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5.1 In the design and operation of reverse osmosis and nanofiltration installations, it is important to predict the CaSO4, SrSO4, and BaSO4 scaling properties of the concentrate stream. Because of the increase in total dissolved solids and the increase in concentration of the scaling salts, the scaling properties of the concentrate stream will be quite different from those of the feed solution. This practice permits the calculation of the scaling potential for the concentrate stream from the feed water analyses and the reverse osmosis or nanofiltration operating parameters.5.2 Scaling by CaSO4, SrSO4, and BaSO4 will adversely affect the reverse osmosis or nanofiltration performance. This practice gives various procedures for the prevention of scaling.1.1 This practice covers the calculation and adjustment of calcium, strontium, and barium sulfates for the concentrate stream of a reverse osmosis or nanofiltration system. The calculations are used to determine the need for scale control in the operation and design of reverse osmosis and nanofiltration installations. This practice is applicable for all types of reverse osmosis devices (tubular, spiral wound, and hollow fiber) and nanofiltration devices.1.2 This practice is applicable to both brackish waters and seawaters.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.5.3 This test method is intended as an alternative to the HPLC method for the determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption, and operating costs.1.1 This test method2 covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with reverse voltage mode and UV detection. It is applicable for 4-CBA from 3 to 400 mg/kg and for p-TOL from 8 to 400 mg/kg, respectively.1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 CEDI devices can be used to produce deionized water from feeds of pretreated water. This test method permits the measurement of key performance capabilities of CEDI devices using a standard set of conditions. The data obtained can be analyzed to provide information on whether changes may have occurred in operating characteristics of the device independently of any variability in feed water characteristics or operating conditions. Under specific circumstances, this test method may also provide sufficient information for plant design.1.1 This test method covers the determination of the operating characteristics of continuous electrodeionization (CEDI) devices, indicative of deionization performance when a device is applied to production of highly deionized water from the product water of a reverse osmosis system. This test method is a procedure applicable to feed waters containing carbonic acid or dissolved silica, or both, and other solutes, with a conductivity range of approximately 2 to 100 microsiemens-cm-1.1.2 This test method covers the determination of operating characteristics under standard test conditions of CEDI devices where the electrically active transfer media therein is predominantly regenerated.1.3 This test method is not necessarily indicative of:1.3.1 Long term performance on feed waters containing foulants or sparingly soluble solutes, or both;1.3.2 Performance on feeds of brackish water, sea water, or other high salinity feeds;1.3.3 Performance on synthetic industrial feed solutions, pharmaceuticals, or process solutions of foods and beverages; or1.3.4 Performance on feed waters less than 2 μS/cm, particularly performance relating to organic solutes, colloidal or particulate matter, or biological or microbial matter.1.4 This test method, subject to the limitations described, can be applied as either an aid to predict expected deionization performance for a given feed water quality, or as a method to determine whether performance of a given device has changed over some period of time. It is ultimately, however, the user’s responsibility to ensure the validity of this test method for their specific applications.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 In the design and operation of reverse osmosis installations, it is important to predict the SiO2 scaling properties of the concentrate stream. Because of the increase in the concentration of SiO2 and the change in pH, the scaling property of the concentrate stream will be quite different from that of the feed solution. This practice permits the calculation of the scaling potential for the concentrate stream from the feedwater analysis and the reverse osmosis operating parameters.5.2 Scaling by SiO2 will adversely affect the reverse osmosis performance. This practice gives various procedures for the prevention of scaling.5.3 The presence of certain metals, for example, Al+3, may significantly alter the solubility of SiO2 via formation of insoluble metal silicates. This practice does not address this phenomena.1.1 This practice covers the calculation and adjustment of silica (SiO2) for the concentrate stream of a reverse osmosis system. The calculations are used to determine the need for scale control in the operation and design of reverse osmosis installations. This practice is applicable for all types of reverse osmosis devices (tubular, spiral wound, and hollow fiber).1.2 This practice is applicable to both brackish waters and seawaters.