5.1 N-methylcarbamates and n-methylcarbomoyloximes are used in agriculture as insecticides and herbicides. They are sometimes found in both surface and ground waters and can be toxic to animals and plants at moderate to high concentrations. The manufacturing precursors and degradation products may be equally as hazardous to the environment.1.1 This is a high-performance liquid chromatographic (HPLC) test method applicable to the determination of certain n-methylcarbamoyloximes and n-methylcarbamates in ground water and finished drinking water (1).2 This test method is applicable to any carbamate analyte that can be hydrolyzed to a primary amine. The following compounds have been validated using this test method:Analyte Chemical Abstract ServicesRegistry Number A   Aldicarb       116-06-3   Aldicarb sulfone       1646-88-4   Aldicarb sulfoxide       1646-87-3   Baygon       114-26-1   Carbaryl       63-25-2   Carbofuran       1563-66-2   3-Hydroxycarbofuran       16655-82-6   Methiocarb       2032-65-7   Methomyl       16752-77-5   Oxamyl       23135-22-0(A) Numbering system of Chemical Abstracts, Inc.1.2 This test method has been validated in a collaborative round-robin study (2) and estimated detection limits (EDLs) have been determined for the analytes listed in 1.1 (Table 1). Observed detection limits may vary between ground waters, depending on the nature of interferences in the sample matrix and the specific instrumentation used.(A) Primary column—250 by 4.6 mm inside diameter Altex Ultrasphere ODS, 5 μm.(B) Confirmation column—250 by 4.6 mm inside diameter Supelco LC-1, 5 μm.(C) Estimated method detection limit in micrograms per litre.1.3 This test method is restricted to use by, or under the supervision of, analysts experienced in both the use of liquid chromatography and the interpretation of liquid chromatograms. Each analyst should demonstrate an ability to generate acceptable results with this test method using the procedure described in 12.3.1.4 When this test method is used to analyze unfamiliar samples for any or all of the analytes listed in 1.1, analyte identifications should be confirmed by at least one additional qualitative technique.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Additional guidance on laboratory safety is available and suitable references for the information are provided (3-5).1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The Clean Water Act promulgated the implementation of water quality standards and contamination limits for a wide range of pollutants including oil and grease. Specifically, the EPA, in 40 CFR Ch. 1, prohibits “the discharges of oil that cause a film or sheen upon or cause discoloration of the surface of the water. . .” Several state and local agencies have adopted this statement in addition to setting concentration limits, that is, 15 mg/L or even 5 mg/L. The purpose of this practice is to evaluate the performance of a separator in regards to the regulations and user requirements when subject to a sudden release. The sudden release may occur in dry weather and local personnel may attempt to hose the contaminated area down or it may occur on a rainy day and enter the separator mixed in with the runoff.5.2 This practice is not applicable if the influent to a separator is simply runoff from contaminated rainwater. For this case, see Practice D6104.5.3 This practice is not applicable if the influent to a separator is conveyed by a pumping means.1.1 This practice describes the testing procedure, any necessary related apparatus, and the sampling technique to be used in determining the performance characteristics of an oil/water separator subjected to the sudden release of a relatively large quantity of hydrocarbons that may appear in its influent in pure form or at high concentration.1.2 This practice does not address the determination of the performance characteristics of an oil/water separator subjected to surface run-off resulting from rain water draining from improved or unimproved land. In this case, refer to Practice D6104.1.3 This practice does not address the determination of the performance characteristics of an oil/water separator subjected to a mechanically emulsified influent such as provided by a pump.1.4 This practice does not investigate the ability of the separator to handle debris or suspended solids, that is, grit or tree leaves.1.5 While the effluent may meet code requirements for total oil and grease content, this practice does not address the presence of soluble organics, that is, benzene, toluene, ethyl-benzene, and xylene (BTEXs) that may be detected in the effluent. It also does not make any provisions for the effects of detergents, surfactants, soaps or any water soluble matter (that is, salts) or any portion of an essentially insoluble matter that may be found in solution on separation. (Effects of certain water soluble chemicals or solids may be investigated by adding them to the water at predetermined constant concentrations.)1.6 In order to estimate the effect of water temperature on the performance of the separator, the tests described in this practice must be performed at two water temperatures. The selected temperatures must be at least 10°C (18°F) apart, with the temperature ranging from a minimum of 0°C (32°F) to a maximum of 50°C (122°F).1.7 This practice does not make any provisions for the variation of pH or temperature during a test run. Refer to Appendix X1 for further detail.1.8 This practice can be used with a variety of hydrocarbons. It adopts No. 2 fuel oil with a density2 of 845 kg/m3 (52.73 lbm/ft3) and a viscosity2 of 1.9 to 4.1 centistokes at 40°C (104°F) and SAE 90 lubricating oil with a density (See SAE J313) of 930 kg/m3 (58 lbm/ft3) at 15.5°C (60°F) and a viscosity (see SAE J306) of 13.5 to <24 centistokes at 100°C (212°F) as the comparative testing media. It is understood that the results obtained from this practice are only directly applicable to No. 2 fuel oil and SAE 90 lubricating oil for the tested concentrations