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3.1 This test method is intended for the determination of the neutral fatty matter contained in fats and oils by means of ether extraction.1.1 This test method covers all degraded glycerides, since they are neutral fats. However, this procedure does not necessarily determine all the mono and diglycerides that may be present in the sample. This is due to the water soluble characteristics of some mono and diglycerides.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 This test method is intended for use in the determination of the acid number of sulfonated and sulfated oils for the purpose of quality assurance.1.1 This test method covers determination of the acidity as free fatty acids in the presence of ammonium or triethanolamine soaps, or both, existing in a sample of sulfonated or sulfated oil, or both, by calculation from the total alkalinity and free-and-alkali combined fatty acids.1.2 The values stated in SI units are to be regarded as standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This test method is intended to cover determination of the solidification point of fatty acids contained in animal, marine, and vegetable fats and oils used in the softening and stuffing of leather, as well as those used in the manufacture of products for such purpose.1.1 This test method covers determination of the solidification point of fatty acids contained in animal, marine, and vegetable fats and oils.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See 5.2 and 5.7 for additional information.

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5.1 The present and growing international governmental requirements to add FAME (biodiesel, as specified in standards such as Specification D6751 and EN 14214) to diesel fuel has had the side effect of leading to potential FAME contamination of jet turbine fuel in multifuel transport facilities such as cargo tankers and pipelines. FAME has been added as an identified incident material to Table 3 of Specification D1655 in which a permitted level of contamination is specified.5.2 This test method has been developed for use in the supply chain by nonspecialized personnel to detect all kinds of FAME covering the range of 10 mg/kg to 400 mg/kg.NOTE 3: This test method can be used to screen for unconverted esters from lipid co-hydroprocessed hydrocarbon synthetic kerosene in aviation turbine fuel. This application is detailed in X1.2.1.1 This test method covers the quantification of the fatty acid methyl esters (FAME) content in aviation turbine fuel in the range of 10 mg/kg to 400 mg/kg by measuring infrared (IR) transmission before, during, and after FAME is converted to molecules that absorb in a different spectral region than FAME using a selective chemical reaction facilitated by a suitable catalyst.NOTE 1: This test method detects all FAME components with peak IR absorbance at approximately 1749 cm-1 and C8 to C22 carbon chain length. The accuracy of this test method is based on the molecular weight of C16 to C18 FAME species. The presence of other FAME species with different molecular weights could affect the accuracy.NOTE 2: Additives such as antistatic agents, antioxidants, and corrosion inhibitors are measured with the FAME by mid IR absorption. However, these additives do not contribute to the differential absorption spectrum used to quantify FAME, as they do not take part in the selective reaction.1.2 This test method has interim repeatability precision only, see Section 15 for more information.1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific warning statements are given in Section 8.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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1.1 These test methods cover colorimetric procedures for the determination of iron in rosin tall oil fatty acids and other related products. Both spectrophotometric and visual methods are covered.1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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3.1 This test method is intended for the determination of the total desulfated matter contained in sulfated oils following their total decomposition with dilute mineral acid.1.1 This test method covers the determination of the total desulfated fatty matter in a sample of sulfated oils by decomposition with diluted mineral acids and extraction of the decomposed fat. This test method is not applicable to samples that are not completely decomposed upon boiling with mineral acids. This test method was derived from Test Methods D500, Sections 29 through 32.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 The color of a tall oil fatty acid is readily affected by heat and oxidization. Variations in degree of heat, time of heat, and exposure to atmosphere during heating have a marked effect on the color obtained; therefore, conformity to the equipment and procedure outlined in this test method is essential to accuracy and precision.1.1 This test method covers the measurement of the Gardner color of tall oil fatty acids after heating in an atmosphere of nitrogen at 205°C for one or two hours, depending on whether its iodine value is over or under 15, respectively. The specimen may be heated using either an aluminum heating block or an oil bath. This method is applicable to all tall oil fatty acids. Applicability of this method to other types of fatty acids has not been determined.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D1982-13(2022) Standard Test Method for Titer of Fatty Acids Active 发布日期 :  1970-01-01 实施日期 : 

