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5.1 HDI is mostly used in the preparation of paints. The use of isocyanates and their industrial needs have been in constant growth.5.2 Diisocyanates and polyisocyanates are irritants to skin, eyes, and mucous membranes. They are recognized to cause respiratory allergic sensitization, asthmatic bronchitis, and acute respiratory intoxication (3-6).5.3 The American Conference of Governmental Industrial Hygienists (ACGIH) has adopted a threshold limit value–time weighted average (TLV-TWA) of 0.005 ppm (V) or 0.034 mg/m3 for monomeric HDI (7). The Occupational Safety & Health Administration of the U.S. Department of Labor (OSHA) has not listed a permissible exposure limit (PEL) for HDI (8).5.4 In any case, there are not separate exposure standards for vapor and aerosol. Therefore, in comparing the results for isocyanate against a standard, results from the two fractions should be combined to give a single total value.5.5 Due to its low LOD and low required volume (15 L), this test method is well suited for monitoring of respiratory and other problems related to diisocyanates and polyisocyanates. Its short sampling times are compatible with the duration of many industrial processes, and its low detection limit with the concentrations often found in the working area.1.1 This test method covers the determination of aerosol hexamethylene diisocyanate (HDI) in air samples collected from workplace and ambient atmospheres. The method described in this test method collects separate fractions. One fraction will be dominated by vapor, and the other fraction will be dominated by aerosol. The results obtained from the analysis of the separate fractions do not necessarily represent the true partition of the measured HDI physical phases, and should only be considered a representation of the general trend in the physical phase partition within samples. The analyses of the two fractions are different, and are provided in separate, linked, standards to avoid confusion. This test method is principally used to determine short term exposure (15 min) of HDI in workplace environments for personal monitoring or in ambient air. The analysis of the vapor fraction is performed separately, as described in Test Method D6562.1.2 Differential air sampling is performed with a segregating device. The aerosol fraction is collected on a polytetrafluoroethylene (PTFE) filter.1.3 The analysis of the aerosol fraction is performed by using a high performance liquid chromatograph (HPLC) equipped with an ultraviolet (UV) detector. An ultra high performance liquid chromatograph (UPLC) can also be used, provided that its performance is equivalent to what is stated in this standard. The range of application of the test method has been validated from 0.052 to 1.04 μg of monomeric HDI/mL, which corresponds, based on a 15 L air sample, to concentrations from 0.004 to 0.070 mg/m3 of HDI. Those concentrations correspond to a range of aerosol phase concentrations from 0.5 ppb (V) to 10 ppb (V) and cover the established threshold limit valve (TLV) value of 5 ppb (V).1.4 The quantification limit for the monomeric HDI is 0.041 μg per mL, which corresponds to 0.003 mg/m3 for a 15 L sampled air volume. This value is equivalent to ten times the standard deviation obtained from ten measurements carried out on a standard solution in contact with the PTFE filter whose concentration of 0.1 μg/mL is close to the expected detection limit.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 9 for additional hazards.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 HDI is mostly used in the preparation of paints. The use of isocyanates and their industrial needs have been in constant growth.5.2 Diisocyanates and polyisocyanates are irritants to skin, eyes, and mucous membranes. They are recognized to cause respiratory allergic sensitization, asthmatic bronchitis, and acute respiratory intoxication (4-7).5.3 The American Conference of Governmental Industrial Hygienists (ACGIH) has adopted a threshold limit value – time weighted average (TLV – TWA) of 0.005 ppm (V) or 0.034 mg/m3 (8). The Occupational Safety and Health Administration of the U.S. Department of Labor (OSHA) has not listed a permissible exposure limit (PEL) for HDI (9).5.4 In any case, there are not separate exposure standards for vapor and aerosol. Therefore, in comparing the results for isocyanate against a standard, results from the two fractions should be combined to give a single total value.5.5 Due to its low LOD and low required volume (15 L), this test method is well suited for monitoring of respiratory and other problems related to diisocyanates and polyisocyanates. Its short sampling times are compatible with the duration of many industrial processes, and its low detection limit with the concentrations often found in the working area.1.1 This test method covers the determination of gaseous hexamethylene diisocyanate (HDI) in air samples collected from workplace