and only careful interpolation or extrapolation, or both, is allowed to other hydrocarbons. Low viscosity or high density hydrocarbons or hydrocarbons that contain a larger fraction of highly soluble compounds may need to be tested separately.NOTE 1: No extrapolation outside the range of the tested influent or effluent oil concentrations is allowed as performance may not be linear. Hence, to establish performance at a higher or lower concentration, the separator shall be tested for that specific condition. In addition, linearity must be established prior to using linear interpolation.1.9 Since regulations are based on effluent total hydrocarbon content, this practice does not set forth any lower limits on oil particle size for the evaluation of separator efficiency. However, a standardized means for mixing oil and water shall be specified to ensure repeatability. It must be noted however that smaller particles, having a greater surface area to volume ratio, rise at a slower rate than their larger counterparts. (Guide F933 requires that 20 % of all oil particles be smaller than or equal to 50 μm and IMO MEPC 60 (30) does not mention any particle size requirements but asks the user to avoid emulsion causing chemicals.)1.10 Although the tests described in this practice intend to simulate the performance of a separator subjected to a sudden release, they do not cover all possible applications. It is the end user's responsibility to determine whether his separation requirements are within the scope of this practice.1.11 A product different from the general description herein may be tested and found to be in compliance with the performance criteria set forth.1.12 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.1.13 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.14 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Lubricating oils can be formulated with additives, which can act as detergents, anti-oxidants, anti-wear agents, and so forth. Some additives can contain one or more of calcium, copper, magnesium, phosphorus, sulfur, and zinc. This test method can be used to determine if the oils, additives, and additive packages meet specification with respect to content of these elements.4.2 Several additive elements and their compounds are added to the lubricating oils to give beneficial performance (Table 3).4.3 This test method can also be used to determine if lubricating oils, additives, and additive packages meet specification with respect to chlorine concentration. In this context, specification can refer to contamination.4.4 This test method is not intended for use on samples that contain some component that significantly interferes with the analysis of the elements specified in the scope.4.5 This test method can complement other test methods for lube oils and additives, including Test Methods D4628, D4927, D4951, and D5185.1.1 This test method covers the determination of calcium, chlorine, copper, magnesium, phosphorus, sulfur, and zinc in unused lubricating oils, additives, and additive packages by wavelength dispersive X-ray fluorescence spectrometry. Matrix effects are handled with mathematical corrections.1.2 For each element, the upper limit of the concentration range covered by this test method is defined by the highest concentration listed in Table 1. Samples containing higher concentrations can be analyzed following dilution.1.3 For each element, the lower limit of the concentration range covered by this test method can be estimated by the limit of detection (LOD)2 (see also 40 CFR 136 Appendix B) or limit of quantification (LOQ),2 both of which can be estimated from Sr, the repeatability standard deviation. LOD and LOQ values, determined from results obtained in the interlaboratory study on precision, are listed in Table 2.1.3.1 LOD and LOQ are not intrinsic constants of this test method. LOD and LOQ depend upon the precision attainable by a laboratory when using this test method.1.4 This test method uses regression software to determine calibration parameters, which can include influence coefficients (that is, interelement effect coefficients) (Guide E1361), herein referenced as alphas. Alphas can also be determined from theory using relevant software.1.5 Setup of this test method is intended for persons trained in the practice of X-ray spectrometry. Following setup, this test method can be used routinely.1.6 The values stated in either SI units or angstrom (Å) units are to be regarded separately as standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Cation conductivity provides one of the most sensitive and dependable on-line means of detecting anionic contamination in the boiler/steam cycle, such as chlorides, sulfates, nitrates, bicarbonates, and organic acids, such as formic and acetic.5.2 High sensitivity is provided by intentionally eliminating the pH adjusting treatment chemical(s), for example, ammonia and amines, from the sample and converting remaining salt contaminants into their acid forms which are approximately three times as conductive.5.3 Guidelines on cation conductivity limits for various cycle chemistry and boiler types have been established by EPRI (2-4) and by ASME (5 and 6).5.4 The sample effluent from the cation exchange column also may be used, and in some cases is preferred, for ion chromatography or other anion measurements.1.1 This practice describes continuous sample conditioning by hydrogen ion exchange and measurement by electrolytic conductivity. It is commonly known as cation conductivity measurement in the power industry although it is actually an indication of anion contamination in high purity water samples. Measurements are typically in a range less than 1 μS/cm.1.2 The actual conductivity measurements are made using Test Method D5391.1.3 This practice does not provide for separate determination of dissolved carbon dioxide. Refer to Test Method D4519.1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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