3.1 Saturated fatty acids solidify at a higher temperature than unsaturated fatty acids. This test method provides a means of measuring the solidification temperature of a sample containing both unsaturated and saturated fatty acids by cooling the specimen and measuring the temperature at which solidification occurs.3.2 Samples containing higher levels of saturated acids will have a higher titer (solidification temperature) than those with lower levels of saturated acids.3.3 Water present in the sample will raise the titer, so provisions are made in the test method to remove traces of moisture.1.1 This test method covers the determination of the solidification (titer) point of fatty acids and is applicable to all fatty acids.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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AbstractThese test methods cover the sampling and chemical analysis of paste, powder, or liquid detergent fatty alkyl sulfates. The different procedure for sampling and chemical analysis of past, powder, or liquid detergent are presented and discussed in details. Distillation test, titration test, and gravimetric test shall be performed to meet the requirements prescribed. The calculations methods for chlorides as sodium chloride are presented in details.1.1 These test methods cover the sampling and chemical analysis of paste, powder, or liquid detergent fatty alkyl sulfates.1.2 The procedures for sampling and analysis appear in the following order:  SectionsSampling:   Powders and Flakes Packed in Cans or Cartons  4 Powders and Flakes in Bulk  5 Liquids  6 Pastes  7 Preparation of Sample  8 Moisture by the Distillation Test Method 11 – 14 pH 15 Alkalinity 16 – 19 Alcohol-Soluble Matter 20 – 22 Alcohol-Insoluble Matter 23 and 24 Unsulfated Material 25 – 28 Combined Alcohols 29 – 32Ester SO3:   Method A. Titration Test Method 36 and 37  SectionsEster SO3:   Method B. Gravimetric Test Method 38 and 39 Sodium Sulfate 40 – 43 Chlorides Calculated as Sodium Chloride (NaCl) 44 – 471.3 The values stated in either inch-pound or SI units are to be regarded separately as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The determination of group type composition of diesel fuel is useful for evaluating quality and expected performance. Aromatics and polyaromatics, in particular, are related to combustion characteristics, cetane number, energy content, lubricity, water solubility and exhaust emissions.5.1.1 Aromatic hydrocarbon type analysis may be useful for evaluating refinery processes.5.1.2 The ability to determine aromatics content in the presence of FAME may be useful to users of diesel fuel.1.1 This test method covers a standard procedure for the determination of group type totals of aromatic, polyaromatic, and FAME content in diesel fuel using gas chromatography and vacuum ultraviolet absorption spectroscopy detection (GC-VUV).1.1.1 Polyaromatic totals are the result of the summation of diaromatic and tri-plus aromatic group types. Aromatics are the summation of monoaromatic and polyaromatic group types. FAME content is the result of summation of individual fatty acid methyl esters.1.1.2 This test method is applicable for renewable diesel fuels from hydrotreated vegetable oil (HVO) or animal fat, gas to liquid (GTL) diesel, light cycle oil, wide boiling range aromatic solvents and biodiesel blends.1.2 Concentrations of group type totals are determined by percent mass or percent volume. The applicable working ranges are as follows:Total Aromatics %Volume 0.088 to 77.000Total Aromatics %Mass 0.104 to 79.451MonoAromatics %Mass 0.076 to 67.848Diaromatics %Mass 0.027 to 34.812Tri-plus aromatics %Mass 0.45 to 6.77PAH %Mass 0.028 to 41.586FAME %Volume 1.08 to 21.671.3 Diesel fuel containing biodiesel, (FAME, that is, fatty acid methyl esters including soy methyl esters, rapeseed methylesters, tallow methylesters and canola methylesters) can be analyzed by this test method. The FAME component completely elutes from the analytical column independent of feedstock.1.4 Individual hydrocarbon components are not reported by this test method; however, any individual component determinations are included in the appropriate summation of the totals of aromatic, polyaromatic, monoaromatic, diaromatic, tri-plus