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5.1 This standard is useful for characterizing the wettability of surfaces. A surface that is easy to wet is one over which a coating is more likely to give good adhesion and appearance and less likely to suffer surface tension related defects such as crawling, cratering, pinholing and orange peel.5.2 This standard also can be used to test pigment surfaces for wettability, particularly by potential surfactant- or resin-based dispersants or mill bases. Easily wetted pigments are more likely to be easy to disperse and dispersants/mill bases that wet pigments of interest are more likely to disperse those pigments well.5.3 Although the contact angle is governed by the surface tensions of the test liquid and test surface, the angle cannot provide a surface tension value directly.5.4 A low advancing contact angle value (<45°) is indicative of wetting and angles of 10 to 20° are indicative of excellent wetting.5.5 Water can be used as a test liquid to establish (via the advancing contact angle) whether a surface is hydrophilic (angle <45°), hydrophobic (angle >90°) or somewhere in-between (angle of 45 to 90°). Water contact angles have been used to estimate surface cleanliness before and after cleaning operations, ease of wettability of surfaces by waterborne coatings and the effectiveness of rinsing processes.5.6 An organic liquid such as a solvent also can be used to characterize a substrate, coating or pigment. The resultant contact angle will depend on the surface tensions of the liquid and the test surface. A low surface tension (energy) test surface will not be wet by a high surface tension liquid.5.7 In addition to water and solvents, a surfactant dispersion or dispersant solution can be used to test a pigment surface. Any test liquid that is a potential dispersant for a test pigment must wet the pigment well or it will not work as a dispersant.5.8 Contact angle measurements can be used to map surfaces in terms of hydrophilicity, presence of low surface tension components or contaminants, or variations in composition. Other analytical methods such as infrared microscopy would be needed to identify the chemical moieties that give the contact angle differences.5.9 This test method can be used on nearly all coatings and substrates and may be extended to pigments by compressing the pigment powder into a solid disk.1.1 This practice covers the measurement of the angle of contact when a drop of liquid is applied to a coated surface, substrate, or preformed disk of pigment.1.2 There are two types of contact angles, advancing and receding. This standard deals only with advancing contact angles.1.3 This practice is intended to supplement the manufacturer’s instructions for the device being used to make the measurements, but is not intended to replace them.1.4 A common test liquid is water, but many other liquids such as solvents, surfactant and dispersant solutions and even liquid paints can be used.1.5 This practice is based on goniometry, which involves the observation of a sessile drop of test liquid on a solid substrate.1.6 Although contact angles are governed by surface tension, this standard cannot be used to measure surface tension directly.1.7 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.9 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Color and tinting strength are the most important properties of a color pigment. This test method provides a means of testing these properties for quality control.5.2 This test method is intended as a referee method so that such matters as the vehicle for preparing the dispersions and the white for making tints have been suggested. However, other vehicles and whites may be suitable for quality control purposes, and changes in this test method are allowed by agreement between the parties to a test.5.3 It is assumed that the most exact comparison of mass color and tinting strength occurs when the pigment is completely dispersed. By following the procedure described in Annex A1, the conditions for achieving the maximum practical degree of dispersion with a mechanical muller may be determined. Color and strength tests should be carried out under these conditions.5.4 The results obtained with a mechanical muller do not necessarily correlate directly with an industrial situation where different dispersing conditions exist. However, dispersion with a mechanical muller is a quick and inexpensive way of testing the color and strength of a pigment for routine quality control.1.1 This test method is intended to be used to compare the color and strength of a pigment under test with a reference standard of the same type and grade.1.2 This test method does not apply to white pigments.NOTE 1: Test Method D3022 is similar to this test method, but it utilizes a miniature sandmill rather than a mechanical muller, to disperse the chromatic pigment.NOTE 2: Test Method D332 and Test Method D2745 are similar to this test method, but they are intended for use with white pigments, rather than chromatic pigments.1.3 The values stated in SI units are the preferred unit of measurement. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 8.

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ASTM D602-81(2019) Standard Specification for Barium Sulfate Pigments Active 发布日期 :  1970-01-01 实施日期 : 

This specification covers the barium sulfate pigments commercially known as barytes and blanc fixe. The pigment shall consist of barium sulfate (BaSO4) without any admixture of other materials in the case of blanc fixe, and without any admixture of other materials not naturally occurring in the barite ore in the case of barytes. The pigments shall be subjected to the following tests: coarse particle test, moisture test, barium sulfate test, ferric oxide test, free silica test, hydrogen ion concentration, and matter water solubility test.1.1 This specification covers the barium sulfate pigments commercially known as barytes and blanc fixe.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 These test methods are suitable for determining if impurities are present and establishing that the required pigments are present. These test methods may be used for manufacturing and purchasing quality control.1.1 These test methods cover procedures for the qualitative chemical analysis of pigments known commercially as copper phthalocyanine blue and green.1.2 The procedures appear in the following order:  SectionIdentification 5Moisture and Other Volatile Matter 6Detection of Basic Dye Derivatives 7Detection of Other Organic Coloring Matter 8Detection of Ultramarine Blue 9Detection of Iron Blue or Chrome Green 101.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D6280-98(2020) Standard Specification for Zinc Phosphate Pigments Active 发布日期 :  1970-01-01 实施日期 : 

