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4.1 The shrinkage of SBR rubbers and their compounds after processing is of importance in many applications. This property can also be used for control, specifications, and fabrication purposes.1.1 These test methods cover the determination of mill shrinkage of hot-polymerized styrene-butadiene rubbers (SBR) and their compounds.1.2 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is designed to determine the nitrogen content of oligomeric 2,2,4-trimethyl-1,2-dihydroquinoline (TMQ) antioxidant. TMQ is used for heat protection of vulcanized rubber.5.2 This test method is suitable for assessing product specifications since nitrogen content is related to product performance, that is, antioxidant efficiency and heat protection. For comparison of product quality at different production facilities sufficient interlaboratory accuracy and precision are required.1.1 This test method covers the determination of the nitrogen content of polymerized 2,2,4-trimethyl-1,2-dihydroquinoline (TMQ). It is based on a potentiometric titration of an acetone solution of TMQ with perchloric acid in acetic acid.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 9.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Measurements of EO content correlate to polyol reactivity (as related to primary hydroxyl content), linearity of foam rise, and hydrophilicity of the polyol and final product.1.1 Test Method A—Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) content of ethylene oxide (EO) propylene oxide (PO) polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols initiated from glycols of EO or PO containing EO percentages >5. For triols initiated with glycerol (glycerin) and trimethylolpropane, an uncorrected EO value is obtained since both initiators have protons that contribute to the EO measurement.1.2 Test Method B—Carbon-13 Nuclear Magnetic Resonance Spectroscopy (13C NMR) measures the polymerized EO content of EO-PO polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols and triols made from the commonly used initiators and containing EO percentages >5.1.3 The values stated in SI units are to be regarded as standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.NOTE 1: There is no known ISO equivalent to this standard.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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