5.1 The test is designed to quantify the amount of dust control material added to calcined coke. The dust control material is applied to calcined coke to help maintain a dust-free environment. It generally serves no other useful purpose. It adds mass to the coke and can have a negative effect on the quality of carbon and graphite artifacts made from the treated coke. For these reasons the coke customer wants to know the amount of dust control material on the coke and can specify a maximum level.1.1 This test method covers the determination of the amount of material applied to calcined coke to control dust associated with coke handling and transportation.1.2 This test method is limited to those materials that are soluble in a solvent that can be used in a Soxhlet extraction type of apparatus such as methylene chloride (dichloro-methane).NOTE 1: Methylene chloride is the most popular solvent for removing dust control oil at the time this procedure is being written. Toluene and methyl chloroform, however, have been used with equal results on all cokes tested which have included only those sprayed with aromatic or waxy materials.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 The determination of the volume percent of the textural components in coke is useful to characterize the optical properties of coke as it relates to utilization. Specifically, the technique has been used as an aid in determining coal blend proportions, and recognition of features present in the coke that can be responsible for coke quality or production problems such as reduced coke strength or difficulty in removing coke from commercial coke ovens, or both. The study of coke textures is also useful in promoting a better understanding of coke reactivity, and the relationship between coal petrography and its conversion to coke.55.2 This test method is used in scientific and industrial research, but not for compliance or referee tests.1.1 This test method covers the equipment and procedures used for determining the types and amounts of coke carbon forms and associated recognizable coal- and process-derived textural components in metallurgical coke in terms of volume percent. This test method does not include coke structural components such as coke pores, coke wall dimensions, or other structural associations.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 Moisture, as determined by this instrumental test method, is used for calculating other analytical results to a dry basis using procedures in Practice D3180.5.2 Moisture can be used in conjunction with the air-dry moisture loss determined by Test Method D3302 to determine total moisture in coal. Total moisture is used for calculating other analytical results to an as-received basis using Practice D3180.5.3 Ash yield is the residue remaining after heating the coal and coke samples (see Note 1).NOTE 1: The ash obtained differs in composition and amount from the mineral constituents present in the original coal. Combustion causes an expulsion of all water, the loss of carbon dioxide from carbonates, the conversion of iron pyrite into iron oxides and sulfur oxides, and other chemical reactions. Ash yield, as determined by this test method, can differ from the amount of ash produced in furnace operations or other combustion systems because combustion conditions influence the chemistry and amount of ash.5.4 Ash yield is used, (1) as a parameter for evaluating sampling procedures and coal cleaning processes, (2) in the ultimate analysis calculation of oxygen by difference using Practice D3176, (3) in calculations including material balance, reactivity and yields of products relevant to coal conversion processes such as gasification and liquefaction, (4) in calculations to estimate the loading on electrostatic precipitators and on the fly ash and bottom ash disposal systems as well as erosion rates on boiler systems.5.5 Volatile matter yield, when determined as herein described, may be used to (1) indicate coke yield on carbonization, (2) provide the basis for purchasing and selling, or (3) establish combustion characteristics.5.6 Fixed carbon is a calculated value. It is the difference between 100 and the sum of the percent moisture, ash, and volatile matter. All percents shall be on the same moisture reference base.5.7 Moisture, ash, and volatile matter are three of the principal parameters used for assessing the quality of coal.1.1 These instrumental test methods cover the determination of moisture, volatile matter, and ash, and the calculation of fixed carbon in the analysis of coal and coke samples prepared in accordance with Practice D2013 and Practice D346.1.2 These instrumental test methods are not applicable to thermogravimetric analyzers using microgram size samples.1.3 Test Methods D3173, D3174, and D3175 shall be considered the referee test methods.