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5.1 This test method provides procedures for obtaining tristimulus values, luminance factors and chromaticity coordinates of fluorescent-retroreflective materials by bispectral colorimetry using a 45:0 or 0:45 optical measuring system.5.2 The CIE 1931 (2°) standard observer is used to calculate the colorimetric properties of fluorescent-retroreflective sheeting and markings used in daytime high visibility traffic control and personal safety applications because in practice these materials are primarily viewed from a distance where they subtend less than 4° of the visual field.5.3 This test method is applicable to object-color specimens of any gloss level.5.4 Due to the retroreflective properties of these materials the colorimetric data may not be suitable for use in computer colorant formulation.5.5 This test method is suitable for quality control testing of fluorescent-retroreflective sheeting and marking materials.NOTE 1: Separation of the fluorescence and reflectance components from the total colorimetric properties provides useful and meaningful information to evaluate independently the luminescent and diffuse reflective efficiency and consistency of these materials.5.6 This test method is the referee method for determining the conformance of fluorescent-retroreflective sheeting and marking materials to standard daytime colorimetric specifications.1.1 This test method describes the instrumental measurement of the colorimetric properties (CIE tristimulus values, luminance factors, and chromaticity coordinates) of fluorescent-retroreflective sheeting and marking materials when illuminated by daylight.1.2 This test method is generally applicable to any sheeting or marking material having combined fluorescent and retroreflective properties used for daytime high visibility traffic control and personal safety applications.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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A lithium fluoride (LiF)-based photo-fluorescent film dosimetry system provides a means of determining absorbed dose to materials by the photo-stimulated emission of wavelengths longer than that of the stimulation wavelength. The absorbed dose is obtained from the amount of the light emission. Imperfections within the ionic lattice of alkali-halide compounds such as LiF act as traps for electrons and electron holes (positively charged negative-ion vacancies). These imperfections are known as color centers because of the part they play in the compound's ability to absorb and then release energy in the form of visible-light photons. Like an atom, these color centers have discrete, allowed energy levels, and electrons can be removed from these sites when energy of the appropriate wavelength and intensity is transferred to the material. The resulting fluorescence spectra contain discrete peaks that can cover a range of wavelengths, depending upon the type of alkali-halide (8). An example of fluorescence spectra from a LiF-based dosimeter is provided in Fig. 1. A system of optical filters within a light-detecting instrument (that is, fluorimeter) can be used to block all but a narrow range of wavelengths that are desired for use. Theories on how color centers are formed, how luminescence mechanisms work, and their application in dosimetry are found in Refs (8-13). For characterization studies on specific photo-fluorescent dosimeters see Refs (1-7) and (14-19).In the application of a specific dosimetry system, absorbed dose is determined by use of an experimentally-derived calibration curve. The calibration curve for the photo-fluorescent dosimeter is the functional relationship between ΔEf and D, and is determined by measuring the net fluorescence of sets of dosimeters irradiated to known absorbed doses. These absorbed doses span the range of utilization of the system.Photo-fluorescent dosimetry systems require calibration traceable to national standards. See ISO/ASTM Guide .The absorbed dose is usually specified relative to water. Absorbed dose in other materials may be determined by applying the conversion factors discussed in ISO/ASTM Guide .During calibration and use, possible effects of influence quantities such as temperature, light exposure, post-irradiation stabilization of signal, and absorbed-dose rate need to be taken into account.Photo-fluorescent dosimeters are sensitive to light, especially during irradiation and post-irradiation stabilization (7). Some color centers are sensitive to the UV and blue regions of the spectrum, while other centers are only sensitive to the UV. Therefore, they need to be packaged in appropriate light-tight packaging shortly after manufacture, and during use they need to be packaged or the appropriate filters placed over room lighting. Filtering the light fixtures involved during irradiation may be required for irradiations using low-energy X-rays or electrons where unpackaged dosimeters are used.The signal from photo-fluorescent dosimeters either increases or decreases with time following irradiation, depending on the color center utilized (19). This stabilization process, which can last from hours to days depending on storage temperature (and dose for some color centers) can be accelerated and stabilized by heat treating the dosimeters after irradiation and before readout (see 9.2).Note—Also shown are transmission curves for green and red emission filters.FIG. 1 Excitation Spectrum and Resulting Fluorescence Spectrum from the Sunna LiF-based Film Dosimeter1.1 This practice covers the handling, testing, and procedure for using a lithium fluoride (LiF)-based photo-fluorescent film dosimetry system to measure absorbed dose (relative to water) in materials irradiated by photons or electrons. Other alkali halides that may also exhibit photofluorescence (for example, NaCl, NaF, and KCl) are not covered in this practice. Although various