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5.1 Latex paints, alkyd paints, and primers are used as coatings for walls, wooden trim, and furnishings in occupied buildings. Paint may be applied to large surface areas and may be applied repeatedly during the lifetime of a building. VOCs are emitted from paint after application to surfaces.5.2 Many other types of architectural coatings may be used in large quantities indoors in buildings. In particular, many different types of coatings are used for floors including wood floor stains and finishes and concrete sealers, hardeners, and stains. Two component finishes are often mixed on site and are applied to floors and other surfaces to create a finished surface.5.3 There is a need for standardized procedures for measuring the emissions of VOCs from paint and coating samples that can be reproduced by different laboratories and that can used for the assessment of the acceptability of VOC emissions from paints and coatings that are intended for use indoors in occupied spaces. This practice describes standardized procedures that can be incorporated into test methods used for the purpose of estimating the impacts of cured paints and coatings on indoor air quality. Different procedures are required for the estimation of VOC exposures to workers applying such products.1.1 This practice describes procedures for testing the emissions of volatile organic compounds (VOCs), formaldehyde, and other carbonyl compounds, from alkyd paint, latex paint, primer, and other architectural coating samples using a small-scale environmental chamber test facility.1.2 This practice describes the requirements for the chamber test facility, the small-scale test chamber, the clean air supply system, the environmental controls, the environmental monitoring and data acquisition system, and the chamber air sampling system.1.3 This practice describes procedures for documenting the paint and coating samples and for the handling and storage of these samples including splitting of samples into smaller containers for storage and subsequent testing.1.4 This practice identifies appropriate substrates to be used for the preparation of test specimens of paints and coatings, as well as procedures for preparing substrates for use.1.5 This practice provides detailed procedures for preparing test specimens of paint and coating samples.1.6 This practice generally describes chamber test procedures and chamber air sampling procedures. The details of these procedures are dependent upon the objectives of the test.1.7 This practice does not recommend specific methods for sampling and analysis of VOCs, formaldehyde, and other carbonyl compounds. The appropriate methods are dependent upon the objectives of the test.1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This specification covers requirements, test methods, materials, and marking for polyethylene (PE), open bottom, buried arch-shaped chambers of corrugated wall construction used for collection, detention, and retention of stormwater runoff. These collection chambers can be used as commercial, residential, agricultural, and highway drainage, including installation under parking lots and roadways. This specification indicates the classifications, tolerances, and dimensions of the chambers. It also lists the test methods that examine the physical and mechanical properties of finished chambers.1.1 This specification covers requirements, test methods, materials, and marking for polyethylene (PE), open bottom, buried arch-shaped chambers of corrugated wall construction used for collection, detention, and retention of stormwater runoff. Applications include commercial, residential, agricultural, and highway drainage, including installation under parking lots and roadways.1.2 Chambers are produced in arch shapes with dimensions based on chamber rise, chamber span, and wall stiffness. Chambers are manufactured with integral feet that provide base support. Chambers may include perforations to enhance water flow. Chambers must meet test requirements for arch stiffness, flattening, and accelerated weathering.1.3 Analysis and experience have shown that the successful performance of this product depends upon the type and depth of bedding and backfill, and care in installation. This specification includes requirements for the manufacturer to provide chamber installation instructions to the purchaser.1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.5 The following safety hazards caveat pertains only to the test method portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Corrosion film growth with thicknesses varying from a monolayer of atoms up to 1 μm can readily be measured on a continuous, real-time, in-situ, basis with QCMs.4.2 The test results obtained for this test method are influenced by various factors, including geometrical effects, temperature, humidity, film thickness, film materials, electrode conditions, gases in the corrosion chamber, atmospheric pressure, and so forth. Calibration of coated crystals and instrumentation and reproducible crystal operating conditions are necessary for consistent results.1.1 This test method monitors the reactivity of a gaseous test environment in which metal surfaces (for example, electrical contacts, assembled printed wiring boards, and so forth) and other materials subject to pollutant gas attack undergo accelerated atmospheric corrosion testing. This test method is applicable to the growth of adherent corrosion films whose total corrosion film thickness ranges from a few atomic monolayers to approximately a micrometre.1.2 The test method provides a dynamic, continuous, in-situ, procedure for monitoring the corrosion rate in corrosion chambers; the