and ambient atmospheres. The method described in this test method collects separate fractions. One fraction will be dominated by vapor, and the other fraction will be dominated by aerosol. The results obtained from the analysis of the separate fractions do not necessarily represent the true partition of the measured HDI physical phases, and should only be considered a representation of the general trend in the physical phase partition within samples. The analyses of the two fractions are different, and are provided in separate, linked, standards to avoid confusion. This test method is principally used to determine short term exposure (15 min) of HDI in workplace environments for personal monitoring or in ambient air. The analysis of the aerosol fraction is performed separately, as described in Test Method D6561.1.2 Differential air sampling is performed with a segregating device. The vapor fraction is collected on a glass fiber filter (GFF) impregnated with 9-(N-methylaminomethyl) anthracene (MAMA).1.3 The range of application of this test method has been validated from 0.006 to 1.12 μg of monomeric HDI/2.0 mL of desorption solution, which corresponds to concentrations equivalent to 0.0004 to 0.075 mg/m3 of HDI based on a 15 L air sample. Those concentrations correspond to a range of vapor phase concentrations from 0.06 ppb(V) to 11 ppb(V) and cover the established threshold limit value (TLV) value of 5 ppb(V).1.4 The quantification limit for the monomeric HDI, using the UV detection, has been established as 0.012 μg/2 mL of desorption solution and as 0.008 μg/2 mL, using the fluorescence detector. These limits correspond to 0.0008 mg/m3 and 0.0005 mg/m3 respectively for an air sampled volume of 15 L. These values are equal to ten times the standard deviation (SD) obtained from ten measurements carried out on a standard solution in contact with the GFF, whose concentration of 0.02 μg/2 mL is close to the expected detection limit.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See Section 9 for additional hazards.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Respirable crystalline silica is a hazard to the health of workers in many industries who are at risk through exposure by inhalation. Industrial hygienists and other public health professionals need to determine the effectiveness of measures taken to control workers’ exposure, and this is generally achieved by taking workplace air measurements. This standard has been published in order to make available a method for making valid exposure measurements for crystalline silica exposures in industry. It will be of benefit to: agencies concerned with health and safety at work; industrial hygienists and other public health professionals; analytical laboratories; industrial users of silica-containing products and their workers, etc.5.2 This standard specifies a generic sampling and analytical method for measurement of the mass concentration of respirable crystalline silica in workplace air using infrared (IR) spectrometric methods. Several different types of sampling apparatus are used to collect respirable dust, according to the occupational hygiene sampling convention. This standard is designed to accommodate a variety of appropriate samplers and sampling materials that are commercially available.1.1 This standard specifies a test method for collection and analysis of samples of airborne particulate matter for measurement of respirable crystalline silica by infrared (IR) spectrometry.1.2 This test method is applicable to the analysis of crystalline silica (the polymorphs quartz, cristobalite and tridymite) over a working range of 0.025 to 0.4 mg/m3 for a 400 L air sample or 0.02 to 0.25 mg/m3 for a 1000 L air sample, depending on the analytical method.1.3 The methodology is applicable to personal sampling of the respirable fraction of airborne particles and to static (area) sampling.1.4 This test method describes three different procedures for sample preparation and infrared analysis of airborne crystalline silica samples, which are delineated in Annex A1 – Annex A3, respectively: (1) a potassium bromide (KBr) disc IR measurement method, (2) indirect IR analysis after redeposition onto a filter used for measurement, and (3) direct on-filter IR analysis.