alkali halides have been used for dosimetry for years utilizing thermoluminescence, the use of photoluminescence is relatively new.1.2 This practice applies to photo-fluorescent film dosimeters (referred hereafter as photo-fluorescent dosimeters) that can be used within part or all of the following ranges:1.2.1 Absorbed dose range of 5 × 10-2 to 3 × 102 kGy (1-3).1.2.2 Absorbed dose rate range of 0.3 to 2 × 104 Gy/s (2-5)).1.2.3 Radiation energy range for photons of 0.05 to 10 MeV (2).1.2.4 Radiation energy range for electrons of 0.1 to 10 MeV (2).1.2.5 Radiation temperature range of -20 to +60°C (6,7).1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 The determination of the total volume percent of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes. This information is also important in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of fuels, such as specified in Specification D1655.1.1 This test method covers the determination of hydrocarbon types of total aromatics, total olefins, and total saturates in petroleum fractions that distill below 315 °C. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.NOTE 1: For the determination of olefins below 0.3 % by volume, other test methods are available, such as Test Method D2710.1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315 °C limit. Such samples are not eluted properly, and results are erratic.1.3 This test method is also applicable to automotive spark-ignition engine fuels which are gasolines with and without blended oxygenates, such as alcohols and ethers (for example MTBE, ethanol) and where gasoline is the primary component by volume in the blend.1.4 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.1.5 This test method has two precision statements depicted in Table 3 and Table 4.1.5.1 Table 3 is applicable to fuels that do not contain oxygenated blending components over the test method concentration working ranges from 5 % to 99 % by volume aromatics, 1 % to 55 % by volume olefins, and 1 % to 95 % by volume saturates in petroleum fractions and with a final boiling point of <315 °C. It may or may not apply to automotive gasolines containing lead antiknock mixtures.1.5.2 Table 4 precision was derived from an ILS containing only blended oxygenated (for example, MTBE, ethanol) and non-oxygenated automotive spark-ignition engine fuels (gasolines) and is applicable only in the test method concentration working range of 13 % to 40 % by volume aromatics, 4 % to 33 % by volume olefins, and 45 % to 68 % by volume saturates.1.5.3 Non-oxygenated automotive spark-ignition engine fuels (gasolines) outside the inclusive valid test result reporting concentration ranges of Table 4 may use the precision in Table 3 and its applicable concentration ranges.1.6 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.1.7 This test method includes a relative bias section based on Practice D6708 accuracy assessment between Test Method D1319 and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test Method D1319 alternative to Test Method D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice D6708 derived correlation equation is only applicable for fuels in the total aromatic concentration range from 3.3 % to 34.4 % by volume as measured by Test Method D1319 and the distillation temperature T95, at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when tested according to Test Method D86.1.7.1 The applicable Test Method D5769 range for total aromatics is 3.7 % to 29.4 % by volume as reported by Test Method D5769 and the distillation temperature T95 values, at which 95 % of the sample has evaporated, when tested according to Test Method D86 is from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F).1.7.2 Regulations may change over time and the user is advised to verify current regulatory requirements.1.8 WARNING—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.1.9 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.10 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7, 8.1, and 10.5.1.11 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The test method is suitable for the development, specification and quality control testing of fluorescent and non-fluorescent coatings that are intended to be inspected for defects under Specification E2501 illumination.1.1 This test method covers the instrumental measurement of the luminance ratio of a fluorescent coating or sheet sample when illuminated by a narrow band source.1.2 This test method is generally applicable to any coating or sheeting material having combined fluorescent and reflective properties, where the fluorescence is activated by 405 nm light.1.3 This test method is intended as a companion to Specification E2501 to support the development and specification of industrial coatings that are used in a system for detection of coating defects when inspected with the Specification E2501 light source. This test method establishes a quantitative measure of the optical property of a coating that correlates to its ability to enhance defect contrast under the specified inspection light source.