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AS 1141.31:2015 Methods for sampling and testing aggregates Light particles 现行 发布日期 :  2015-04-14 实施日期 : 

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AS 1141.31-1997 Methods for sampling and testing aggregates Light particles 现行 发布日期 :  1997-10-05 实施日期 : 

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5.1 This guide is intended for use by entities involved in the handling of UNP in occupational settings. This guide covers handling principles and techniques that may be applied, as appropriate, to the variety of UNP materials and handling settings. These settings include research and development activities, material manufacturing, and material use and processing. This guide may also be used by entities that receive materials or articles containing or comprising nanoscale particles fixed upon or within a matrix (that is, bound nanoscale particles), but whose own processes or use may reasonably be expected to cause such particles to become unbound.1.1 This guide describes actions that could be taken by the user to minimize human exposures to unbound, engineered nanoscale particles (UNP) in research, manufacturing, laboratory and other occupational settings where UNP may reasonably be expected to be present. It is intended to provide guidance for controlling such exposures as a cautionary measure where neither relevant exposure standards nor definitive hazard and exposure information exist.1.2 General Guidance—This guide is applicable to occupational settings where UNP may reasonably be expected to be present. Operations across those settings will vary widely in the particular aspects relevant to nanoscale particle exposure control. UNP represent a vast variety of physical and chemical characteristics (for example, morphology, mass, dimension, chemical composition, settling velocities, surface area, surface chemistry) and circumstances of use. Given the range of physical and chemical characteristics presented by the various UNP, the diversity of occupational settings and the uneven empirical knowledge of and experience with handling UNP materials, the purpose of this guide is to offer general guidance on exposure minimization approaches for UNP based upon a consensus of viewpoints, but not to establish a standard practice nor to recommend a definite course of action to follow in all cases.1.2.1 Accordingly, not all aspects of this guide may be relevant or applicable to all circumstances of UNP handling. The user should apply reasonable judgment in applying this guide including consideration of the characteristics of the particular UNP involved, the user’s engineering and other experience with the material, and the particular occupational settings where the user may apply this guide. Users are encouraged to obtain the services of qualified professionals in applying this guide.1.2.2 Applicable Where Relevant Exposure Standards Do Not Exist—This guide assumes that the user is aware of and in compliance with any authoritative occupational exposure standard applicable to the bulk form of the UNP. This guide may be appropriate where such exposure standards do not exist, or where such standards exist, but were not developed with consideration of the nanoscale form of the material.1.3 Applicable Where Robust Risk Information Does Not Exist—This guide assumes the absence of scientifically sound risk assessment information relevant to the particular UNP involved. Where sound risk assessment information exists, or comes to exist, any exposure control measures should be designed based on that information, and not premised on this guide. Such measures may be more or less stringent than those suggested by this guide.1.4 Materials Within —This guide pertains to unbound engineered nanoscale particles or their respirable agglomerates or aggregates thereof. Relevant nanoscale particle types include, for example, intentionally produced fullerenes, nanotubes, nanowires, nanoropes, nanoribbons, quantum dots, nanoscale metal oxides, and other engineered nanoscale particles. Respirable particles are those having an aerodynamic equivalent diameter (AED) less than or equal to 10 µm (10 000 nm) or those particles small enough to be collected with a respirable sampler (1-3).2 The AED describes the behavior of an airborne particle and is dependent upon the particle density, shape, and size—for instance, a particle with a spherical shape, smooth surface, density of 1.0 g/cc and a physical diameter of 4 µm would have an AED of 4 µm, whereas a particle with a spherical shape, smooth surface, density of 11.35 g/cc and a physical diameter of 4 µm would have an AED of 14 µm and would therefore be of a nonrespirable size. Respirable fibers are those having physical diameters less than or equal to 3 µm (3000 nm) or those fibers small enough to be collected with a thoracic sampler (4, 5).1.5 Materials Beyond : 1.5.1 UNP may be present in various forms, such as powders or suspensions, or as agglomerates and aggregates of primary particles, or as particles dispersed in a matrix. This guide does not pertain to UNP incapable, as a practical matter, from becoming airborne or be expected to generate or release UNP in occupational settings under the particular circumstances of use (for example, UNPs dispersed or otherwise fixed within a solid, strongly bonded to a substrate or contained within a liquid matrix such as aggregated primary crystals of pigments in paints). This guide does not pertain to aggregates or agglomerates of UNP that are not of a respirable size.1.5.2 This guide does not pertain to materials that present nanoscale surface features, but do not contain UNPs (for example, nanoscale lithography products, nanoelectronic structures or materials comprised of nanoscale layers).1.5.3 This guide does not pertain to UNPs which exist in nature which may be present in normal ambient atmospheres or are unintentionally produced by human activities, such as by combustion processes. Nor does it pertain to materials that have established exposure control programs (for example, safe handling protocols for nanoscale biological agents) or published exposure limits such as occupational exposure limits for welding fumes. See Appendix X1.1.6 Handling Considerations Beyond —The use of this guide is limited to the scope set forth in this section. This guide generally does not address actions related to potential environmental exposures, nor to exposures potentially arising at disposal or other end-uses.1.7 Not a Standard of Care—This guide does not necessarily represent the standard of care by which the adequacy of a set of exposure control measures should be judged; nor should this document be used without consideration of the particular materials and occupational circumstances to which it may be applied. The word “standard” in the title means only that the document has been approved through the ASTM consensus process.1.8 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.10 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Coarse particles in printing inks reduce the efficiency of the dispersion process, requiring not only extra milling passes, but also frequent changes in pump filters. In printing processes, they may cause excessive wear to metal plates, piling or localized retention of ink on blankets and plates, and water balance problems. Coarse particles also reduce color strength and the gloss of printed matter.4.2 This test method is suitable for quality control. The precision may be improved by the use of a specimen size larger than that prescribed.4.3 Test results are sensitive to the type of washout solvent used. Strong solvents are to be avoided because they may dissolve large particles of resin in the ink vehicle.1.1 This test method covers the determination of the weight concentration of coarse particles in printing ink dispersions by sieve retention.1.2 This test method is applicable to printing inks, flushed pigments, and other pigment dispersions that contain particles larger than 45 μm. With proper choice of solvent, it is applicable both to paste and liquid inks.NOTE 1: This test method is similar in principle to Test Methods D185. For particles under 25 μm, see Test Method D1316.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Reported particle size measurement is a function of both the actual particle dimension and shape factor, as well as the particular physical or chemical properties of the particle being measured. Caution is required when comparing data from instruments operating on different physical or chemical parameters or with different particle size measurement ranges. Sample acquisition, handling, and preparation can also affect the reported particle size results.1.1 These test methods cover the determination of the size distribution and quantity of particulate matter contamination from aerospace fluids isolated on a membrane filter. The microscopical techniques described may also be applied to other properly prepared samples of small particles. Two test methods are described for sizing particles as follows:1.1.1 Test Method A—Particle sizes are measured as the diameter of a circle whose area is equal to the projected area of the particle.1.1.2 Test Method B—Particle sizes are measured by their longest dimension.1.2 The test methods are intended for application to particle contamination determination of aerospace fluids, gases, surfaces, and environments.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 These test methods do not provide for sizing particles smaller than 5 μm.NOTE 1: Results of these methods are subject to variables inherent in any statistical method. The use of these methods as a standard for initially establishing limits should be avoided unless ample tolerances are permissible.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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