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5.1 In gasoline blending, the determination of organic oxygenated compounds is important. Alcohols, ethers, and other oxygenates are added to gasoline to increase the octane number and to reduce tailpipe emissions of carbon monoxide. They must be added in the proper concentration and ratios to meet regulatory limitations and to avoid phase separation and problems with engine performance or efficiency.5.2 This test method provides sufficient oxygen-to-hydro-carbon selectivity and sensitivity to allow determination of oxygenates in gasoline samples without interference from the bulk hydrocarbon matrix.1.1 This test method covers a gas chromatographic procedure for the quantitative determination of organic oxygenated compounds in gasoline having a final boiling point not greater than 220 °C and oxygenates having a boiling point limit of 130 °C. It is applicable when oxygenates are present in the 0.1 % to 20 % by mass range.1.2 This test method is intended to determine the mass concentration of each oxygenate compound present in a gasoline. This requires knowledge of the identity of each oxygenate being determined (for calibration purposes). However, the oxygen-selective detector used in this test method exhibits a response that is proportional to the mass of oxygen. It is, therefore, possible to determine the mass concentration of oxygen contributed by any oxygenate compound in the sample, whether or not it is identified. Total oxygen content in a gasoline may be determined from the summation of the accurately determined individual oxygenated compounds. The summed area of other, uncalibrated or unknown oxygenated compounds present, may be converted to a mass concentration of oxygen and summed with the oxygen concentration of the known oxygenated compounds.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method was originally developed to evaluate oxidation stability of lubricating base oils combined with additives chemistries similar to those found in gasoline engine oils and service.25.2 This test method is useful for screening formulated oils before engine tests. Within similar additive chemistries and base oil types, the ranking of oils in this test appears to be predictive of ranking in certain engine tests. When oils having different additive chemistries or base oil type are compared, results may or may not reflect results in engine tests. Only gasoline engine oils were used in generating the precision statements in this test method.1.1 This test method covers the oxidation stability of lubricants by thin-film oxygen uptake (TFOUT) Catalyst B. This test method evaluates the oxidation stability of petroleum products, and it was originally developed as a screening test to indicate whether a given re-refined base stock could be formulated for use as automotive engine oil3 (see Test Method D4742). The test is run at 160 °C in a pressure vessel under oxygen pressure, and the sample contains a metal catalyst package, a fuel catalyst, and water to partially simulate oil conditions in an operating engine. In addition, the test method has since been found broadly useful as an oxidation test of petroleum products.41.2 The applicable range of the induction time is from a few minutes up to several hundred minutes or more. However, the range of induction times used for developing the precision statements in this test method was from 40 min to 280 min.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3.1 Exception—Pressure units are provided in psig, and dimensions are provided in inches in Annex A1 and Annex A2, because these are the industry accepted standard and the apparatus is built according to the figures shown.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is used primarily to determine the heat evolved in, or contributed to, a fire involving products of the test material. Also included is a determination of the effective heat of combustion, mass loss rate, the time to sustained flaming, and smoke production. These properties are determined on small size specimens that are representative of those in the intended end use.5.2 This test method is applicable to various categories of products and is not limited to representing a single fire scenario. Additional guidance for testing is given in X1.2.3 and X1.11.5.3 This test method is not applicable to end-use products that do not have planar, or nearly planar, external surfaces.FIG. 1 Overall View of ApparatusNOTE 1: All dimensions are in millimetres.NOTE 2: * Indicates a critical dimension.FIG. 2 Cross-Section View Through the HeaterNOTE 1: All dimensions are in millimetres.NOTE 2: * Indicates a critical dimension.FIG. 3 Exploded View, Horizontal OrientationFIG. 