This specification covers three types of pigments commercially known as zinc phosphate each of which may or may not be available in specific grades delineated by particle size or oil absorption. The following types of pigments are: Type I which is zinc phosphate, dihydrate predominant, Type II which is zinc phosphate, dihydrate tetrahydrate mixture, and Type III which is zinc phosphate, tetrahydrate predominant. Zinc phosphate functions as both a chemical and a pigment. As a pigment it is used in a variety of applications including that of corrosion inhibiting paints. The pigments shall be subjected to the following tests: specific gravity test, oil absorption test, Hegman grind test, coarse particles test, pH test, specific resistance test, moisture test, and loss on ignition test.1.1 This specification covers three types of pigments commercially known as zinc phosphate each of which may or may not be available in specific grades delineated by particle size or oil absorption.1.1.1 Type I—Zinc Phosphate, dihydrate predominant.1.1.2 Type II—Zinc Phosphate, dihydrate tetrahydrate mixture.1.1.3 Type III—Zinc Phosphate, tetrahydrate predominant.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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3.1 These test methods are suitable for determining the level of purity and for determining the levels of various impurities. They may be used to establish compliance with specification requirements.1.1 These test methods cover procedures for the chemical analysis of basic carbonate white lead and basic sulfate white lead.NOTE 1: If it is necessary to separate these pigments from others, refer to Practice D215.1.2 The analytical procedures appear in the following order:  Section Preparation of Sample  6Basic Carbonate White Lead:   Small Amounts of Iron  7 Total Lead  8 Moisture and Other Volatile Matter  9 Carbon Dioxide (Evolution Method) 10 Carbon Dioxide and Combined Water (Combustion Method) 11 Lead Carbonate 12 Total Matter Insoluble in Acetic Acid 13 Total Matter Insoluble in Acid Ammonium Acetate 14 Total Impurities Other Than Moisture 15 Coarse Particles 16Basic Sulfate White Lead:   Small Amounts of Iron 17 Total Lead   Moisture and Other Volatile Matter 19 Total Sulfate 20 Zinc Oxide 21 Basic Lead Oxide 22 Total Impurities 23 Coarse Particles 241.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D603-66(1996)e1 Standard Specification for Aluminum Silicate Pigments (Hydrous) (Withdrawn 2004) Withdrawn, No replacement 发布日期 :  1970-01-01 实施日期 : 

1.1 This specification covers the white pigments that consist substantially of natural hydrous aluminum silicate (of the 1:1 layer type), and are restricted to those minerals which conform to the chemical limits prescribed herein and which can be suitably processed to what is commercially known as paint pigment quality.

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ASTM D763-06(2019) Standard Specification for Raw and Burnt Umber Pigments Active 发布日期 :  1970-01-01 实施日期 : 

This specification covers raw and burnt umber pigments. The pigments could be in a dry or paste in oil form. Dry pigments should conform to the composition requirements for iron oxide content, calcium compound content, moisture and other volatile matter content, coarse particle content, and organic color content. Raw umber dry pigments should be in a soft, dry form and made from a hydrated iron oxide permeating a siliceous base and free of admixtures. Burnt umber dry pigments should be produced by raw amber calcination and free of admixtures. Paste in oil pigments should conform to the specified pigment content, nonvolatile vehicle content, moisture by distillation content, and coarse particle and skin content. Both raw and burnt umber paste in oil pigments should be made by thoroughly grinding the pigment with linseed oil with a small amount of wetting or dispersing agents.1.1 This specification covers the pigments commercially known as raw umber and burnt umber.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D153-84(2020) Standard Test Methods for Specific Gravity of Pigments Active 发布日期 :  1970-01-01 实施日期 : 

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4.1 White zinc pigments find considerable use in white paints, and as such it is useful to formulators and users to be able to monitor the amounts of these pigments in whole paints. It is also of interest to raw material suppliers and paint producers to check the specifications of each pigment.1.1 These test methods cover procedures for the analysis of white zinc pigments.1.2 The analytical procedures appear in the following order:  SectionPreparation of Sample  6 Zinc OxideTotal Zinc, Using Diphenylamine as Internal Indicator  7 Total Zinc, Using Uranyl Acetate as External Indicator  8 Total Impurities  9 Total Sulfur 10Moisture and Other Volatile Matter 11Leaded Zinc OxideTotal Lead 12Total Zinc 13Total Sulfur 14Total Impurities 15Moisture and Other Volatile Matter 16Water-Soluble Salts 17Zinc SulfideZinc Oxide 18Zinc Sulfide 19Water-Soluble Salts 20Moisture and Other Volatile Matter 21Barium Sulfate 22Titanium Dioxide 231.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D79-86(2020) Standard Specification for Zinc Oxide Pigments Active 发布日期 :  1970-01-01 实施日期 : 

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ASTM D3619-77(1996)e1 Standard Specification for Aluminum Silicate Pigments (Anhydrous) (Withdrawn 2004) Withdrawn, No replacement 发布日期 :  1970-01-01 实施日期 : 

1.1 This specification covers the white pigments that consist substantially of anhydrous (calcined) natural aluminum silicates (of the 1+1 layer type) and are restricted to those minerals which conform to the chemical compositional limits prescribed herein and which can be suitably processed to what is known as paint pigment quality.

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ASTM D765-87(2020) Standard Specification for Raw and Burnt Sienna Pigments Active 发布日期 :  1970-01-01 实施日期 : 

This specification establishes the properties and requirements for the pigments commercially known as raw sienna and burnt sienna in the dry and paste in oil forms. The dry pigments shall be sampled and tested as appropriate, and conform accordingly to composition requirements as to iron oxide, calcium compounds, moisture and other volatile matter, coarse particles (total residue retained on a No. 325 sieve), and organic colors. The pigments in paste in oil form shall conversely be tested and conform to composition requirements as to pigment, nonvolatile vehicle, moisture by distillation, and coarse particles (total residue retained on a No. 325 sieve). Both forms shall adhere to specified mass color, tint character, and tinting strength requirements as well.1.1 This specification covers the pigments commercially known as raw sienna and burnt sienna.1.2 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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