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 Liquid penetrant examination methods indicate the presence, location, and, to a limited extent, the nature and magnitude of the detected discontinuities. This practice is normally used for production examination of critical components or structures when (a) removal of excessive amounts of penetrant from discontinuities using a water-washable process can be a problem and (b) the use of a hydrophilic remover is impractical.1.1 This practice covers procedures for fluorescent liquid penetrant examination utilizing the lipophilic post-emulsification process. It is a nondestructive testing method for detecting discontinuities that are open to the surface such as cracks, seams, laps, cold shuts, laminations, through leaks, or lack of fusion and is applicable to in-process, final, and maintenance examination. It can be effectively used in the examination of nonporous, metallic materials, both ferrous and of nonmetallic materials such as glazed or fully densified ceramics and certain nonporous plastics and glass.1.2 This practice also provides a reference:1.2.1 By which a fluorescent liquid penetrant examination, lipophilic post-emulsification process recommended or required by individual organizations can be reviewed to ascertain its applicability and completeness.1.2.2 For use in the preparation of process specifications dealing with the fluorescent penetrant examination of materials and parts using the lipophilic post-emulsification process. Agreement by the purchaser and the manufacturer regarding specific techniques is strongly recommended.1.2.3 For use in the organization of the facilities and personnel concerned with the liquid penetrant examination.1.3 This practice does not indicate or suggest standards for evaluation of the indications obtained. It should be pointed out, however, that indications must be interpreted or classified and then evaluated. For this purpose there must be a separate code or specification or a specific agreement to define the type, size, location, and direction of indications considered acceptable, and those considered unacceptable.1.3.1 The user is encouraged to use materials and processing parameters necessary to detect conditions of a type or severity which could affect the evaluation of the product.1.4 Units—The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.5 All areas of this document may be open to agreement between the cognizant engineering organization and the supplier, or specific direction from the cognizant engineering organization.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Liquid penetrant testing methods indicate the presence, location, and, to a limited extent, the nature and magnitude of the detected discontinuities. This method is normally used for production inspection of large volumes of parts or structures, where emphasis is on productivity. The method enjoys a wide latitude in applicability when extensive and controlled conditions are available. Multiple levels of sensitivity can be achieved by proper selection of materials and variations in process.1.1 This practice2 covers procedures for water-washable fluorescent penetrant testing of materials. It is a nondestructive testing method for detecting discontinuities that are open to the surface such as cracks, seams, laps, cold shuts, laminations, isolated porosity, through leaks, or lack of porosity and is applicable to in-process, final, and maintenance examination. It can be effectively used in the examination of nonporous, metallic materials, both ferrous and nonferrous, and of nonmetallic materials such as glazed or fully densified ceramics and certain nonporous plastics and glass.1.2 This practice also provides a reference:1.2.1 By which a fluorescent penetrant testing method using the water-washable process recommended or required by individual organizations can be reviewed to ascertain its applicability and completeness.1.2.2 For use in the preparation of process specifications dealing with the water-washable fluorescent penetrant examination of materials and parts. Agreement by the purchaser and the manufacturer regarding specific techniques is strongly recommended.1.2.3 For use in the organization of the facilities and personnel concerned with the liquid penetrant testing.1.3 This practice does not indicate or suggest standards for evaluation of the indications obtained. It should be pointed out, however, that indications must be interpreted or classified and then evaluated. For this purpose there must be a separate code or specification or a specific agreement to define the type, size, location, and direction of indications considered acceptable, and those considered unacceptable.1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.5 All areas of this document may be open to agreement between the cognizant engineering organization and the supplier, or specific direction from the cognizant engineering organization (CEO).1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Liquid penetrant examination methods indicate the presence, location, and, to a limited extent, the nature and magnitude of the detected discontinuities. This practice is normally used for production examination of critical components, where reproducibility is essential. More procedural controls and processing steps are required than with other processes.1.1 This practice covers procedures for fluorescent penetrant examination utilizing the hydrophilic post-emulsification process. It is a nondestructive testing method for detecting discontinuities that are open to the surface such as cracks, seams, laps, cold shuts, laminations, isolated porosity, through leaks, or lack of fusion and is applicable to in-process, final, and maintenance examination. It can be effectively used in the examination of nonporous, metallic materials, both ferrous and nonferrous, and of nonmetallic materials such as glazed or fully densified ceramics and certain nonporous plastics and glass.1.2 This practice also provides a reference:1.2.1 By which a fluorescent penetrant examination hydrophilic post-emulsification process recommended or required by individual organizations can be reviewed to ascertain their applicability and completeness.1.2.2 For use in the preparation of process specifications dealing with the fluorescent penetrant examination of materials and parts using the hydrophilic post-emulsification process. Agreement by the purchaser and the manufacturer regarding specific techniques is strongly recommended.1.2.3 For use in the organization of the facilities and personnel concerned with the liquid penetrant examination.1.3 This practice does not indicate or suggest standards for evaluation of the indications obtained. It should be pointed out, however, that indications must be interpreted or classified and then evaluated. For this purpose there must be a separate code or specification or a specific agreement to define the type, size, location, and direction of indications considered acceptable, and those considered unacceptable.1.3.1 The user is encouraged to use materials and processing parameters necessary to detect conditions of a type or severity which could affect the evaluation of the product.1.4 Units—The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.5 All areas of this practice may be open to agreement between the cognizant engineering organization and the supplier, or specific direction from the cognizant engineering organization.