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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4.1 Apparent and true specific gravity, as determined by this test method, are influenced by the type of coals carbonized and the operating and preparational conditions of that carbonization, that is, charge bulk density, heating rate, and pulverization level. In turn, these properties directly influence the performance in processes using coke.1.1 This test method covers the determination of apparent specific gravity (Sections 5 to 9) and true specific gravity (Sections 10 to 14) of lump coke larger than 25 mm [1 in.] size and calculating porosity (Section 15) from the specific gravity data.1.2 Units—The values stated in either SI units or non-SI units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 The real density of calcined petroleum coke directly influences the physical and chemical properties of the manufactured carbon and graphite artifacts for which it is used. Density, therefore, is a major quality specification of calcined petroleum coke and is used as a control in coke calcination.1.1 This test method covers the determination of the real density (RD) of calcined petroleum coke. Real density, by definition is obtained when the particle size of the specimen is smaller than 75 µm (U.S. No. 200 Sieve).1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 The density of petroleum coke directly influences the physical and chemical properties of the manufactured carbon and graphite artifacts for which it is used. Density, therefore, is a major quality specification of calcined petroleum coke and is used as a control in coke calcination.1.1 This test method covers the determination of the real density (RD) of calcined petroleum coke. Real density, by definition, is obtained when the particle size of the test specimen is smaller than 75 μm (No. 200 sieve).1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Sections 10 and 11.1.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 The objective of this practice is to provide guidelines for the preparation of samples for interlaboratory studies to evaluate new test methods or for quality control purposes.5.2 Samples prepared using these guidelines may be used for the testing of the precision and bias mandatory for ASTM test methods. Such an evaluation is necessary to provide guidance to the user as to the reliability of measurements that can be expected by its use. The statements are developed on the basis of user experience (ordinarily through interlaboratory studies) with the test method.5.3 The availability of appropriate samples is a key requirement for interlaboratory studies.5.4 The homogeneity of the sample produced for interlaboratory studies must be small enough so that the variance caused by the sample is small compared to the variance of the test being performed.1.1 This practice describes the essential activities that are required to produce samples for interlaboratory studies.1.2 The suitability of a particular interlaboratory sample developed using this guide will depend on the tests being made.1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 Ash, as determined by this test method, is the residue remaining after burning the coal and coke. Ash obtained differs in composition from the inorganic constituents present in the original coal. Incineration causes an expulsion of all water, the loss of carbon dioxide from carbonates, the conversion of iron pyrites into ferric oxide, and other chemical reactions. Ash, as determined by this test method, will differ in amount from ash produced in furnace operations and other firing systems because incineration conditions influence the chemistry and amount of the ash. References for correcting ash results determined by this test method to a mineral-matter-free basis are listed in Classification D388, Section 9.1.1 This test method covers the determination of the inorganic residue as ash in the analysis sample of coal or coke as prepared in accordance with Practice D2013 or Practice D346. The results obtained can be applied as the ash in the proximate analysis, Practice D3172, and in the ultimate analysis, Practice D3176. For the determination of the constituents in ash, reference is made to Test Methods D3682, D4326, and D6349. Test Methods D6357 should be used to prepare ash to be used for trace element analysis. See Terminology D121 for definition of ash.1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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5.1 Vibrated bulk density, VBD, is an indicator of calcined petroleum coke porosity, which affects its suitability for use in pitch-bonded carbon applications. (Warning—Vibrated bulk density for a sample of calcined petroleum coke is strongly dependent upon average particle size and particle size range. Bulk density tends to increase with decreasing coke size. A narrow particle size range for this test minimizes the possibility for variation due to skewing of the test sample toward either screen defining the sample. Particle size range tested should be agreed upon by the purchaser and supplier.)NOTE 1: An example of the use of VBD to characterize coke for prebaked anodes for aluminum smelting is reported by Belitskus3 who found particles passing through a 0.59 mm opening, No. 30, sieve and retained on a 0.30 mm opening, No. 50, sieve to be preferred. Other popular ranges are particles passing through a 2.36 mm opening, No. 8, sieve and retained on a 1.17 mm opening, No. 16, sieve for the continuous Soderberg anode process and particles passing through a 6.68 mm opening sieve (equivalent to a 0.265 in. USA Series) and retained on a 3.33 mm opening, No. 6, sieve for graphite electrode manufacture.1.1 This test method covers the determination of bulk density of a representative 2 kg sample of calcined petroleum coke, after vibration to increase compaction.1.2 The procedure is limited to particles passing through a 6.68 mm opening sieve (equivalent to a 0.265 in. USA Series) and retained on a 0.21 mm opening sieve (equivalent to a 70 mesh USA Series). Further, the procedure is limited to a specific test sample having particles retained between screens having openings that differ by a factor of less thanand preferably less than 2.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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