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This test method details the standard procedure for measuring the viscosity of resin solutions. The apparatuses required here are constant-temperature water bath, wide-mouthed screw capped bottles, cellophane sheets, No. 2 short taper corks, viscosity tube holder, bottle shaker, timing device, and viscosity tubes. Solid resins are dissolved in organic solvents by cold-cut or hot-cut methods in the laboratory. The viscosity of such prepared solutions, or of commercial solutions of resins is then determined by the bubble time method. The bubble seconds are approximately equal to stokes.1.1 This practice provides instructions for preparing resin solutions viscosity measurement by bubble time method.1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This test method is used to measure the apparent viscosity of thermoplastic pavement marking at elevated temperatures. Elevated temperature viscosities of thermoplastic pavement marking may be related to the properties of coatings, adhesives, and composite thermoplastics. This method is helpful in determining the flow properties which can be used in determining processability when applied to the road surface.5.2 Thermoplastic pavement markings may be applied to the road surface in several different ways. Typical methods of application are screed extrude, ribbon extrude, thin film spray, and standard spray. Proper application depends on the viscosity of the thermoplastic material at application temperatures for the method being used. Thin-line applied thermoplastic pavement marking, for example, requires a relatively lower viscosity. Screed extrude applied thermoplastic requires a higher viscosity.5.3 Materials of the type described in this procedure may be non-Newtonian, and as such, the apparent viscosity will be a function of shear rate under the conditions of test. Although the viscometer described in this test method operates under conditions of relatively low shear rate, differences in shear effect can exist depending upon the spindle and rotational speed conditions selected for the test program. Comparisons between non-Newtonian viscosity values should be made only for measurements made with similar viscometers under conditions of equivalent shear. For this method, “torpedo” spindles are recommended. Spindles considered torpedo spindles are ~1-in. long and come in many diameters with a 45° conical bottom. A diameter that is half the diameter of the thimbles used is recommended. If large glass beads are used in the pavement marking formulation, a smaller diameter spindle may be needed so the beads do not cause an impedance of the spindle due to a jamming between the inside wall of the thimble and the spindle.1.1 This test method covers the sample preparation and testing procedure needed to determine the apparent viscosity of a thermoplastic pavement marking formulation at elevated temperatures to the specimen.1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are customary units and are provided as a courtesy to the user.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 These test methods are intended for use as control and acceptance tests. They are also applicable in the partial evaluation of materials for specific end uses and as a means for detecting changes in materials due to specific deteriorating causes.4.2 The steps involved in running this method are:4.2.1 Calibration of the viscometers,4.2.2 Preparation of solutions,4.2.3 Determination of efflux time,4.2.4 Calculation of relative viscosity (which requires the following),4.2.4.1 Determining the density of the polymer/formic acid solution, and4.2.4.2 Determining the absolute viscosity of the formic acid used.4.3 Solvents used to prepare concentrated solutions for use in this test method are formic acid (9.2.6.1) and m-cresol (9.2.6.2).4.4 Solvents used to prepare dilute solutions of various polyamides are designated in ASTM D6779, ISO 16396, and ISO 307. These include:4.4.1 Formic Acid—PA 6, PA 46, PA 66, PA 69, PA 610, PA MXD6 and corresponding copolyamides4.4.2 Sulfuric Acid—PA 6, PA 46, PA 66, PA 69, PA 610, PA 612, PA MXD6 and corresponding copolyamides4.4.3 m-cresol—PA 612, PA1010, PA1012, PA 11, PA 12, PA1212, PA 11/12 copolymers, PA 6T/66, PA 6I/66, PA 6I/6T, PA 6T/6I/66, PA 6T/6I, PA 6I/6T/664.4.4 Phenol/1,1,2,2-tetrachloroethane (where legal)—PA 6T/66, PA 6I/66, PA 6I/6T, PA 6T/6I/66, PA 6T/6I, PA 6I/6T/66, PA 6T/66, PA 6I/66, PA 6I/6T, PA 6T/6I/66, PA 6T/6I, PA 10T PA 6I/6T/66, PPA and copolyamides1.1 This test method covers the determination of relative viscosity as it applies to concentrated solutions of polyamide (PA).1.2 This test method does not address measures of viscosity derived from measurements with dilute solutions.1.3 The values stated in SI units are to be regarded as standard. The values given in brackets are for information only.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.NOTE 1: This standard and ISO 307 address the same subject, buy the technical content is different.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The logarithmic viscosity number provides information on the effect of compounding or processing of PVC.5.2 Exposure of PVC compositions to shear or to high temperatures can result in a change in the logarithmic viscosity number of the resin.1.1 This test method covers the determination of the logarithmic viscosity number of poly(vinyl chloride) (PVC) homopolymers after compounding or processing.1.2 It is the basic assumption of this technique that the formulation of the compounded resin is known and that any additives present can be separated from the resin by extraction with diethyl ether. This is necessary to permit adjustment of the amount of sample used in the test to give a resin concentration in cyclohexanone of 0.2 ± 0.002 g/100 mL.