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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The SCCW may be present in the workplace atmosphere where these materials are manufactured, processed, transported, or used. This test method can be used to monitor airborne concentrations of fibers in these environments. It may be employed as part of a personal or area monitoring strategy.This test method is based on morphology, elemental composition, and crystal structure. The analysis technique has the ability to positively identify SCCW.Note 1—This test method assumes that the analyst is familiar with the operation of TEM/EDS instrumentation and the interpretation of data obtained using these techniques.This test method is applicable for the measurement of the total population of SCCW fibers including fibers with diameters ≤0.1 μm.Results from the use of this test method shall be reported along with 95 % confidence limits for the samples being studied. Individual laboratories shall determine their intralaboratory coefficient of variation and use it for reporting 95 % confidence limits (2,5,6).1.1 This test method covers the sampling methods and analysis techniques used to assess the airborne concentration and size distribution of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used. This test method is based on the filtration of a known quantity of air through a filter. The filter is subsequently evaluated with a transmission electron microscope (TEM) for the number of fibers meeting appropriately selected morphological and compositional criteria. This test method has the ability to distinguish among different types of fibers based on energy dispersive X-ray spectroscopy (EDS) analysis and selected area electron diffraction (SAED) analysis. This test method may be appropriate for other man-made mineral fibers (MMMF).1.2 This test method is applicable to the quantitation of fibers on a collection filter that are greater than 0.5 μm in length, less than 3 μm in width, and have an aspect ratio equal to or greater than 5:1 (1). The data are directly convertible to a statement of concentration per unit volume of air sampled. This test method is limited by the amount of coincident interference particles.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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The SCCW may be present in the workplace atmosphere where these materials are manufactured, processed, transported, or used. This test method can be used to monitor airborne concentrations of fibers in these environments. It may be employed as part of a personal or area monitoring strategy.This test method is based on dimensional considerations only. As such, it does not provide a positive identification of the fibers counted. Analysis by SEM or TEM is required when additional fiber identification information is needed.Note 1—This test method assumes that the analyst is familiar with the operation of PCM instrumentation and the interpretation of data obtained using this technique.This test method is not appropriate for measurement of fibers with diameters less than approximately 0.25 μm due to visibility limitations associated with PCM. The SEM or TEM methods may be used to provide additional size information of SCCW if needed (refer to Practice D6058 for additional information on the use of these methods).Results from the use of this test method shall be reported along with 95 % confidence limits for the samples being studied. Individual laboratories shall determine their intralaboratory coefficient of variation and use it for reporting 95 % confidence limits (1,3,4).1.1 This test method covers the sampling methods and analysis techniques used to assess the airborne concentration of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used. This test method is based on the collection of fibers by filtration of a known quantity of air through a filter. The filter is subsequently evaluated with a phase contrast microscope (PCM) for the number of fibers meeting appropriately selected counting criteria. This test method cannot distinguish among different types of fibers. This test method may be appropriate for other man-made mineral fibers (MMMF).1.2 This test method is applicable to the quantitation of fibers on a collection filter that are greater than 5 μm in length, less than 3 μm in width, and have an aspect ratio equal to or greater than 5:1. The data are directly convertible to a statement of concentration per unit volume of air sampled. This test method is limited by the diameter of the fibers visible by PCM (typically greater than 0.25 μm in width) and the amount and type of coincident interference particles.1.3 A more definitive analysis may be necessary to confirm the identity and dimensions of the fibers located with the PCM, especially where other fiber types may be present. Such techniques may include scanning electron microscopy (SEM) or transmission electron microscopy (TEM). The use of these test methods for the identification and size determination of SCCW is described in Practice D6058 and Test Methods D6059 and D6056.1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 The SCCW may be present in the workplace atmosphere where these materials are manufactured, processed, transported, or used. The test methods discussed in this practice can be used to provide guidance when monitoring airborne concentrations of SCCW in these environments.5.2 Because of their visibility limitations, a significant fraction of the very small thin fibers that are present in some samples may not be detected by PCM or SEM. Therefore, TEM is considered to be the reference technique for the analysis of airborne SCCW. The TEM must be used to