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3.1 International standard ANSI/ISO/IEC 17025 promotes the use of documented accountability and quality control procedures to assure a laboratory and its clients that the laboratory can produce technically valid data and results in the routine performance of its sampling, sample preparation and testing activities.3.2 A laboratory shall use ANSI/ISO/IEC 17025 to develop its quality system. Clause 4 of ANSI/ISO/IEC 17025 specifies the requirements for sound management. Clause 5 of ANSI/ISO/IEC 17025 specifies the requirements for technical competence for the type of tests or calibrations, or both the laboratory undertakes.3.3 In addition to complying with the requirements of ANSI/ISO/IEC 17025, the Annex of this standard practice contains information that shall be considered important for the evaluation and operation of a competent Coal and Coke sampling or testing facility, or both. The information in this Annex is presented where it is not otherwise covered in ANSI/ISO/IEC 17025 or the applicable ASTM methods.3.4 Laboratory clients, regulatory authorities, and accreditation bodies that recognize the competence of testing and calibration laboratories can use this standard practice as the basis for their evaluation.3.5 The primary significance of this practice is to establish that for a laboratory to generate measurements traceable to SI units, it must:3.5.1 Have a clear understanding of the work requested by the client.3.5.2 Meet the quality system requirements of the internationally accepted ANSI/ISO/IEC 17025 standard.3.5.3 Use test methods which have been shown to be traceable to SI units of measurement.3.5.4 Be able to demonstrate that the laboratory is in statistical control at the time the measurements are made.1.1 This practice specifies requirements to operate and evaluate the quality and management systems in a laboratory that provides services with respect to sample collection, sample preparation, or testing of coal, coke, and ash derived from coal or coke using ASTM standards that are under the jurisdiction of Committee D05 on Coal and Coke.NOTE 1: The word “laboratory” is used throughout this practice when referring to an organization that provides services in coal sampling or testing, or both. It is recognized, however, that the word may not be appropriate to an organization that does not perform actual laboratory sample testing.1.2 International standard ANSI/ISO/IEC 17025 shall be the governing document specifying requirements for management, technical competence and evaluation of a laboratory.NOTE 2: An accrediting body or user of laboratory services can also impose technical or non-technical requirements not specifically addressed in ANSI/ISO/IEC 17025 provided they do not invalidate the requirements of ANSI/ISO/IEC 17025.1.3 This practice is used to evaluate only those capabilities specifically claimed by a laboratory.1.4 All percentages are percent mass fractions unless otherwise noted.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 The combustible carbon content of solid residues is used to calculate efficiency of fuel combustion in boiler furnaces and similar combustors.5.2 Combustible carbon values are also used to determine the residual fuel value of incompletely combusted/reacted coal and coke in other reactors that consume carbonaceous fuels (examples include fluidized bed furnaces and liquefaction, gasification and pyrolysis reactors).5.3 The combustible carbon content of flyash is an important parameter in the use of flyash as a cement additive.1.1 This test method covers the determination of total, combustible, and carbonate carbon remaining in the solid byproducts of combustion from boiler furnaces and similar reactors, including ash, flyash, char, slag, and similar materials.1.2 This test method is intended for the use of industry to determine the performance of boiler furnaces and similar combustion reactors and aid in determining the quality of the solid residue from combustion.1.3 This test method comprises the use of any of several methods to determine total carbon content combined with any of several methods to determine carbonate carbon, and the calculation, by difference, of the combustible carbon remaining in a sample.1.4 Alternatively, this test method applies to the determination of total carbon remaining in a material after acidification with strong acid to evolve carbonate carbon. In this case, the combustible carbon is the total carbon measured in the sample after acidification.1.5 The values stated in SI units are to be regarded as standard. Non-SI units, if provided, are for information only and are contained within parentheses.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and to determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Sulfur is part of the ultimate analysis of coal and coke.4.2 Results of the sulfur analysis are used for evaluation of coal preparation and cleaning, evaluation of potential sulfur emissions from coal and coke combustion or conversion processes, and evaluation of coal and coke quality in relation to contract specifications, as well as for scientific purposes.4.3 The competency of laboratories with respect to use of this standard can be established through reference to Practice D7448.1.1 This test method covers the determination of sulfur in samples of coal or coke by high-temperature tube furnace combustion.1.1.1 Two analysis methods are described.1.2 When automated equipment is used, either method can be classified as an instrumental method.1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.4 All percentages are percent mass fractions unless otherwise noted.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Carbon and hydrogen values can be used to determine the amount of oxygen (air) required in combustion processes and for calculation of the efficiency of combustion processes.5.2 Carbon and hydrogen determinations can be used in calculations including material balance, reactivity and yields of products relevant to coal conversion processes such as gasification and liquefaction.5.3 Carbon and nitrogen values can be used in material balance calculations employed for emission accounting purposes.NOTE 2: The bulk composition of coal changes at a rate that varies from coal to coal during storage. As a result, using coal for calibration can yield incorrect estimates of carbon, and hydrogen content in particular.1.1 Test Method A covers the determination of carbon in the range of 54.9 % to 84.7 %, hydrogen in the range of 3.26 % to 5.08 %, and nitrogen in the range of 0.57 % to 1.76 % in analysis samples (8.1) of coal and of carbon in analysis samples of coke in the range of 86.6 % to 97.9 %.1.1.1 Test Method B covers the determination of carbon in analysis samples of coal in the range of 57.7 % to 84.0 %, and carbon in analysis samples of coke in the range of 86.3 % to 95.4 %.NOTE 1: The coals included in the interlaboratory studies employed to derive the precision statements for this standard cover ASTM rank lignite A to low volatile bituminous. Additional information concerning the composition of these coals appears in Annex A4 and Annex A5. The cokes used in the interlaboratory study employed to derive the precision statement for coke for Method A included five each metallurgical (met) cokes and seven each petroleum (pet) cokes, and Method B included an equal number (five each) of met cokes and pet cokes.1.2 All percentages are percent mass fractions unless otherwise noted.1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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