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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4.1 Dual-wall reverse-circulation drilling can be used in support of geoenvironmental exploration and for installation of subsurface water quality monitoring devices in unconsolidated and consolidated sediment or bedrock. Dual-wall reverse-circulation drilling methods allows for the collection of water quality samples at most depth(s), the setting of temporary casing during drilling, and continual sampling of cuttings while drilling fluid is circulating, if warranted or needed. Other advantages of the dual-wall reverse-circulation drilling method include, but are not limited to: (1) the capability of drilling without the introduction of any drilling fluid(s) (for example, drilling mud or similar) to the subsurface; (2) maintenance of borehole stability for sampling purposes and monitoring well installation/construction in poorly-indurated to unconsolidated sediment.4.1.1 The user of dual-wall reverse-circulation drilling for geoenvironmental exploration and monitoring-device installations should be cognizant of both the physical (temperature and airborne particles) and chemical (compressor lubricants and other fluid additives) qualities of compressed air that may be used as the circulating medium.4.2 The application of dual-wall reverse-circulation drilling to geoenvironmental exploration may involve soil or rock sampling, or in situ soil/sediment, rock, or pore-fluid testing.NOTE 2: The user may install a monitoring device within the same borehole wherein sampling, in situ or pore-fluid testing, or coring was performed.4.3 The subsurface water quality monitoring devices that are addressed in this guide consist generally of a screened- or porous-intake device and riser pipe(s) that are usually installed with a filter pack to enhance the longevity of the intake unit, and with isolation seals and low-permeability backfill to deter the vertical movement of fluids or infiltration of surface water between hydrologic units penetrated by the borehole (see Practice D5092). Since a piezometer is primarily a device used for measuring subsurface hydraulic heads, the conversion of a piezometer to a water quality monitoring device should be made only after consideration of the overall quality and integrity of the installation to include the quality of materials that will contact sampled water or gas. Both water quality monitoring devices and piezometers should have adequate casing seals, annular isolation seals, and backfills to deter cross-communication of contaminants between hydrogeologic units.NOTE 3: The quality of the results produced by this guide is dependent on the competence of the personnel performing it and the suitability of the equipment and facilities used. Agencies that meet the criteria of Practice D3740 are generally considered capable of competent and objective testing. Users of this test method are cautioned that compliance with Practice D3740 does not in itself ensure reliable results. Reliable results depend on many factors; Practice D3740 provides a means of evaluating some of those factors.1.1 This guide covers how dual-wall reverse-circulation drilling may be used for geoenvironmental exploration and installation of subsurface water quality monitoring devices. The term reverse circulation with respect to dual-wall drilling in this guide indicates that the circulating fluid is forced down the annular space between the double-wall drill pipe and transports soil/sediment and rock particles to the surface through the inner pipe.NOTE 1: This guide does not include considerations for geotechnical site characterizations that are addressed in a separate guide.1.2 Dual-wall reverse-circulation for geoenvironmental exploration and monitoring-device installations will often involve safety planning, administration, and documentation. This guide does not purport to specifically address exploration and site safety.1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This guide offers an organized collection of information or a series of options and does not recommend a specific course of action. This document cannot replace education or experience and should be used in conjunction with professional judgment. Not all aspects of this guide may be applicable in all circumstances. This ASTM standard is not intended to represent or replace the standard of care by which the adequacy of a given professional service must be judged, nor should this document be applied without consideration of a project's many unique aspects. The word “Standard” in the title of this document means only that the document has been approved through the ASTM consensus process.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 Proper operation and maintenance of RO and NF systems are key factors in obtaining successful performance. This guide provides the necessary input for the evaluation of the performance of the RO and NF systems, the pretreatment system, and the mechanical equipment in the plant.4.2 This guide is for general guidance only and must not be used in place of the operating manual for a particular plant.4.3 Site-dependent factors prevent specific recommendations for all recordkeeping. Thus, only the more general recordkeeping is covered by this guide.4.4 This guide can be used for both brackish and seawater systems which contain either spiral-wound or hollow-fiber devices.1.1 This guide covers procedures for well-defined recordkeeping of reverse osmosis (RO) and nanofiltration (NF) systems.1.2 This guide includes a start-up report, recordkeeping of RO and NF operating data, recordkeeping of pretreatment operating data, and a maintenance log.1.3 This guide is applicable to waters including brackish waters and seawaters but is not necessarily applicable to wastewaters.