aromatic, or FAME groups.1.4.1 Individual components are typically not baseline-separated by the procedure described in this test method. The coelutions are resolved at the detector using VUV absorbance spectra and deconvolution algorithms.1.5 This test method may apply to other hydrocarbon streams boiling between heptane (98 °C) and triacontane (450 °C), but has not been extensively tested for such applications.1.6 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 These test methods are designed to broaden the scope of the previous edition of these test methods by the inclusion of tall oil as a test material. Test Methods D803 currently includes methods for the determination of the rosin acid and fatty acid content of crude tall oil. Test Methods D803 references Test Method D1585.4.2 Rosin and tall oil are composed primarily of rosin acids and fatty acids, and the measurement of these components is important in establishing the composition of these materials.1.1 These test methods cover the determination of the fatty acids of pine chemicals, including rosin, tall oil, and related products.1.2 These test methods may not be applicable to adducts or derivatives of rosin or other pine chemical products.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The present and growing international governmental requirements to add fatty acid methyl esters (FAME) to diesel fuel has had the unintended side-effect of leading to potential FAME contamination of jet turbine fuel in multifuel transport facilities such as cargo tankers and pipelines, and industry wide concerns.5.2 Analytical methods have been developed with the capability of measuring down to <5 mg/kg levels of FAME, however these are complex, and require specialized personnel and laboratory facilities. This Rapid Screening method has been developed for use in the supply chain by non specialized personnel to cover the range of 10 mg/kg to 150 mg/kg.1.1 This test method specifies a rapid screening method using flow analysis by Fourier transform infrared (FA-FTIR) spectroscopy with partial least squares (PLS-1) processing for the determination of the fatty acid methyl ester (FAME) content of aviation turbine fuel (AVTUR), in the range of 10 mg/kg to 150 mg/kg.NOTE 1: Specifications falling within the scope of this test method are: Specification D1655 and Defence Standard 91-91.NOTE 2: This test method detects all FAME components, with peak IR absorbance at approximately 1749 cm-1 and C8 to C22 molecules, as specified in standards such as Specification D6751 and EN 14214. The accuracy of the method is based on the molecular weight of C16 to C18 FAME species; the presence of other FAME species with different molecular weights could affect the accuracy.NOTE 3: Additives such as antistatic agents, antioxidants and corrosion inhibitors are measured with the FAME by the FTIR spectrometer. However the effects of these additives are removed by the flow analysis processing.NOTE 4: FAME concentrations from 150 mg/kg to 500 mg/kg, and below 10 mg/kg can be measured but the precision could be affected.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Biodiesel is a fuel commodity primarily used as a value-added blending component with diesel fuel.5.2 This test method is applicable for quality control in the production and distribution of diesel fuel and biodiesel blends containing FAME.5.3 The use of triglycerides in fuels is not approved for transportation applications within any ASTM specification. This test method allows the quantification of triglyceride concentration in biodiesel blends, thus enabling detection of out-of-specification blending.5.4 This test method is fast, simple to run, inexpensive and requires no sample preparation.1.1 This test method covers the determination of fatty acid methyl ester (FAME) biodiesel and triglyceride (TAG) concentrations in traditional diesel and renewable diesel fuel blends using a portable mid-infrared spectrometer.1.2 The method applies to samples with biodiesel concentrations from 3 % to 40 % by volume. Additionally, it applies to samples with biodiesel concentrations from 2 % to 27 % by volume which contain triglycerides concentrations from 1 % to 10 % by volume. Triglycerides from 2 % to 10 % by volume can be determined in samples of diesel having biodiesel concentrations from 3 % to 27 % by volume. FAME and triglyceride can be simultaneously determined outside these stated ranges, but the stated precision estimates do not apply.1.3 The method is not able to distinguish TAG and FAME if the TAG concentrations is below 0.142× the measured FAME concentrations.1.4 This procedure is not appropriate for the determination of the concentration of biodiesel in the form of fatty acid ethyl esters (FAEE), see Section 6 for further discussion of possible interferences.1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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