4 Exploded View, Vertical OrientationFIG. 5 Exhaust SystemNOTE 1: All dimensions are in millimetres (not to scale).FIG. 6 Horizontal Specimen HolderNOTE 1: All dimensions are in millimetres.NOTE 2: * Indicates a critical dimension.FIG. 7 Vertical Specimen HolderNOTE 1: All dimensions are in millimetres except where noted.NOTE 2: * Indicates a critical dimension.FIG. 8 Optional Wire Grid (For Horizontal or Vertical Orientation)NOTE 1: All dimensions are in millimetres.FIG. 9 Gas Analyzer InstrumentationNOTE 1: Rotameter is on outlet of the oxygen (O2) analyzer.FIG. 10 Smoke Obscuration Measuring SystemFIG. 11 Calibration BurnerNOTE 1: All dimensions are in millimetres except where noted.FIG. 12 Optional Retainer Frame for Horizontal Orientation TestingNOTE 1: All dimensions are in millimetres.NOTE 2: * Indicates a critical dimension.1.1 This fire-test-response standard provides for measuring the response of materials exposed to controlled levels of radiant heating with or without an external ignitor.1.2 This test method is used to determine the ignitability, heat release rates, mass loss rates, effective heat of combustion, and visible smoke development of materials and products.1.3 The rate of heat release is determined by measurement of the oxygen consumption as determined by the oxygen concentration and the flow rate in the exhaust product stream. The effective heat of combustion is determined from a concomitant measurement of specimen mass loss rate, in combination with the heat release rate. Smoke development is measured by obscuration of light by the combustion product stream.1.4 Specimens shall be exposed to initial test heat fluxes in the range of 0 kW/m2 to 100 kW/m2. External ignition, when used, shall be by electric spark. The value of the initial test heat flux and the use of external ignition are to be as specified in the relevant material or performance standard (see X1.2). The normal specimen testing orientation is horizontal, independent of whether the end-use application involves a horizontal or a vertical orientation. The apparatus also contains provisions for vertical orientation testing; this is used for exploratory or diagnostic studies only.1.5 Ignitability is determined as a measurement of time from initial exposure to time of sustained flaming.1.6 This test method has been developed for use for material and product evaluations, mathematical modeling, design purposes, or development and research. Examples of material specimens include portions of an end-use product or the various components used in the end-use product.1.7 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.8 This standard is used to measure and describe the response of materials, products, or assemblies to heat and flame under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.1.10 Fire testing is inherently hazardous. Adequate safeguards for personnel and property shall be employed in conducting these tests.1.11 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The O2GTR is an important determinant of the packaging protection afforded by barrier materials. It is not, however, the sole determinant, and additional tests, based on experience, must be used to correlate packaging performance with O2GTR. It is suitable as a referee method of testing, provided that the purchaser and the seller have agreed on sampling procedures, standardization procedures, test conditions, and acceptance criteria.5.2 Testing which has compared select instruments with other sensors to the instruments specifically described in Test Method D3985 is shown in Section 16, Precision and Bias, of this method.5.3 The Precision and Bias section of this method shows results using several instruments with non-coulometric and coulometric sensors.1.1 This test method covers a procedure for determination of the steady-state rate of transmission of oxygen gas through plastics in the form of film, sheeting, laminates, coextrusions, or plastic-coated papers or fabrics. It provides for the determination of (1) oxygen gas transmission rate (O2GTR), (2) the permeance of the film to oxygen gas (PO2), and (3) oxygen permeability coefficient (P′O2) in the case of homogeneous materials.1.2 This test method does not purport to be the only method for measurement of O2GTR. There may be other methods of O2GTR determination that use other oxygen sensors and procedures.1.3 This test method has intentionally been prepared to allow for the use of various sensors, devices, and procedures. The precision and bias of each design needs to be individually established to determine the applicability of that instrument or method to meet the needs of the user.