uniformity of corrosion chambers; and the corrosion rate on different surfaces. Response time in the order of seconds is possible.1.3 With the proper samples, the quartz crystal microbalance (QCM) test method can also be used to monitor the weight loss from a surface as a result of the desorption of surface species (that is, reduction of an oxide in a reducing atmosphere). (Alternative names for QCM are quartz crystal oscillator, piezoelectric crystal oscillator, or thin-film evaporation monitor.)1.4 This test method is not sufficient to specify the corrosion process that may be occurring in a chamber, since a variety of pollutant gases and environments may cause similar weight gains.1.5 This test method is generally not applicable to test environments in which solid or liquid particles are deposited on the surface of the quartz crystal.1.6 The values stated in SI units are to be regarded as standard. The values in parentheses are for information only.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Electrical devices that contain electrical contacts generally contain some copper-based materials. Atmospheric corrosion of copper parts in such devices often occurs in service environments. A quantitative measure of the effect of a laboratory corrosion test on copper permits assessment of the severity of the test. In addition, corrosion tests may be defined in terms of their effect on copper; this test method provides a way of comparing one test against a standard defined elsewhere, or allows a comparison of the performance of a test over a period of time. Although this test method provides for a relatively simple check of a test, the user is advised that additional analysis of the test chamber ambient is generally required to reproduce test conditions.4.2 Atmospheric corrosion tests are used on a variety of materials besides copper. Care should be exercised in drawing conclusions about the effects on such materials of apparently equivalent tests if the composition of gases or experimental conditions are different. The primary use of this calibration test method is to assure correlation among nominally identical tests.1.1 This test method covers the calibration of atmospheric corrosion test chambers for electrical contacts that produce an adherent film of corrosion product on copper, such as a test comprised of a mixture of flowing gases that react with copper.1.2 This test method is not applicable to tests where corrosion products may be removed from a copper surface during the test by fluids.1.3 This test method is not applicable to tests where airborne solid or liquid material may be deposited on a copper surface during the test, as in a test which includes particulates suspended in the atmosphere.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to become familiar with all hazards including those identified in the appropriate Safety Data Sheet (SDS) for this product/material as provided by the manufacturer, to establish appropriate safety, health, and environmental practices, and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Manufacturers of SPF insulation may need to test their products for vapor-phase emissions of volatile and semi-volatile organic compounds in order to comply with voluntary standards, purchase specifications, or other requirements.5.2 Since SPF insulation is formed by chemical reaction when combining a two-component mixture during spraying, specialized equipment and procedures are needed to reproducibly create representative samples suitable for emission testing.5.3 SPF insulation product manufacturer’s specifications and instructions must be followed carefully and detailed information regarding the spraying process must be recorded (see 7.3). Other precautions regarding handling and shipping are needed to ensure that the chemical integrity of the samples is preserved to the extent possible by practical means (see 7.5).5.4 Laboratories must prepare representative test specimens from samples of SPF insulation in a consistent manner so that emission tests can be reproduced and reliable comparisons can be made between test data for different samples.1.1 This practice describes standardized procedures for the preparation, spraying, packaging, and shipping of fresh spray polyurethane foam (SPF) insulation product samples to be tested for their emissions of volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs). These procedures are applicable to both closed-cell and open-cell SPF insulation products. Potential chemical emissions of interest include blowing agents, solvents, aldehydes, amine catalysts, diisocyanates, and flame retardants.1.2 Typically, SPF insulation samples are prepared at one location, such as a chemical manufacturing facility or a field product installation site. The newly prepared samples are preserved in a sealed bag, placed in a secondary container, and then shipped to a laboratory for testing.1.3 The spraying of SPF insulation products is only to be performed by trained individuals using professional spraying equipment under controlled conditions. The details of the spraying equipment and spraying procedures are based on industry practice and are outside of the scope of this practice.1.4 This practice also describes procedures for the laboratory preparation of test specimens from open-cell and closed-cell SPF insulation product samples. These specimens are prepared for testing in small-scale chambers following Guide D5116 and in micro-scale chambers that are described in Test Method D8142.1.5 Procedures for VOC and SVOC emission testing, gas sample collection and chemical analysis are outside of the scope of this practice. Such procedures will need to address the potential for emissions of some SVOCs, for example, amine catalysts, flame retardant and isocyanates, to adhere to the chamber walls.