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Liquid penetrant examination methods indicate the presence, location, and, to a limited extent, the nature and magnitude of the detected discontinuities. This practice is intended primarily for portability and for localized areas of examination, utilizing minimal equipment, when a higher level of sensitivity than can be achieved using visible process is required. Surface roughness may be a limiting factor. If so, an alternative process such as post-emulsified penetrant should be considered, when grinding or machining is not practical.1.1 This practice2 covers procedures for fluorescent penetrant examination utilizing the solvent-removable process. It is a nondestructive testing method for detecting discontinuities that are open to the surface, such as cracks, seams, laps, cold shuts, laminations, isolated porosity, through leaks, or lack of fusion and is applicable to in-process, final, and maintenance examination. It can be effectively used in the examination of nonporous, metallic materials, both ferrous and nonferrous, and of nonmetallic materials such as glazed or fully densified ceramics and certain nonporous plastics and glass.1.2 This practice also provides a reference:1.2.1 By which a fluorescent penetrant examination solvent-removable process recommended or required by individual organizations can be reviewed to ascertain its applicability and completeness.1.2.2 For use in the preparation of process specifications dealing with the fluorescent solvent-removable liquid penetrant examination of materials and parts. Agreement by the purchaser and the manufacturer regarding specific techniques is strongly recommended.1.2.3 For use in the organization of the facilities and personnel concerned with the liquid penetrant examination.1.3 This practice does not indicate or suggest standards for evaluation of the indications obtained. It should be pointed out, however, that indications must be interpreted or classified and then evaluated. For this purpose there must be a separate code or specification or a specific agreement to define the type, size, location, and direction of indications considered acceptable, and those considered unacceptable.1.3.1 The user is encouraged to use materials and processing parameters necessary to detect conditions of a type or severity which could affect the evaluation of the product.1.4 All areas of this document may be open to agreement between the cognizant engineering organization and the supplier, or specific direction from the cognizant engineering organization.1.5 Units—The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The most general method for obtaining CIE tristimulus values or, through their transformation, other coordinates for describing the colors of fluorescent objects is by the use of spectrometric data obtained under defined and controlled conditions of illumination and viewing. This practice describes the instrumental measurement requirements, calibration procedures, and material standards needed for measuring the total spectral radiance factors of fluorescent specimens illuminated by simulated daylight approximating CIE D65 and calculating total tristimulus values and total chromaticity coordinates for either the CIE 1931 or 1964 observers.5.2 The precise colorimetry of fluorescent specimens requires the spectral distribution of the instrument light source illuminating the specimen closely duplicate the colorimetric illuminant used for the calculation of tristimulus values, which is CIE D65 in this practice. The fundamental basis for this requirement follows from the defining property of a fluorescent specimen: instantaneous light emission resulting from electronic excitation by absorption of radiant energy (η) where the wavelengths of emission (λ) are as a rule longer than the excitation wavelengths (1).7 For a fluorescent specimen, the total spectral radiance factors used to calculate tristimulus values are the sum of two components – an ordinary reflectance factor, β(λ)S, and a fluorescence factor, β(η,λ)F : β(λ) = β(λ)S  + β(η,λ)F. Ordinary spectral reflectance factors are solely a function of the specimen's reflected radiance efficiency at the viewing wavelength (λ) and independent of the spectral distribution of the illumination. The values of the spectral fluorescent radiance factors at the viewing wavelength (λ) vary directly with the absolute spectral distribution of illumination within the excitation range (η), and consequently so will the total spectral radiance factors and derived colorimetric values. One-monochromator colorimetric spectrometers used in this practice are generally designed for the color measurement of ordinary (non-fluorescent) specimens and the precision with which they can measure the color of fluorescent specimens is directly dependent on how well the instrument illumination simulates CIE D65.5.3 CIE D65 is a virtual illuminant that numerically defines a standardized spectral illumination distribution for daylight and not a physical light source (2). There is no CIE recommendation for a standard source corresponding to CIE D65 nor is there a standardized method for rating the quality (or adequacy) of