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The OTR is an important determinant of the packaging protection afforded by barrier materials. It is not, however, the sole determinant, and additional tests, based on experience, must be used to correlate packaging performance with OTR. It is suitable as a referee method of testing, provided that the purchaser and the seller have agreed on sampling procedures, standardization procedures, test conditions, and acceptance criteria.5.2 Limited statistical data on correlations with Test Method D1434 methods are available4; however, the oxygen transmission rate of a standard reference material (see 12.1) as determined manometrically by NIST, is in good agreement with the values obtained in the coulometric interlaboratory test using material from the same manufacturing lot. Thus, this test method may be used as a referee method.1.1 This test method covers a procedure for determination of the steady-state rate of transmission of oxygen gas through plastics in the form of film, sheeting, laminates, coextrusions, or plastic-coated papers or fabrics. It provides for the determination of (1) oxygen gas transmission rate (OTR), (2) the permeance of the film to oxygen gas (PO2), and (3) oxygen permeability coefficient (P′O2) in the case of homogeneous materials.1.2 This test method does not purport to be the only method for measurement of OTR. There may be other methods of OTR determination that use other oxygen sensors and procedures.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The Oxygen Transmission Rate is an important determinant of packaging functionality afforded by packaging materials for a wide variety of packaged products including food, pharmaceuticals and medical devices. In some applications, sufficient oxygen must be allowed to permeate into the package. In others, the oxygen ingress must be minimized to maintain product quality.5.2 Other ASTM Standard Methods to measure the oxygen transmission rate are described in Test Method D3985 and Test Method F2622.1.1 This test method covers a procedure for determination of the transmission rate of oxygen gas through plastics in the form of film, sheeting, laminates, coextrusions, coated or uncoated papers or fabrics.1.2 This test method is not the only method for measurement of the oxygen transmission rate (OTR). There are other methods of OTR determination that use other oxygen sensors and procedures.1.3 The values stated in SI units are to be regarded as standard. Commonly used metric units used to report Oxygen Transmission Rate are included in Terminology, Procedure, Precision and Bias sections and in the Calculation section of the Appendix.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 This test method comprises two phases and is used to evaluate the ignition sensitivity and fault tolerance of oxygen pressure regulators used for medical and emergency applications.4.2 Phase 1: Oxygen Pressure Shock Test—The objective of this test phase is to determine whether the heat or temperature from oxygen pressure shocks will result in burnout or visible heat damage to the internal parts of the pressure regulator.4.2.1 The criteria for a valid test are specified in ISO 10524–1, Section 6.6 for oxygen pressure regulators and ISO 10524–3, Section 6.6 for oxygen VIPRs.4.2.2 The pass/fail criteria for a pressure regulator are specified in ISO 10524–1, Section 6.6 for oxygen pressure regulators and ISO 10524–3, Section 6.6 for oxygen VIPRs.4.3 Phase 2: Promoted Ignition Test—4.3.1 Oxygen Pressure Regulator—The objective of this test phase is to determine if an ignition event upstream of the pressure regulator inlet filter will result in sustained combustion and burnout of the pressure regulator.4.3.1.1 The criterion for a valid test is either, (1) failure of the pressure regulator, as defined in 4.3.1.2, or (2) if the pressure regulator does not fail, consumption of at least 90 % of the ignition pill as determined by visual inspection or mass determination.4.3.1.2 Failure of the pressure regulator is defined as the breach of the pressurized regulator component (burnout), which may include the CGA 870 seal ring, and ejection of molten or burning metal or any parts, including the gauge, from the pressure regulator. See Appendix X6 Testing Pressure Regulators and VIPRs with Gauges. However, momentary (less than 1 s) ejection of flame through normal vent paths, with sparks that look similar to those from metal applied to a grinding wheel, is acceptable and does not constitute a failure.4.3.2 Oxygen VIPR—The objective of this test is to determine if an ignition event upstream of the shut-off valve or within the