification D5797. This test method provides a quantitative approach to measure the methanol content in methanol fuel blends, from 10 % to 99 % by volume. The usual concentration is 70 % to 85 % by volume (M70 to M85). The method is also used to analyze fuel methanol (M99) prior to blending.1.1 This test method covers the determination of the methanol content, by gas chromatography, of M10 to M99 in methanol fuel blends, including fuel methanol (M99).1.1.1 Methanol may be determined from 10 % to 99 % by volume.1.2 This test method is designed to measure not only methanol in the blended gasoline but also the impurities in fuel methanol (M99) itself in the range of 5 mg/kg to 1000 mg/kg. However, not all impurities are measured nor detected by this test method.1.2.1 Water cannot be determined by this test method and shall be measured by a procedure such as Test Method D1364 and the result used to correct the concentrations determined by this test method.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Blends of fuel ethanol and hydrocarbon have a limited solvency for water that is dependent upon temperature and the ratio of ethanol to hydrocarbon. Good handling practices are important during the blending, storage, and transportation of fuel to avoid water contamination. High concentrations of water can cause haze or phase separation in ethanol and hydrocarbon blends and lead to freezing problems at low temperatures. Water has also been associated with corrosion and filter plugging.1.1 This test method covers the determination of water in blends of ethanol, hydrocarbon, and corresponding blends. It is intended for measuring water content of gasoline or other hydrocarbon blendstock, denatured fuel ethanol as cited in Specification D4806, and ethanol fuel blends such as those cited in Specification D5798 and Practice D7794. This test method is not applicable to samples that are phase separated.1.1.1 Procedure A—For measurement of water from 0.004 % by mass to 1.63 % by mass in ethanol and hydrocarbon using coulometric Karl Fischer titration. This is the referee method for samples containing up to 1.63 % water.1.1.2 Procedure B—For measurement of water from 0.02 % by mass to 5.41 % by mass in ethanol and hydrocarbon using volumetric Karl Fischer titration.1.2 This method measures mass percent water and allows for the alternative reporting of volume percent. This test method recommends the use of pyridine-free reagents.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 8.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers the methanol fuel blend, M70-M85, for use in ground vehicles that run on automotive spark-ignition engines. Fuels are grouped into three vapor pressure classes (Classes 1, 2, and 3) on the basis of seasonal and geographical volatility. The fuel blends shall undergo chemical analysis for methanol, higher alcohols, hydrocarbon/aliphatic ether, acidity as acetic acid, solvent washed and unwashed gum content, total chlorine as chloride, lead, phosphorus, water, sulfur, and inorganic chloride. The product's appearance shall be clear and bright, visibly free of suspended or precipitated contaminants.1.1 This specification covers the requirements for automotive fuel blends of methanol and gasoline for use in ground vehicles equipped with methanol-capable flexible-fuel, and dedicated methanol spark-ignition engines. Fuel produced to this specification contains 51 % to 85 % by volume methanol. This fuel is sometimes referred to at retail as “M85.” Appendix X1 discusses the significance of the properties specified. Appendix X2 presents the current status in the development of a luminosity test procedure (flame visibility) for methanol fuel blends (M51–M85).1.2 The vapor pressure of methanol fuel blends is varied for seasonal climatic changes. Vapor pressure is increased at lower temperatures to ensure adequate vehicle operability and safety. Methanol content and selection of gasoline blendstocks are adjusted by the blender to meet these vapor pressure requirements.1.3 The United States government has established various programs for alternative fuels. Many of the definitions of alternative fuel used by these programs can be more or less restrictive than the requirements of this specification. See Annex A1 for additional information on alternative fuels containing methanol.1.4 The values stated in SI units are to be regarded as the standard.1.4.1 Exception—Non-SI units are provided for information only. In most cases, U.S. federal regulations specify non-SI units.1.5 The following precautionary caveat pertains only to the test method portions–Appendix X2 of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers a fuel blend, nominally 51 to 83 volume % ethanol for use in ground vehicles equipped with ethanol fuel blend flexible-fuel spark-ignition engines. Ethanol fuel blends, also referred to as “Ethanol Flex Fuel” shall conform to the performance requirements prescribed. Ethanol fuel blends shall be visually free of sediment and suspended matter. The vapour pressure, acidity, pHe requirements, gum content, inorganic chloride, water requirements, copper requirements, and sulphur requirements shall be tested to meet the requirements prescribed.1.1 This specification covers the requirements for automotive fuel blends of ethanol and gasoline for use in ground vehicles equipped with ethanol fuel blend flexible-fuel spark-ignition engines. Fuel produced to this specification contains 51 % to 83 % by volume ethanol. This fuel is for use in flexible-fuel vehicles and is sometimes referred to at retail as “Ethanol Flex-Fuel.” Appendix X1 discusses the significance of the properties specified.1.2 The vapor pressure of ethanol fuel blends is varied for seasonal climatic changes. Vapor pressure is increased at lower temperatures to ensure adequate flexible-fuel vehicle operability. Ethanol content and selection of hydrocarbon blendstock are adjusted by the blender to meet these vapor pressure requirements.1.3 This specification formerly covered Fuel Ethanol (Ed70-Ed85) for Automotive Spark-Ignition Engines, also known commercially as E85. The nomenclature “fuel ethanol” has been changed to “ethanol fuel blends” to distinguish this product from denatured fuel ethanol Specification D4806. To facilitate blending of ethanol fuel blends that meet seasonal vapor pressure requirements, a new lower minimum ethanol content has been