an instrument's simulation of CIE D65 for the general instrumental colorimetry of fluorescent specimens. The requirement that the instrument simulation of CIE D65 shall have a rating not worse than BB (CIELAB) as determined by the method of CIE Publication 51 has often been referenced. However, the method of CIE 51 is only suitable for ultraviolet-excited specimens evaluated for the CIE 1964 (10°) observer. The methods described in CIE 51 were developed for UV activated fluorescent whites and have not been proven to be applicable to visible-activated fluorescent specimens.NOTE 1: Aging of the instrument lamp will occur with normal usage resulting in changes in the spectral distribution and intensity of the illumination on the specimen over time. Measurement of the spectral distribution of the illumination at the sample port and evaluation of the adequacy of the CIE D65 simulation at regular intervals are recommended.5.4 Differences in the absolute spectral irradiance distribution on the specimen between instrument models can produce significant variation in the measured color values of fluorescent specimens and result in poor reproducibility (3). In order to reproduce adequately the spectral irradiance on the specimen required for maximum measurement reproducibility, it may be necessary for a single model of instrument to be specified for use by both buyer and seller.5.5 This practice is primarily for the instrumental color measurement of chromatic fluorescent specimens. While use of this practice for the color measurement of fluorescent whites is not precluded, other standards are more commonly used for measurement of these types of specimens (4, 5, 6) (see Test Methods D985, ISO 11475, ISO 2469, and TAPPI T 571).5.6 For geometrically sensitive fluorescent specimens angular tolerances on the axes and the angular aperture sizes must be well defined by the user to ensure adequate repeatability and reproducibility. Significant variation in measurement results for engineered surfaces and optical materials, for example retroreflective sheeting, can result from differences in the absolute axis angles of illumination and viewing and absolute size of the apertures between instruments (7). In order to replicate the measurement geometry, absolute angles and angular tolerances between instruments that is required for maximum measurement reproducibility, it may be necessary for a single model of instrument to be specified for use by both buyer and seller.NOTE 2: To ensure inter-instrument agreement in the measurement of specimens with intermediate gloss, for formulation, or retroreflective specimens, tight geometric tolerances are required of the instrument axis angles and the instrument aperture angles.5.7 Bidirectional (45:0 or 0:45) geometry is recommended for this practice.5.7.1 Hemispherical geometry using an integrating sphere is not recommended because of the spectral sphere error resulting from radiation emitted by the fluorescent specimen reflecting off the sphere wall and re-illuminating the specimen, thereby changing the spectral illuminance distribution on the specimen from that of the original instrument source (8).NOTE 3: The spectral sphere error associated with hemispherical geometry decreases as the ratio of the internal area of the sphere to the measurement area increases. When the spectral sphere error is negligible, results obtained using hemispherical geometry may for some specimens under specific measurement conditions approach those obtained using 45:0 geometry (9).5.8 This practice provides procedures for selecting the operating parameters of spectrometers used for providing data of the desired precision. It also provides for instrument calibration by means of artifact standards and selection of suitable specimens for obtaining precision in the measurements.5.9 Bispectral colorimetry using a bidirectional optical measuring system with a 45:0 or 0:45 illuminating and viewing geometry should be used when a high level of repeatability and reproducibility are required. The bispectral, or two-monochromator, method is the definitive method for the determination of the general radiation-transfer properties of fluorescent specimens. The bispectral method is accepted as the referee procedure for obtaining illuminant-independent photometric data on a fluorescent specimen that can be used to calculate its color for any desired illuminant and observer. The advantage of the bispectral method is that it avoids the inaccuracies associated with source simulation and various methods of approximation (10, 11) (see Practices E2152, E2153, and Test Method E2301).1.1 This practice applies to the instrumental color measurement of fluorescent specimens excited by near ultraviolet and visible radiation that results in fluorescent emission within the visible range. It is not intended for other types of photoluminescent materials such as phosphorescent, chemiluminescent, or electroluminescent, nor is this practice intended for the measurement of the fluorescent properties for chemical analysis.1.2 This practice describes the instrumental measurement requirements, calibration procedures, and material standards needed for the color measurement of fluorescent specimens when illuminated by simulated daylight approximating CIE Standard Illuminant D65 (CIE D65).1.3 This practice is limited in scope to colorimetric spectrometers providing continuous broadband polychromatic illumination of the specimen and employing only a viewing monochromator for analyzing the radiation leaving the specimen.1.4 This practice can be used for calculating total tristimulus values and total chromaticity coordinates for fluorescent colors in the CIE Color System for either the CIE 1931 Standard Colorimetric Observer or the CIE 1964 Supplementary Standard Colorimetric Observer.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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