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 7.3 and 8.4.1.NOTE 1: This test method and ISO 1628-2 are not equivalent.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 At one time the petroleum industry relied on measuring kinematic viscosity by means of the Saybolt viscometer, and expressing kinematic viscosity in units of Saybolt Universal Seconds (SUS) and Saybolt Furol Seconds (SFS). This practice is now obsolete in the petroleum industry.4.2 This practice establishes the official equations relating SUS and SFS to the SI kinematic viscosity units, mm2/s.4.3 This practice allows for the conversion between SUS and SFS units and SI units of kinematic viscosity.1.1 This practice2 covers the conversion tables and equations for converting kinematic viscosity in mm2/s at any temperature to Saybolt Universal viscosity in Saybolt Universal seconds (SUS) at the same temperature and for converting kinematic viscosity in mm2/s at 122 °F and 210 °F (50 °C and 98.9 °C) to Saybolt Furol viscosity in Saybolt Furol seconds (SFS) at the same temperatures. Kinematic viscosity values are based on water being 1.0034 mm2/s (cSt) at 68 °F (20 °C).1.2 If a method other than Test Method D445 is used to generate the kinematic viscosity data, apply appropriate relative-bias correction factors as found in the precision section of that method, before performing the calculations of this practice.NOTE 1: The equations in D2161 were originally empirically derived using data from both D445 and the Saybolt viscometer method. Therefore, it is conceivable that an error could result if the kinematic viscosities used are not bias-corrected to D445 results. It is recommended that kinematic viscosity be reported in millimetres squared per second, instead of Saybolt Universal Seconds (SUS) or Saybolt Furol Seconds (SFS). This method is being retained for the purpose of calculation of kinematic viscosities from SUS and SFS data that appear in past literature. One millimetre squared per second (mm2/s) equals one centistoke (cSt), which is another unit commonly found in older literature.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are provided for reference information purposes only. The SI unit of kinematic viscosity is mm2/s.1.3.1 Exception—Fahrenheit temperature units are used in this practice because they are accepted by industry for the type of legacy conversions described in this practice.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Because there are surface tension or kinematic viscosity differences, or both, between the primary standard (7.4) and kinematic viscosity standards (7.5), special procedures using master viscometers are required to “step-up” from the kinematic viscosity of the primary standard to the kinematic viscosities of oil standards.5.2 Using master viscometers calibrated according to this practice, an operator can calibrate kinematic viscometers in accordance with Specifications D446.5.3 Using viscosity oil standards established in this practice, an operator can calibrate kinematic viscometers in accordance with Specifications D446.1.1 This practice covers the calibration of master viscometers and viscosity oil standards, both of which may be used to calibrate routine viscometers as described in Test Method D445 and Specifications D446 over the temperature range from 15 °C to 100 °C.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.2.1 The SI-based units for calibration constants and kinematic viscosities are mm2/s2 and mm 2/s, respectively.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Many petroleum products, and some non-petroleum materials, are used as lubricants, and the correct operation of the equipment depends upon the appropriate viscosity of the liquid being used. In addition, the viscosity of many petroleum fuels is important for the estimation of optimum storage, handling, and operational conditions. Thus, the accurate determination of viscosity is essential to many product specifications.1.1 This test method specifies a procedure for the determination of the kinematic viscosity, ν, of liquid petroleum products, both transparent and opaque, by measuring the time for a volume of liquid to flow under gravity through a calibrated glass capillary viscometer. The dynamic viscosity, η, can be obtained by multiplying the kinematic viscosity, ν, by the density, ρ, of the liquid.NOTE 1: For the measurement of the kinematic viscosity and viscosity of bitumens, see also Test Methods D2170 and D2171.NOTE 2: ISO 3104 corresponds to Test Method D445 – 03.1.2 The result obtained from this test method is dependent upon the behavior of the sample and is intended for application to liquids for which primarily the shear stress and shear rates are proportional (Newtonian flow behavior). If, however, the viscosity varies significantly with the rate of shear, different results may be obtained from viscometers of different capillary diameters. The procedure and precision values for residual fuel oils, which under some conditions exhibit non-Newtonian behavior, have been included.1.3 The range of kinematic viscosities