determine both fiber count and morphology when samples are from previously uncharacterized workplaces or materials.5.3 Although TEM is the reference technique, PCM or SEM are considered to be the primary screening methods for the analysis of airborne SCCW.5.4 Parallel TEM measurements shall be carried out, at least initially, to provide an index or relative measure of the fraction of total fibers that are seen by PCM or SEM. Only in instances when this percentage has been shown to be at a high and reproducible level may the lower resolution techniques (that is, PCM or SEM) be relied on exclusively.1.1 This practice is intended to assist individuals in the sampling and analysis of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, in the workplace environment. It describes sampling and analytical techniques used to assess the airborne concentration and size distribution of SCCW, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used.1.2 The protocols currently in use for asbestos and other fibrous materials have been used as a guide in developing sampling and analytical procedures for characterizing fibers produced from the manufacture and use of SCCW. The sampling and analysis protocols described here have been written specifically for SCCW, however, they may be appropriate for other man-made mineral fibers (MMMF).1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 The health of workers in many industries is at risk through exposure by inhalation to toxic metals. Industrial hygienists and other public health professionals need to determine the effectiveness of measures taken to control workers' exposures, and this is generally achieved by making workplace air measurements. Exposure to some metal-containing particles has been demonstrated to cause dermatitis, skin ulcers, eye problems, chemical pneumonitis, and other physical disorders (16).35.2 FAAS is capable of quantitatively determining many metals in air samples at the levels required by federal, state, and local occupational health and air pollution regulations. The analysis results can be used for the assessment of workplace exposures to metals in workplace air. The suitability of FAAS for elemental analysis for exposure assessment purposes must be investigated prior to carrying out workplace air sampling, in consideration of relevant occupational exposure limit values (OELVs) for metals of concern.1.1 This test method covers the collection, dissolution, and determination of trace metals in workplace atmospheres, by flame atomic absorption spectrophotometry (FAAS).1.2 The estimated method detection limits and optimum working concentration ranges for 21 metals are given in Table 1.1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. (Specific safety precautionary statements are given in Section 9.)1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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The SCCW may be present in the workplace atmosphere where these materials are manufactured, processed, transported, or used. This test method can be used to monitor airborne concentrations of SCCW fibers in these environments. It may be employed as part of a personal or area monitoring strategy.This test method is based on morphology and elemental composition. The analysis technique has the ability to identify SCCW.Note 1—This test method assumes that the analyst is familiar with the operation of SEM/EDS instrumentation and the interpretation of data obtained using these techniques.This test method is not appropriate for measurement of fibers with diameters ≤0.10 to 0.25 μm due to visibility limitations associated with SEM. The TEM method may be used to provide additional size information of SCCW if needed (see Practice D6058 for additional information on the use of this test method).Results from the use of this test method shall be reported along with 95 % confidence limits for the samples being studied. Individual laboratories shall determine their intralaboratory coefficient of variation and use it for reporting 95 % confidence limits (1,3,4).1.1 This test method covers the sampling methods and analysis techniques used to assess the airborne concentration and size distribution of single-crystal ceramic whiskers (SCCW), such as silicon carbide and silicon nitride, which may occur in and around the workplace where these materials are manufactured, processed, transported, or used. This test method is based on the collection of fibers by filtration of a known quantity of air through a filter. The filter is subsequently evaluated with a scanning electron microscope (SEM) for the number of fibers meeting appropriately selected morphological and compositional criteria. This test method has the ability to distinguish among many different types of fibers based on energy dispersive X-ray spectroscopy (EDS) analysis. This test method may be appropriate for other man-made mineral fibers (MMMF).1.2 This test method is applicable to the quantitation of fibers on a collection