Separation and identification of stabilizers used in the manufacture of HDPE are necessary in order to correlate performance properties with polymer composition. This test method provides a means of determining BHT, BHEB, Isonox 129, Irganox 1010, and Irganox 1076 levels in HDPE samples. This test method should be applicable for the determination of other antioxidants such as Cyanox 425, Cyanox 1790, Cyanox 2246, Ultranox 236, and Ultranox 246, but the applicability of this test method has not been investigated for these antioxidants. The additive-extraction procedure is made effective by the insolubility of the polymer sample in solvents generally used for liquid chromatographic analysis. The lowest level of detection for a phenolic antioxidant is approximately 2 ppm under optimum conditions. Other procedures that have been used successfully to remove additives from the plastics matrix include thin-film, microwave,10 ultrasonic,11 and supercritical fluid extractions.11 , 12 , 13 Procedures other than HPLC have been used successfully to separate additives, including SFC13 and capillary GC.14 1.1 This test method covers a liquid-chromatographic procedure for the separation of some additives currently used in high-density polyethylene. These additives are extracted with cyclohexane prior to liquid-chromatographic separation. The ultraviolet absorbance (200 nm) of the compound(s) is measured; quantitation is performed using the internal standard method. Note 1—There is no similar or equivalent ISO standard. 1.2 The values stated in SI units are to be regarded as the standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 9.
1.1 This provisional test method covers the determination of maximum specific gravity of loose bituminous mixtures, as defined in Terminology E 1547, by the vacuum sealing method.1.2 This method can be used with 100 and 150 mm diameter compacted bituminous laboratory and field specimens.1.3 The bulk specific gravity of the compacted bituminous mixtures may be used in calculating the unit weight of the mixture.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.Note 1—Provisional standards require only subcommittee consensus and are published for a limited time of two years. The provisional process was used because of the immediate need for this method to be used in testing pavement mixtures with open graded design, mixtures that readily absorb water and mixtures that allow water to rapidly penetrate and drain out.
1.1 This provisional test method covers the determination of maximum specific gravity of and density of uncompacted bituminous paving mixtures at 25°C (77°F).1.2 The values stated in SI units are to be regarded as the standard. The other units given may be approximate and are given to help the user interpret units on available standard equipment used with this provisional test method.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.Note 1—Provisional standards require only subcommittee consensus and are published for a limited time of two years. The provisional process was used because agencies and private organizations have an immediate need for a method that will save time and accurately reduce water absorption by absorptive mixes, eliminating the need for post vacuum "dry back" correction and stripping. This method provides a quick way to test loose bitminous mixtures for maximum specific gravity.
Separation and identification of stabilizers used in the manufacture of linear low-density polyethylene are necessary in order to correlate performance properties with polymer composition. This test method provides a means to determine BHT, BHEB, Isonox 129, erucamide slip, Irganox 1010, and Irganox 1076 levels in linear low-density polyethylene samples. This test method should be applicable for the determination of other antioxidants such as Ultranox 626, Ethanox 330, Santanox R, and Topanol CA, but the applicability of this test method has not been investigated for these antioxidants.The additive extraction procedure is made effective by the insolubility of the polymer sample in solvents generally used for liquid chromatographic analysis.Under optimum conditions, the lowest level of detection for a phenolic antioxidant is approximately 2 ppm.Other methods that have been successfully used to remove additives from the plastics matrix include thin film, microwave, ultrasonic, and supercritical fluid extractions. Other methods have been successfully used to separate additive including SFC and GC.1.1 This test method covers a liquid-chromatographic procedure for the separation of some additives currently used in linear low-density polyethylene. These additives are extracted with either isobutanol or isopropanol prior to liquid-chromatographic separation. The ultraviolet absorbance (200 nm) of the compound(s) is measured; quantitation is performed using the internal standard method.1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 9.Note 1—There is no equivalent ISO standard.
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