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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1.1 This specification covers requirements, test methods, materials, and marking for closed-cell cellular polypropylene (PP), open bottom, buried chambers of corrugated wall construction used for collection, detention, and retention of stormwater runoff. Applications include commercial, residential, agricultural, and highway drainage, including installation under parking lots and roadways.1.2 Chambers are produced in arch shapes with dimensions based on chamber rise, chamber span, and wall stiffness. Chambers are manufactured with integral feet that provide base support. Perforations to enhance water flow are permitted. Chambers must meet test requirements for arch stiffness, and flattening. Chamber end caps shall be produced of PP or polyethylene (PE) by a suitable manufacturing process provided that all other product requirements in this standard are met.1.3 Analysis and experience have shown that the successful performance of this product depends upon the type and depth of bedding and backfill, and care in installation. This specification includes requirements for the manufacturer to provide chamber installation instructions to the purchaser.1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.5 This standard does not purport to address water quality issues or hydraulic performance requirements associated with its use. It is the responsibility of the user to ensure that appropriate engineering analysis is performed to evaluate the water quality issues and hydraulic performance requirements for each installation.1.6 The following safety hazards caveat pertains only to the test method portion, Section 6, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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6.1 SPF insulation is applied and formed onsite, which creates unique challenges for measuring product emissions. This test method provides a way to measure post-application chemical emissions from SPF insulation.6.2 This test method can be used to identify compounds that emit from SPF insulation products, and the emission factors may be used to compare emissions at the specified sampling times and test conditions.6.3 Emission data may be used in product development, manufacturing quality control and comparison of field samples.6.4 This test method is used to determine chemical emissions from freshly applied SPF insulation samples. The utility of this test method for investigation of odors in building scale environments has not been demonstrated at this time.1.1 This test method is used to identify and to measure the emissions of volatile organic compounds (VOCs) emitted from samples of cured spray polyurethane foam (SPF) insulation using micro-scale environmental test chambers combined with specific air sampling and analytical methods for VOCs.1.2 Specimens prepared from product samples are maintained at specified conditions of temperature, humidity, airflow rate, and elapsed time in micro-scale chambers that are described in Practice D7706. Air samples are collected periodically at the chamber exhaust at the flow rate of the micro-scale chambers.1.2.1 Samples for formaldehyde and other low-molecular weight carbonyl compounds are collected on treated silica gel cartridges and are analyzed by high performance liquid chromatography (HPLC) as described in Test Method D5197 and ISO 16000-3.1.2.2 Samples for other VOCs are collected on multi-sorbent samplers and are analyzed by thermal-desorption gas chromatography / mass spectrometry (TD-GC/MS) as described in U.S. EPA Compendium Method TO-17 and ISO 16000-6.1.3 This test method is intended specifically for SPF insulation products. Compatible product types include two component, high pressure and two-component, low pressure formulations of open-cell and closed-cell SPF insulation.1.4 VOCs that can be sampled and analyzed by this test method generally include organic blowing agents such as 1,1,1,3,3-pentafluoropropane, formaldehyde and other carbonyl compounds, residual solvents, and some amine catalysts. Emissions of some organic flame retardants can be measured after 24 h with this method, such as tris (chloroisopropyl) phosphate (TCPP).1.5 This test method does not cover the sampling and analysis of methylene diphenyl diisocyanate (MDI) or other isocyanates.1.6 Area-specific and mass-specific emission rates are quantified at the elapsed times and chamber conditions as specified in 13.2 and 13.3 of this test method.1.7 This test method is used to identify emitted compounds and to estimate their emission factors at specific times. The emission factors are based on specified conditions, therefore, use of the data to predict emissions in other environments may not be appropriate and is beyond the scope of this test method. The results may not be representative of other test conditions or comparable with other test methods.1.8 This test method is primarily intended for freshly applied, SPF insulation samples that are sprayed and packaged as described in Practice D7859. The measurement of emissions during spray application and within the first hour following application is outside of the scope of this test method.1.9 This test method can also be used to measure the emissions from SPF insulation samples that are collected from building sites where the insulation has already been applied. Potential uses of such measurements include investigations of odor complaints after product application. However, the specific details of odor investigations and other indoor air quality (IAQ) investigations