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1.1 This test method covers the gravimetric determination of phthalic anhydride in alkyd resins and esters that contain dibasic acids such as maleic, fumaric, adipic, and sebacic, which would interfere if Test Method D 563 was used.1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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4.1 Any residual fatty acid and esters (FA&E) should be present only at very low levels in purified glycerine.4.2 This procedure requires the addition of a measured volume of sodium hydroxide, in excess of the amount actually needed to react with FA&E in the glycerine sample. After boiling, the excess sodium hydroxide is back titrated with standardized hydrochloric acid. The quantity of the substance being titrated is calculated as the difference between the volumes of the sodium hydroxide solution originally added, corrected by means of a blank titration, and that was consumed by the titrant in the back titration.NOTE 1: The standardized solutions for sodium hydroxide and hydrochloric acid are commercially available.1.1 This test method provides the quantitative determination of the fatty acid and ester content in purified glycerin by the titrimetric method.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard may involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautions are listed in Section 8.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Biodiesel is a blendstock commodity primarily used as a value-added blending component with diesel fuel.5.2 This test method is applicable for quality control in the production and distribution of diesel fuel and biodiesel blends containing FAME.1.1 This test method covers the determination of the content of fatty acid methyl esters (FAME) biodiesel in diesel fuel oils. It is applicable to concentrations from 1.00 % to 20 % by volume (see Note 1). This procedure is applicable only to FAME. Biodiesel in the form of fatty acid ethyl esters (FAEE) will cause a negative bias.NOTE 1: Using the proper ATR sample accessory, the range may be expanded from 1 % to 100 % by volume, however precision data is not available above 20 % by volume.1.2 The values stated in SI units of measurement are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The present and growing international governmental requirements to add fatty acid methyl esters (FAME) to diesel fuel has had the unintended side-effect of leading to potential FAME contamination of jet turbine fuel in multifuel transport facilities such as cargo tankers and pipelines, and industry wide concerns.5.2 Analytical methods have been developed with the capability of measuring down to <5 mg/kg levels of FAME, however these are complex, and require specialized personnel and laboratory facilities. This Rapid Screening method has been developed for use in the supply chain by non specialized personnel to cover the range of 10 mg/kg to 150 mg/kg.1.1 This test method specifies a rapid screening method using flow analysis by Fourier transform infrared (FA-FTIR) spectroscopy with partial least squares (PLS-1) processing for the determination of the fatty acid methyl ester (FAME) content of aviation turbine fuel (AVTUR), in the range of 10 mg/kg to 150 mg/kg.NOTE 1: Specifications falling within the scope of this test method are: Specification D1655 and Defence Standard 91-91.NOTE 2: This test method detects all FAME components, with peak IR absorbance at approximately 1749 cm-1 and C8 to C22 molecules, as specified in standards such as Specification D6751 and EN 14214. The accuracy of the method is based on the molecular weight of C16 to C18 FAME species; the presence of other FAME species with different molecular weights could affect the accuracy.NOTE 3: Additives such as antistatic agents, antioxidants and corrosion inhibitors are measured with the FAME by the FTIR spectrometer. However the effects of these additives are removed by the flow analysis processing.NOTE 4: FAME concentrations from 150 mg/kg to 500 mg/kg, and below 10 mg/kg can be measured but the precision could be affected.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 This test method is useful for identifying and for determining the quantity of various impurities in acetate esters.4.2 Total purity of the acetate esters must be determined by use of other appropriate ASTM procedures with this test method.1.1 This test method covers the determination by gas chromatography of the ester content and the corresponding alcohol content of acetate esters. This test method has been applied to ethyl, n-propyl, isopropyl, n-butyl, isobutyl, and 2-ethoxyethyl acetates.1.2 Water, and in some cases acetic acid, cannot be determined by this test method and must be measured by other appropriate ASTM procedures and the results used to normalize the chromatographic value.1.3 For purposes of determining conformance of an observed or a calculated value using this test method to relevant specifications, test result(s) shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet for material listed in this specification.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Biodiesel is a fuel commodity primarily used as a blending component with diesel fuel. It is important to check the concentration of biodiesel in the diesel fuel in order to make sure it is either not below the minimum allowable limit and or does not exceed the maximum allowable limit.5.2 This test method is applicable for quality control in the production and distribution of diesel fuel and biodiesel blends.1.1 This test method determines fatty acid methyl esters (FAME or biodiesel) in diesel fuel oils. FAME can be quantitatively determined from 1.0 % to 30.0 % by volume. This test method uses linear variable filter (LVF) array based mid-infrared spectroscopy for monitoring FAME concentration.NOTE 1: See Section 6 for a list of interferences that could affect the results produced from this method.1.2 This test method uses a horizontal attenuated total reflectance (HATR) crystal and a univariate calibration.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is used to measure the reactivity of different lots of unsaturated polyester and vinyl ester resins. The information provided by this test is often used for assessing the predicted performance of a resin when used in elevated temperature as part of the process used to convert the resin into a finished product.5.2 The method is used in research and development by companies that manufacture resins and for incoming quality control companies using these polymers as raw materials for production. The method is based on the methods which were previously outlined in the Handbook of Reinforced Plastics, “Procedure for Running Exotherm Curves Using the Block Test Method” published by the Society of the Plastics Industry.1.1 This standard provides a standardized test method for determining the gelation and exotherm curve of unsaturated polyester and vinyl ester resins. This method provides guidance for measurement of the “Standard 180°F (82.2°C) Exotherm Curve” along with information on potential variances of the measurement for some special resins. This test method provides information concerning the reactivity of unsaturated polyester and vinyl ester resins as they go through polymerization after mixing with the initiator.NOTE 1: There is no known ISO equivalent to this standard, although ISO 584 is similar.1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems has the potential to result in nonconformance with the standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The mass of particulates present in a fuel is a significant factor, along with the size and nature of the individual particles, in the rapidity with which fuel system filters and other small orifices in fuel systems can become plugged. This test method provides a means of assessing the mass of particulates present in a fuel sample.5.2 The test method can be used in specifications and purchase documents as a means of controlling particulate contamination levels in the fuels purchased.1.1 This test method covers the determination of the mass of particulate contamination in B100 biodiesel in accordance with Specification D6751 and BXX blends that are prepared against all No. 1 and No. 2 grade fuels allowed within Specifications D396 and D975.NOTE 1: Middle distillate fuels with flash points less than 38 °C have been ignited by discharges of static electricity when the fuels have been filtered through inadequately bonded or grounded glass fiber filter systems. See Guide D4865 for a more detailed discussion of static electricity formation and discharge.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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