established.1.4 The United States government has established various programs for alternative fuels. Many of the definitions of alternative fuel used by these programs may be more restrictive than the requirements of this specification. See 4.1.2.1 for additional information on alternative fuels containing ethanol.1.5 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.6 The following safety hazard caveat pertains only to the test method portion, 8.1.8, of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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1.1 This practice applies to the blending of automotive spark-ignition engine fuels with ethanol concentrations greater than those suitable for conventional-fuel vehicles and less than the minimum ethanol content specification limits of Specification D5798. These mid-level ethanol fuel blends are for use in flexible-fuel vehicles and are sometimes referred to at retail as “Ethanol Flex Fuel.”1.2 These mid-level ethanol fuel blends are only suitable for use in ground flexible-fuel vehicles equipped with spark-ignition engines. Flexible-fuel vehicles are designed to operate on gasoline or gasoline-ethanol blends that meet the requirements of Specification D4814, ethanol fuel blends that meet the requirements of Specification D5798, or any combination of these. In the United States, these vehicles are certified by the U.S. EPA as emissions compliant with these types of fuels.1.3 The mid-level ethanol fuel blend shall be blended from either:1.3.1 Denatured fuel ethanol conforming to the requirements of Specification D4806 with a reduced limit on inorganic chloride content that will ensure no more than 1 mg/kg inorganic chloride in the finished fuel and from spark-ignition engine fuel conforming to Specification D4814 (often at a distribution terminal or bulk plant), or1.3.2 Ethanol fuel blends conforming to Specification D5798 and from spark-ignition engine fuel conforming to Specification D4814 (often at a retail site).1.4 This practice describes the required procedures for blending various mid-level ethanol fuel blends for flexible-fuel vehicles at the bulk distribution point or retail/commercial delivery site. These requirements may be applied at other points in the production and distribution system when provided by agreement between the purchaser and the supplier.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 The laboratory preparation of gas blends of known composition is required to provide primary standards for the calibration of chromatographic and other types of analytical instrumentation.1.1 This practice covers a laboratory procedure for the preparation of low-pressure multicomponent gas blends. The technique is applicable to the blending of components at percent levels and can be extended to lower concentrations by performing dilutions of a previously prepared base blend. The maximum blend pressure obtainable is dependent upon the range of the manometer used, but ordinarily is about 101 kPa (760 mm Hg). Components must not be condensable at the maximum blend pressure.1.2 The possible presence of small leaks in the manifold blending system will preclude applicability of the method to blends containing part per million concentrations of oxygen or nitrogen.1.3 This practice is restricted to those compounds that do not react with each other, the manifold, or the blend cylinder.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method measures acidity in ethanol or ethanol blends quantitatively. Denatured fuel ethanol may contain additives such as corrosion inhibitors and detergents as well as contaminants from manufacturing that can affect the acidity of finished ethanol fuel. Very dilute aqueous solutions of low molecular mass organic acids, such as acetic acid, are highly corrosive to many metals. It is important to keep such acids at a very low level.5.2 Acceptable levels of acidity in ethanol or ethanol blends can vary with different specifications but in general it is below 200 mg/kg (ppm). Knowledge of the acidity can be required to establish whether the product quality meets specification.1.1 This test method covers the determination of acidity as acetic acid (see Specification D4806) in commonly available grades of denatured ethanol, and ethanol blends with gasoline ranging from E95 to E30. This test method is used for determining low levels of acidity, below 200 mg/kg (ppm mass), with the exclusion of carbon dioxide.1.1.1 Procedure A—Developed specifically for measurement of acidity by potentiometric titration. This is the referee method.1.1.2 Procedure B—Developed specifically for measurement of acidity by color end point titration.1.2 The ethanol and ethanol blends may be analyzed directly by this test method without any sample preparation.1.3 Review the current and appropriate Material Safety Data Sheets (MSDS) for detailed information concerning toxicity, first aid procedures, and safety precautions and proper personal protective equipments.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Some specific hazards statements are given in Section 7 on Hazards.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 A standard procedure for blend preparation is essential to ensure material quality, specification compliance, and procedural uniformity.1.1 This practice covers the procedure for preparation of hot recycled bituminous blends for testing in the laboratory. The procedure involves an iterative trial blend process followed by the preparation of batch blends.1.2 The batch blends can be used for extensive evaluation such as viscosity, penetration, ductility, aging properties (such as Rolling Thin Film Oven or Thin-Film Oven tests, or both (RTFO/TFO)), composition analysis, solubility analysis, and other user-selected tests.1.3 This practice assumes that a representative reclaimed asphalt pavement (RAP) sample is extracted and the aged binder recovered using Test Methods D2172/D2172M and Test Method D1856 (this practice may be modified by using a rotary evaporator which is extensively evaluated in the minutes of the 18th Pacific Coast Conference on Asphalt Specifications2) or any other acceptable test method.1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the standard.1.5 The text of this standard references notes and footnotes which provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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