are outside of the scope of this test method.1.10 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.11 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.12 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 A tiered strategy for characterization of nanoparticle properties is necessary to draw meaningful conclusions concerning dose-response relationships observed during inhalation toxicology experiments. This tiered strategy includes characterization of nanoparticles as produced (that is, measured as the bulk material sold by the supplier) and as administered (that is, measured at the point of delivery to a test subject) (Oberdorster et al. (6)).5.2 Test Methods B922 and C1274 and ISO 9277 and ISO 18757 exist for determination of the as produced surface area of bulk metal and metal oxide powders. During the delivery of nanoparticles in inhalation exposure chambers, the material properties may undergo change and therefore have properties that differ from the material as produced. This test method describes the determination of the as administered surface area of airborne metal oxide nanoparticles in inhalation exposure chambers for inhalation toxicology studies.1.1 This test method covers determination of surface area of airborne metal oxide nanoparticles in inhalation exposure chambers for inhalation toxicology studies. Surface area may be measured by gas adsorption methods using adsorbates such as nitrogen, krypton, and argon (Brunauer et al. (1),2 Anderson (2), Gregg and Sing (3)) or by ion attachment and mobility-based methods (Ku and Maynard (4)). This test method is specific to the measurement of surface area by gas adsorption by krypton gas adsorption. The test method permits the use of any modern commercial krypton adsorption instruments but strictly defines the sample collection, outgassing, and analysis procedures for metal and metal oxide nanoparticles. Use of krypton is required due to the low overall surface area of particle-laden samples and the need to accurately measure the background surface area of the filter used for sample collection. Instrument-reported values of surface area based on the multipoint Brunauer, Emmett and Teller (BET) equation (Brunauer et al. (1), Anderson (2), Gregg and Sing (3)) are used to calculate surface area of airborne nanoparticles collected on a filter.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. State all numerical values in terms of SI units unless specific instrumentation software reports surface area using alternate units.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 The static chambers have several different applications:4.1.1 The static chambers can be used to compare the susceptibility of different materials to the colonization and amplification of various microorganisms under defined conditions.4.1.2 Chambers operated at high relative humidities may be used to perform worst case scenario screening tests on materials by providing an atmosphere where environmental conditions may be favorable for microbial growth.4.1.3 Use of multiple chambers with different environmental parameters, such as a range of relative humidities, permits the evaluation of multiple microenvironments and allows investigation of materials under differing environmental conditions.4.1.4 Drying requirements for wetted materials may also be investigated. This information may be relevant for determining material resistance to microbial growth after becoming wet. These conditions may simulate those where materials are subjected to water incursion through leaks as well as during remediation of a building after a fire.4.1.5 Growth rates of microorganisms on the material may also be investigated. Once it has been established that organisms are able to grow on a particular material under defined conditions, investigations into the rate of organism growth may be performed. These evaluations provide base line information and can be used to evaluate methods to limit or contain amplification of microorganisms.4.2 These techniques should be performed by personnel with training in microbiology. The individual must be competent in the use of sterile technique, which is critical to exclude external contamination of materials.1.1 Many different types of microorganisms (for example, bacteria, fungi, viruses, algae) can occupy indoor spaces. Materials that support microbial growth are potential indoor sources of biocontaminants (for example, spores and toxins) that can become airborne indoor biopollutants. This guide describes a simple, relatively cost effective approach to evaluating the ability of a variety of materials to support microbial growth using a small chamber method.1.2 This guide is intended to assist groups in the development of specific test methods for a definite material or groups of materials.1.3 Static chambers have certain limitations. Usually, only small samples of indoor materials can be evaluated. Care must be taken that these samples are representative of the materials being tested so that a true evaluation of the material is performed.1.4 Static chambers provide controlled laboratory microenvironment conditions. These chambers are not intended to duplicate room conditions, and care must be taken when interpreting the results. Static chambers are not a substitute for dynamic chambers or field studies.1.5 A variety of microorganisms, specifically bacteria and fungi, can be evaluated using these chambers. This guide is not intended to provide human health effect data. However, organisms of clinical interest, such as those described as potentially allergenic, may be studied using this approach.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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