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5.1 Manufacturers of carpet need to monitor emissions of VOCs to assess the environmental impact of their products indoors. These results are also used to demonstrate compliance with VOC emission limits for individual VOCs.5.2 These data are also used to understand which VOCs are emitted from a product or material and to measure the magnitude of those emissions.5.3 Emission data may be used to compare different lots of carpet of the same materials of construction, or carpets composed of different materials of construction, in order to develop products with lower emissions and lower potential environmental impact.5.4 This test method should be used in conjunction with practices/guidelines for emissions testing such as Guide D5116, Practice D7143, Practice D7706, ISO 16000-9, and ISO 16000-10. These detail how to select and prepare samples and how and when to carry out emissions tests such that the concentration and profile of vapors in the exhaust air of the emission chamber/cell are representative of the product under test. This test method covers the sampling and analysis of volatile organic compounds in the exhaust gas from the chamber/cell using thermal desorption—compatible sorbent tubes and will provide the necessary analytical consistency to ensure that reproducible data is obtained for the analysis of identical vapor samples by different laboratories.1.1 This test method describes an analytical procedure for identifying and quantifying the masses of individual volatile organic compounds (individual VOCs or IVOCs) that are emitted into a flow of air from carpet specimens and collected on sorbent sampling tubes during emissions testing.1.2 This test method will be used in conjunction with a standard practice for sampling and preparing carpet specimens for emissions testing. If a specific chamber practice is not available for the carpet specimens, this test method should be used in conjunction with approved standard practices for emissions testing and sample preparation.1.3 When used in conjunction with standard practices for carpet specimen preparation and collection of vapor-phase emissions , this test method will provide a standardized means of determining the levels of IVOC in the exhaust stream of the emissions test chamber/cell. If this test method is used with a reliable practice for emissions testing, these IVOC levels can be used to determine the emission rate from a unit quantity (usually surface area) of the sample material under test.1.4 VOCs in the exhaust stream of an emissions test device are collected on thermal desorption tubes packed with a specific combination of sorbents using active (pumped) sampling. (See Practice D6196 for a more general description of vapor collection using pumped sampling onto sorbent tubes.) The samples are analyzed by thermal desorption (TD) with gas chromatography and mass spectrometry detection (GC/MS) and/or flame ionization detection (FID) depending upon the requirements of the specific materials emissions testing/certification protocol.1.5 This test method can be used for the measurement of most GC-compatible organic vapors ranging from the approximate volatility from n-hexane to n-hexadecane (that is, compounds with vapor pressures ranging from 16 kPa to 4 × 10-4 kPa at 25°C). Properties other than a compound’s vapor pressure such as affinity for the sorbent may need to be taken into account. Compounds with vapor pressures outside this range may or may not be quantifiable by this test method. However, qualitative data concerning the identity of a compound(s), outside the stated volatility range for quantitation, may still be useful to the user. This test method can be applied to analytes over a wide concentration range—typically 1 μg/m3 to 1 mg/m3 concentration of vapor in the exhaust air from the emission cell or chamber.1.6 This test method is not capable of quantifying all compounds which are emitted from carpets. See the appropriate test practices/methods for determining other compounds that are not amenable to analysis by gas chromatography (that is, Test Method D5197 for the determination of aldehydes).1.7 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Purgeable organic compounds, including organohalides, have been identified as contaminants in raw and drinking water. These contaminants may be harmful to the environment and man. Dynamic headspace sampling is a generally applicable method for concentrating these components prior to gas chromatographic analysis (1-5).3 This test method can be used to quantitatively determine purgeable organic compounds in raw source water, drinking water, and treated effluent water.1.1 This test method covers the determination of most purgeable organic compounds that boil below 200°C and are less than 2 % soluble in water. It covers the low μg/L to low mg/L concentration range (see Section 15 and Appendix X1).1.2 This test method was developed for the analysis of drinking water. It is also applicable to many environmental and waste waters when validation, consisting of recovering known concentrations of compounds of interest added to representative matrices, is included.1.3 Volatile organic compounds in water at concentrations above 1000 μg/L may be determined by direct aqueous injection in accordance with Practice D2908.1.4 It is the user's responsibility to assure the validity of the test method for untested matrices.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 8.5.5.1.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Free films are required for conducting tests to evaluate physical and mechanical properties such as tensile and elongation (Test Methods D2370), moisture vapor permeability (Test Methods D1653 and E96/E96M), microbiological activity resistance (Test Method D5590), and other physical properties of organic coatings where the substrate may interfere with the determination.1.1 This practice covers the preparation of free films of organic coatings for use in determining the physical properties of the coatings.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Low operating temperature fuel cells such as PEMFCs require high purity hydrogen for optimal performance and longevity. Organic halides and formaldehyde can react with catalyst in PEMs and non-methane hydrocarbons degrade PEM stack performance.1.1 The gas chromatography/mass spectrometry (GC/MS) procedure described in this test method is used to determine concentrations of total organic halides and total non-methane hydrocarbons (TNMHC) in hydrogen by measurement of individual target halocarbons (Table 1) and hydrocarbons (including formaldehyde, Table 1 and Table 2), respectively.1.2 Mention of trade names in this test method does not constitute endorsement or recommendation for use. Other manufacturers’ equipment or equipment models can be used.1.3 Units—The values stated in SI units are to be regarded as standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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