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定价: 515 加购物车

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This specification is intended to provide a callout system for polyethylene utilizing specimen preparation procedures and test methods based primarily on ISO standards. The classification system provides for the identification of unfilled polyethylene plastics molding and extrusion materials, with a melt index of <1g/10 min, in such a manner that the supplier and the user agree on the acceptability of different commercial lots or shipments. The specification also lists the requirements that would allow for the use of recycled polyethylene materials. These requirements include the colour and form of the material.1.1 This classification system provides for the identification of unfilled polyethylene plastics molding and extrusion materials, with a melt index of <1g/10 min, in such a manner that the supplier and the user agree on the acceptability of different commercial lots or shipments. The tests involved in this specification are intended to provide information for identifying materials in accordance with the groups, classes, and grades covered. It is not the function of this classification system to provide specific engineering data for design purposes.1.2 This classification system allows for the use of recycled polyethylene materials provided that the requirements as stated in this classification system are met. The proportions of recycled material used, as well as the nature and amount of any contaminant, however, will not be covered in this specification.NOTE 1: See Guide D7209 for information and definitions related to recycled plastics.1.3 The properties included in this classification system are those required to identify the compositions covered. There may be other requirements necessary to identify particular characteristics important to specialized applications. These shall be agreed upon between the user and the supplier by using the suffixes given in Section 5.1.4 This classification system and subsequent line callout (specifications) are intended to provide a means of calling out plastic materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection should be made by those having expertise in the plastic field after careful consideration of the design and the performance requirements of the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent properties of the material other than those covered by this classification system.1.5 The values stated in SI units are regarded as the standard.1.6 The following precautionary caveat pertains to the test method portion only, Section 12 of this classification system. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.7 For information regarding plastic pipe materials, see Specification D3350. For information regarding wire and cable materials, see Specification D1248. For information regarding classification of PE molding and extrusion materials using ASTM test methods, see Specification D4976.NOTE 2: There is no known ISO equivalent to this standard.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

定价: 590 加购物车

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5.1 DOSS is an anionic detergent that is approved by the United States Food and Drug Administration (U.S. FDA) and is used widely as a laxative, emulsifying, solubilizing, and dispersing agent, and is used in the cosmetic industry.4 DOSS may also be used as a dispersing agent to treat oil. DOSS may be released into the environment at levels that may be harmful to aquatic life. The U.S. EPA aquatic life benchmark for DOSS is 40 ppb.55.2 This test method has been investigated for use with reagent and sea water.1.1 This test method covers the determination of dioctyl sulfosuccinate (DOSS) in sea water by direct injection using liquid chromatography (LC) and detection with tandem mass spectrometry (MS/MS). This analyte is qualitatively and quantitatively determined by this test method. This test method adheres to selected reaction monitoring (SRM) mass spectrometry.1.2 The detection verification level (DVL) and reporting range for DOSS are listed in Table 1.1.2.1 The DVL is required to be at a concentration at least 3 times below the reporting limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 and Fig. 2 display the signal/noise ratio of the selected reaction monitoring (SRM) transition.FIG. 1 Detection Verification Level Signal/Noise RatioFIG. 2 Reporting Level Signal/Noise Ratio1.2.2 The reporting limit is the concentration of the Level 1 calibration standard as shown in Table 5 for DOSS, taking into account the 50 % sample preparation dilution factor.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

定价: 646 加购物车

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5.1 This practice has been developed in support of the U.S. EPA Office of Water, Office of Science and Technology by the Chicago Regional Laboratory (CRL).5.2 Nonylphenol (NP) and Octylphenol (OP) have been shown to have toxic effects in aquatic organisms. The prominent source of NP and OP is from common commercial surfactants which are longer chain APEOs. The most widely used surfactant is nonylphenol polyethoxylate (NPnEO) which has an average ethoxylate chain length of nine. The APEOs are readily biodegraded to form NP1EO, NP2EO, nonylphenol carboxylate (NPEC) and NP. NP will also biodegrade, but may be released into environmental waters directly at trace levels. This practice screens for the longer chain APEOs which may enter the STP at elevated levels and may cause a STP to violate its permitted discharge concentration of nonylphenol.1.1 This practice covers the determination of nonylphenol polyethoxylates (NPnEO, 3 ≤ n ≤ 18) and octylphenol polyethoxylates (OPnEO, 2 ≤ n ≤ 12) in water by Single Reaction Monitoring (SRM) Liquid Chromatography/ Tandem Mass Spectrometry (LC/MS/MS) using direct injection liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS) detection. This is a screening practice with qualified quantitative data to check for the presence of longer chain ethoxylates in a water sample.1.1.1 All data are qualified because neat standards of each alkylphenol ethoxylate (APEO) are not available and the synthesis and characterization of these neat standards would be very expensive. The Igepal2 brand standards, which contain a mixture of various chain lengths of the alkylphenol ethoxylates (APEOs), were used. The mixture was characterized in-house assuming the instrument response at an optimum electrospray ionization cone and collision voltage for each APEO was the same. This assumption, which may not be accurate, is used to determine qualified amounts of each ethoxylate in the standards. The n-Nonylphenol diethoxylate (n-NP2EO) surrogate was available as a neat characterized standard, therefore, this concentration and recovery data was not estimated. APEOs are not regulated by the EPA, but nonylphenol, a breakdown product of NPnEOs, is regulated for fresh and saltwater dischargers. A request by a sewage treatment plant (STP) was made to make this practice available through ASTM in order to screen for the influent or effluent from sources of APEOs coming into the STP. The interest lies in stopping the source of the longer chain APEOs from entering the STP in order to meet effluent guidelines. Based upon the above, this is a practice rather than a test method. A comparison between samples is possible using this practice to determine which has a higher concentration of APEOs.1.2 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this practice.1.3 The estimated screening range shown in Table 1 was calculated from the concentration of the Level 1 and 7 calibration standards shown in Table 4. These numbers are qualified, as explained in Section 1, and must be reported as such. Figs. 1-5 show the SRM chromatograms of each analyte at the Level 1 concentration with the signal to noise (S/N) ratio. This is a screening practice and method detection limits are not given. The S/N ratio for each analyte at the Level 1 concentration must be at least 5:1 for adequate sensitivity. If the instrument can not meet the criteria, the screening limit must be raised to an acceptable level.FIG. 1 SRM Chromatograms NP3EO-NP8EOFIG. 2 SRM Chromatograms NP9EO-NP14EOFIG. 3 SRM Chromatograms NP15EO-NP18EO and n-NP2EOFIG. 4 SRM Chromatograms OP2EO-OP7EOFIG. 5 SRM Chromatograms OP8EO-OP12EO1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

定价: 646 加购物车

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定价: 515 加购物车

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