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Reverse osmosis and nanofiltration desalinating devices can be used to produce potable water from brackish supplies (<10 000 mg/L) and seawater as well as to upgrade the quality of industrial water. These test methods permit the measurement of the performance of reverse osmosis devices using standard sets of conditions and are intended for short-term testing (<24 h). These test methods can be used to determine changes that may have occurred in the operating characteristics of reverse osmosis and nanofiltration devices but are not intended to be used for plant design.1.1 These test methods cover the determination of the operating characteristics of reverse osmosis devices using standard test conditions and are not necessarily applicable to natural waters. Three test methods are given, as follows:  Sections Test Method A—Brackish Water Reverse Osmosis Devices 8 – 14Test Method B—Nanofiltration Devices 15 – 21Test Method B—Seawater Reverse Osmosis Devices 22 – 281.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The performance of RO or NF membranes is strongly influenced by the composition of the feed solution. Overall salt rejection is dependent upon the ratio of monovalent to polyvalent ions as well as the sum total of ions present. The permeate flow rate of RO or NF devices is also dependent upon the sum total of the ions present and the operating temperature, pressure, and recovery rate. Analyses and measurements performed in this guide will provide vital data for salt rejection and permeate flow projections of RO or NF systems for specific feedwaters.5.2 The recovery at which a RO or NF system can be safely operated is dependent upon the composition of the feed solution. The analyses and measurements performed in this guide will provide data for the calculation of the maximum recovery of a RO or NF system for a given feed solution.5.3 The analyses and measurements performed in this guide will be of great assistance in determining the pretreatment requirements for a RO or NF system on a given feedwater.1.1 This guide covers the analyses that should be performed on any given water sample if reverse osmosis (RO) or nanofiltration (NF) application is being considered. (See also Test Methods D511, D512, D513, D516, D858, D859, D888, D1068, D1179, D1253, D1293, D1889, D3352, D3370, D3561, D3867, D4189, D4194, and D4382.)1.2 This guide is applicable to waters including brackish waters and seawaters but is not necessarily applicable to waste waters.1.3 This is a guide only and should not be construed as a delineation of all ions known to exist in waters.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 These practices may be used to determine whether a RO or NF device is free of leaks if the mechanical integrity of the device is to be confirmed. They may also be used to detect leaks in RO or NF devices whose operating performance indicates a possible leak. These practices may be used for either new or used devices.1.1 These practices cover detecting leaks in which there is a direct communication between the feed or concentrate, or both, and the permeate. Several types of leaks are possible with the various configurations of reverse-osmosis (RO) and nanofiltration (NF) devices.1.2 Types of Leaks: 1.2.1 With hollow-fiber devices, feed or concentrate leakage, or both, into the permeate stream by leaks through the tube sheet and past the tube sheet O-ring are possible. “Leaks” caused by broken fibers are not covered by these practices.1.2.2 With spiral-wound devices, leaks may occur through damage of the membrane surface itself by punctures or scratches, by glue-line failure, and by O-ring leaks on product tube interconnectors.1.2.3 With tubular devices, leaks due to membrane damage, tube end seal leaks, and leaks from broken tubes or product headers are possible.1.3 Three leak test practices are given as follows:  SectionsPractice A—Tube Sheet and O-Ring Leak Test for Hollow Fiber Devices 8 to 9Practice B—Vacuum Test for Spiral Wound Devices 10 to 12Practice C—Dye Test for Spiral Wound and Tubular Devices 13 to 181.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process and 4-CBA imparts coloration to the polymer due to thermal instability.4.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used.1.1 This test method covers the determination of the 4-Carboxybenzaldehyde (4-CBA) and p-Toluic acid (p-TOL) in purified terephthalic acid (PTA) by reverse phase high performance liquid chromatography (HPLC). This method is applicable for 4-CBA from 2 to 500 mg/kg and for p-TOL from 10 to 500 mg/kg, respectively.1.2 In determining the conformance of the test results using this method to applicable specification, results shall be rounded off in accordance with the rounding-off method of Practice E29.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 During the operation of an RO system, system conditions such as pressure, temperature, conversion, and feed concentration can vary, causing permeate flow and salt passage to change. To effectively evaluate system performance, it is necessary to compare permeate flow and salt passage data at the same conditions. Since data may not always be obtained at the same conditions, it is necessary to convert the RO data obtained at actual conditions to a set of selected constant conditions, thereby standardizing the data. This practice gives the procedure to standardize RO data.5.2 This practice can be used for both spiral wound and hollow fiber systems.5.3 This practice can be used for a single element or a multi-element system. However, if the RO system is brine staged, that is, the brine from one group of RO devices is the feed to a second group of RO devices, standardize the permeate flow and salt passage for each stage separately.5.4 This practice is applicable for RO systems with high rejections and with no significant leaks between the feed-brine and permeate streams.1.1 This practice covers the standardization of permeate flow, salt passage, and coefficient of performance data for reverse osmosis (RO) systems.1.2 This practice is applicable to waters including brackish waters and seawaters but is not necessarily applicable to waste waters.