filter that are greater than 5 μm in length, less than 3 μm in width, and have an aspect ratio equal to or greater than 5:1. The data are directly convertible to a statement of concentration per unit volume of air sampled. This test method is limited by the diameter of the fibers visible by SEM (typically greater than 0.10 to 0.25 μm in width as determined in 12.1.5) and the amount of coincident interference particles.1.3 A more definitive analysis may be necessary to confirm the presence of fibers with diameters ≤0.10 to 0.25 μm in width. For this purpose, a transmission electron microscope (TEM) is appropriate. The use of the TEM method for the identification and size measurement of SCCW is described in Practice D6058 and Test Method D6056.1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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5.1 Airborne hexavalent chromium is carcinogenic (1-3),4 and analytical methods for the measurement of this species in workplace aerosols are desired. Worker exposure to hexavalent chromium occurs primarily through inhalation (1-3), and this test method provides a means for exposure assessment to this highly toxic species. Analytical results from this procedure can be used for regulatory compliance purposes (4).1.1 This test method specifies a method for the determination of the time-weighted average mass concentration of hexavalent chromium in workplace air samples.1.2 This test method is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708, and to area (static) sampling.1.3 The sample dissolution procedure specifies separate procedures for soluble and insoluble hexavalent chromium.1.4 This test method is applicable to the determination of masses of 0.01 μg to 10 μg of hexavalent chromium per sample without dilution.1.5 The concentration range for hexavalent chromium in air for which this procedure is applicable is approximately 0.1 μg/m3 to 100 μg/m3, assuming 1 m3 of air sample. The range can be extended upwards by appropriate dilution.1.6 Interconversion of trivalent and hexavalent chromium species may occur during sampling and sample preparation, but these processes are minimized to the extent possible by the sampling and sample preparation procedures employed.1.7 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The capability of this test method to collect and quantitate both particulate and gaseous fluorides over the ranges normally encountered in industrial atmospheres makes it applicable for industrial hygiene evaluation and control purposes. The recommended range of this test method is from 0.005 to 5 mg F−/m3 air.1.1 This test method covers the simultaneous collection and separate measurements of gaseous fluoride (for example, hydrogen fluoride) and particulate fluoride found in certain industrial workplaces. The gaseous fluorides and particulate fluorides collected are reported in terms of fluoride. The method covers sample collection, preparation, and fluoride measurement.1.2 The procedure is not applicable to the collection or analysis of gaseous fluoro compounds (for example, fluorocarbon or fluorosulfur compounds).1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Vinyl chloride monomer (VCM) is the starting material for the manufacture of poly(vinyl chloride) (PVC), which is used extensively in construction, electronics, packaging, and other industries. The vinyl chloride gas can escape during manufacturing, transportation, and polymerization stages. Residual monomer can also escape during subsequent fabrication processes.5.2 Vinyl chloride is a toxic and explosive hazardous material.5.3 Vinyl chloride is suspected to be a carcinogenic agent (4), and occupational exposure limits (OELs) have been established for this agent. For instance, the present U.S. Occupational Safety and Health Administration (OSHA) permissible exposure limit (PEL) for VCM is 1.0 ppm (v) with a 0.5-ppm (v) action level; the maximum length of operator exposure at 5 ppm (v) is 15 min (5).5.4 This test method is made selective for vinyl chloride by choosing chromatographic columns that will separate vinyl chloride from other organic compounds in the sample.5.5 This test method meets requirements (for example, those of OSHA and NIOSH) for monitoring workplace atmospheres in vinyl chloride and poly(vinyl chloride) production and fabrication processes.1.1 This test method describes the determination of vinyl chloride monomer (VCM) in workplace atmospheres using a modified charcoal tube method (see Practice D3686).1.2 This procedure is compatible with low-flow rate personal sampling equipment. It can be used for personal or stationary monitoring. It cannot be used to determine instantaneous fluctuations in concentration to detect maximum values. Alternative on-site procedures, such as gas chromatography or infrared spectrometry, are required to measure fast-changing concentrations.1.3 The range of this test method is from the limit of quantitation approximately 0.03 to 100 ppm (v).1.4 The sampling method provides a time-weighted average sample.1.5 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For more specific precautionary statements, see Section 9, 10.2.3, and 11.1.3.