shut-off valve will result in sustained combustion and burnout of the VIPR, while the VIPR is flowing oxygen in the patient-use direction.4.3.2.1 The criterion for a valid test is either, (1) failure of the VIPR as defined in 4.3.2.2, or (2) if the VIPR does not fail, consumption of at least 90 % of the ignition pill as determined by visual inspection or mass determination. Although the intent and desired result is to provide sufficient energy to ignite the shut-off valve seat, ignition of the shut-off valve seat is not required for a valid test. See Rationale in Appendix X7.4.3.2.2 Failure of the VIPR is defined as the breach of the pressurized VIPR component (burnout) and ejection of molten or burning metal or any parts, including the gauge, from the VIPR. See Appendix X6 Testing Pressure Regulators and VIPRs with Gauges. However, momentary (less than 1 s) ejection of flame through normal vent paths, with sparks that look similar to those from metal applied to a grinding wheel, is acceptable and does not constitute a failure.4.3.3 There is no requirement that the oxygen pressure regulator or oxygen VIPR be functional after being subjected to the promoted ignition test.NOTE 4: The criterion for both the pressure regulator and VIPR Phase 2 tests does not include evaluation of external hardware (such as plastic guards and bags) that could be subjected to a momentary ejection of flame through normal vent paths.1.1 For the purpose of this standard, a pressure regulator, also called a pressure-reducing valve, is a device intended for medical or emergency purposes that is used to convert a medical or emergency gas pressure from a high, variable pressure to a lower, more constant working pressure [21 CFR 868.2700 (a)]. Some of these oxygen pressure regulators are a combination of a pressure regulator and cylinder valve. These devices are often referred to as valve integrated pressure regulators, or VIPRs.1.2 This standard provides an evaluation tool for determining the ignition sensitivity and fault tolerance of oxygen pressure regulators and VIPRs used for medical and emergency applications. An ignition-sensitive pressure regulator or VIPR is defined as having a high probability of ignition as evaluated by rapid pressurization testing (Phase 1). A fault-tolerant pressure regulator or VIPR is defined as having a low consequence of ignition as evaluated by forced ignition testing (Phase 2).NOTE 1: It is essential that a risk assessment be carried out on breathing gas systems, especially concerning toxic product formation due to ignition or decomposition of nonmetallic materials as weighed against the risk of flammability (refer to Guide G63 and ISO 15001.2). See Appendix X1 and Appendix X2 for details.1.3 This standard applies only to:1.3.1 Oxygen pressure regulators used for medical and emergency applications that are designed and fitted with CGA 540 inlet connections, CGA 870 pin-index adapters (CGA V-1), or EN ISO 407 pin-index adapters.1.3.2 Oxygen VIPRs used for medical and emergency applications that are designed to be permanently fitted to a medical gas cylinder.1.4 This standard is a test standard not a design standard; This test standard is not intended as a substitute for traditional design requirements for oxygen cylinder valves, pressure regulators and VIPRs. A well-designed pressure regulator or VIPR should consider the practices and materials in standards such as Guides G63, G88, G94, and G128, Practice G93, CGA E-18, CGA E-7, ISO 15001, ISO 10524-1 and ISO 10524-3.NOTE 2: Medical applications include, but are not limited to, oxygen gas delivery in hospitals and home healthcare, and emergency applications including, but not limited to, oxygen gas delivery by emergency personnel.1.5 This standard is also intended to aid those responsible for purchasing or using oxygen pressure regulators and VIPRs used for medical and emergency applications by ensuring that selected pressure regulators are tolerant of the ignition mechanisms that are normally active in oxygen systems.1.6 This standard does not purport to address the ignition sensitivity and fault tolerance of an oxygen regulator or VIPR caused by contamination during field maintenance or use. Pressure regulator and VIPR designers and manufacturers should provide design safeguards to minimize the potential for contamination or its consequences (see Guide G88).NOTE 3: Experience has shown that the use of bi-direction flow filters in components can lead to accumulation and re-release of contaminants (refer to Guide G88-05 Section 7.5.3.8 and EIGA Info 21/08).1.7 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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