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Home reverse osmosis devices are typically used to remove salts and other impurities from drinking water at the point of use. They are usually operated at tap water line pressure, with water containing up to several hundred milligrams per litre of total dissolved solids. This practice permits measurement of the performance of home reverse osmosis devices using a standard set of conditions and is intended for short-term testing (less than 24 h). This practice can be used to determine changes that may have occurred in the operating characteristics of home reverse osmosis devices during use, but it is not intended to be used for system design. This practice does not necessarily determine the device’s performance when solutes other than sodium chloride are present. Use Practice D4516 and Test Methods D4194 to standardize actual field data to a standard set of conditions.5.2 This practice is applicable for spiral-wound devices.1.1 This practice covers determination of the operating characteristics of home reverse osmosis devices using standard test conditions. It does not necessarily determine the characteristics of the devices operating on natural waters.1.2 This practice is applicable for spiral-wound devices.1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 In the design and operation of RO installations, it is important to predict the calcium carbonate scaling properties of the concentrate stream. Because of the increase in total dissolved solids in the concentrate stream and the difference in passages for calcium ion, bicarbonate ion, and free carbon dioxide, the calcium carbonate scaling properties of the concentrate stream will generally be quite different from those of the feed solution. This practice permits the calculation of the Langelier saturation index for the concentrate stream from the feed water analyses and the RO operating parameters.5.2 A positive Langelier saturation index indicates the tendency to form a calcium carbonate scale, which can be damaging to RO performance. This practice gives various procedures for the adjustment of the Langelier saturation index.5.3 The tendency to form calcium carbonate scale can be suppressed by the addition of antiscalents or crystal modifiers. Suppliers of antisealents and crystal modifiers can provide information on the scale inhibition peformance of these types of chemical. Their use may be appropriate for reducing scale formation in RO systems. The RO system supplier should be consulted prior to the use of antisealents and crystal modifiers to ensure they will not have a negative impact on the RO system.1.1 This practice covers the calculation and adjustment of the Langelier saturation index for the concentrate stream of a reverse osmosis (RO) device. This index is used to determine the need for calcium carbonate (CaCo3) scale control in the operation and design of RO installations. This practice is applicable for concentrate streams containing 10 to 10 000 mg/L of total dissolved solids. For concentrate containing over 10 000 mg/L, see Practice D4582.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 The need to understand the relationships found in membrane unit processes for water treatment increases with the continuing demand for these separation systems. Defining the terms common to microfiltration, ultrafiltration, nanofiltration, and reverse osmosis processes assist the manufacturer, consultant, and end-user in eliminating inter-process terminology confusion. This standard expands the definitions found in Terminology D1129.1.1 This terminology covers the use of microfiltration, ultrafiltration, nanofiltration, and reverse osmosis for membrane separation processes.1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 In the design and operation of reverse osmosis installations, it is important to predict the calcium carbonate scaling properties of the concentrate stream. Because of the increase in total dissolved solids in the concentrate stream and the differences in salt passages for calcium ion, bicarbonate ion, and free CO2, the calcium carbonate scaling properties of the concentrate stream will generally be quite different from those of the feed solution. This practice permits the calculation of the S & DSI for the concentrate stream from the feed water analyses and the reverse osmosis operating parameters.5.2 A positive S & DSI indicates the tendency to form a calcium carbonate scale, which can be damaging to reverse osmosis performance. This practice gives procedures for the adjustment of the S & DSI.1.1 This practice covers the calculation and adjustment of the Stiff and Davis Stability Index (S & DSI) for the concentrate stream of a reverse osmosis device. This index is used to determine the need for calcium carbonate scale control in the operation and design of reverse osmosis installations. This practice is applicable for concentrate streams containing more than 10 000 mg/L of total dissolved solids. For concentrate streams containing less than 10 000 mg/L of total dissolved solids, refer to Practice D3739.1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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