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Most oxides of nitrogen are formed during high-temperature combustion. The U.S. Environmental Protection Agency (EPA) has set primary and secondary air quality standards for NO2 that are designed to protect the public health and the public welfare (40 CFR, Part 50).5.2 Oxides of nitrogen are generated by many industrial processes that can result in employee exposures. These are regulated by the Occupational Safety and Health Administration (OSHA), which has promulgated exposure limits for the industrial working environment (29 CFR, Part 1910).5.3 These test methods have been found to be satisfactory for measuring oxides of nitrogen in ambient and workplace atmospheres over the ranges shown in 1.1.1.1 These test methods cover procedures for the continuous determination of total nitrogen dioxide (NO2) and nitric oxide (NO) as NOx, or nitric oxide (NO) alone or nitrogen dioxide (NO2) alone, in the ranges shown in the following table:  Approximate Range of Concentration(25°C and 101.3 kPa (1 atm))     Gas Ambient Atmosphere Workplace Atmosphere  μg/m3 (ppm) mg/m3 (ppm)     NO 10 to 600 (0.01 to 0.5) 0.6 to 30 (0.5 to 25)(NO + NO2) = NOx 20 to 1000 (0.01 to 0.05) 1 to 50 (0.5 to 25) NO2 20 to 1000 (0.01 to 0.5) 1 to 50 (0.5 to 25) 1.2 The test methods are based on the chemiluminescent reaction between nitric oxide and ozone.1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section 9.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Asphalt is a material used in the construction of roads and as a roofing material and sealant.5.2 This test method provides a means of evaluating exposure to asphalt fume in the working environment at the presently recommended exposure guidelines (for example, Threshold Limit Values and Biological Exposure Indices, ACGIH).75.3 This procedure has been adapted from NIOSH Method 5023 (withdrawn prior to 4th edition (1994) and replaced in 1998 with NIOSH Method 5042) and OSHA Method 58 to reduce the level of background contamination providing better reproducibility.1.1 This test method covers the determination of asphalt fume particulate matter (as benzene soluble fraction) and total particulate matter weight in workplace atmospheres using a polytetrafluoroethylene (PTFE) filter methodology.1.2 This procedure has been adapted from NIOSH Method 5023 (withdrawn prior to 4th edition (1994) and replaced in 1998 with NIOSH Method 5042) and OSHA Method 58. This adaptation was made to reduce the level of background contamination providing better reproducibility.1.3 This procedure is compatible with high flow rate personal sampling equipment–0.5 to 2.0 L/min. It can be used for personal or area monitoring.1.4 The sampling method develops a time-weighted average (TWA) sample and can be used to determine short-term exposure limit (STEL).1.5 The applicable concentration range for the TWA sample is from 0.2 to 2.0 mg/m3.NOTE 1: A study has suggested candidate solvents for benzene replacement.2 A less toxic solvent for this analysis would be more appropriate, although the substitution with a solvent other than benzene needs further validations with field data.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For more specific precautionary statements, see Section 9.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Ethylene oxide is a major raw material used in the manufacture of numerous other bulk industrial chemicals, and is also used as a sterilizing agent.This test method provides a means of evaluating exposure to ethylene oxide in the working environment. Examples of recommended occupational exposure limits (OELs) include: a U.S. Occupational Safety and Health Administration (OSHA) personal exposure limit (PEL) of 1 ppm(v) (8-h TWA) and an American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) of 1 ppm(v).1.1 This test method describes the determination of ethylene oxide (oxirane) in workplace atmospheres using charcoal tube sampling methodology. Subsequent analysis is carried out by gas chromatography.1.2 This test method is compatible with low flow rate personal sampling equipment: 10 to 200 mL/min. It can be used for personal or area monitoring.1.3 The sampling method develops a time-weighted averaged (TWA) sample and can be used to determine short-term excursions (STE).1.4 The applicable concentration range for the TWA sample is from 0.3 to 20 ppm(v).1.5 The applicable concentration range for the STE sample ranges from 1 to 1000 ppm(v).1.6 The values stated in SI units shall be regarded as the standard. Inch-pound units are provided for information only.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. (For more specific safety precautionary statements see Section 9 and 10.2.3 and 11.1.3.)

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