covered by this test method is from 0.2 mm2/s to 300 000 mm2/s (see Table A1.1) at all temperatures (see 6.3 and 6.4). The precision has only been determined for those materials, kinematic viscosity ranges and temperatures as shown in the footnotes to the precision section.1.4 The values stated in SI units are to be regarded as standard. The SI unit used in this test method for kinematic viscosity is mm2/s, and the SI unit used in this test method for dynamic viscosity is mPa·s. For user reference, 1 mm2/s = 10-6 m2/s = 1 cSt and 1 mPa·s = 1 cP = 0.001 Pa·s.1.5 WARNING—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use Caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Aircraft turbine lubricants, upon standing at low temperatures for prolonged periods of time, may show an increase in kinematic viscosity. This increase may cause lubrication problems in aircraft engines. Thus, this test method is used to ensure that the kinematic viscosity does not exceed the maximum kinematic viscosity in certain specifications for aircraft turbine lubricants.1.1 This test method covers the determination of the kinematic viscosity of aircraft turbine lubricants at low temperature, and the percent change of viscosity after a 3 h and a 72 h standing period at low temperature.1.1.1 The range of kinematic viscosities covered by this test method is from 7700 mm2/s to 14 000 mm2/s at –40 °C and from 7000 mm2/s to 17 500 mm2/s at –51 °C. The precision has only been determined for those materials, kinematic viscosity ranges, and temperatures as shown in the precision section. Kinematic viscosities and percent change of viscosity may be measured and reported at other temperatures and other thermal soak period intervals as agreed by the contracting parties.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.2.1 The SI unit used in this test method for Kinematic Viscosity is mm2/s. For user reference, 1 mm2/s = 10-6 m2/s = 1 cSt.1.3 Warning—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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This test method deals with the standards for the measurement of apparent viscosity of roofing bitumen by mean of a parallel plate plastometer. This method involves measuring viscosity using pre-determined arbitrary shear stress levels. The method involves molding the sample into a disc of specified dimensions, heating it to a selected temperature and placing it between the plates of a pre-heated apparatus and pressing under the standard conditions for a measured time.1.1 This test method covers the measurement of apparent viscosity of roofing bitumen by means of a parallel plate plastometer. This test method is applicable for a viscosity range from 102 to 109 Pa·s [103 to 1010 poises]. See Note 1.NOTE 1: This relatively simple test method of measuring viscosity uses predetermined, arbitrary shear stress levels. Since roofing bitumens are non-Newtonian, other viscosity test methods may give different results.1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The kinematic viscosity characterizes flow behavior. The method is used to determine the consistency of liquid asphalt as one element in establishing the uniformity of shipments or sources of supply. The specifications are usually at temperatures of 60 and 135 °C.NOTE 3: The quality of the results produced by this standard are dependent on the competence of the personnel performing the procedure and the capability, calibration, and maintenance of the equipment used. Agencies that meet the criteria of Specification D3666 are generally considered capable of competent and objective testing, sampling, inspection, etc. Users of this standard are cautioned that compliance with Specification D3666 alone does not completely ensure reliable results. Reliable results depend on many factors; following the suggestions of Specification D3666 or some similar acceptable guideline provides a means of evaluating and controlling some of those factors.1.1 This test method covers procedures for the determination of kinematic viscosity of liquid asphalts, road oils, and distillation residues of liquid asphalts all at 60 °C [140 °F] and of liquid asphalt binders at 135 °C [275 °F] (see table notes, 11.1) in the range from 6 to 100 000 mm2/s [cSt].1.2 Results of this test method can be used to calculate viscosity when the density of the test material at the test temperature is known or can be determined. See Annex A1 for the method of calculation.NOTE 1: This test method is suitable for use at other temperatures and at lower kinematic viscosities, but the precision is based on determinations on liquid asphalts and road oils at 60 °C [140 °F] and on asphalt binders at 135 °C [275 °F] only in the viscosity range from 30 to 6000 mm2/s [cSt].NOTE 2: Modified asphalt binders or asphalt binders that have been conditioned or recovered are typically non-Newtonian under the conditions of this test. The viscosity determined from this method is under the assumption that asphalt binders behave as Newtonian fluids under the conditions of this test. When the flow is non-Newtonian in a capillary tube, the shear rate determined by this method may be invalid. The presence of non-Newtonian behavior for the test conditions can be verified by measuring the viscosity with viscometers having different-sized capillary tubes. The defined precision limits in 11.1 may not be applicable to non-Newtonian asphalt binders.1.3 Warning—Mercury has been designated by the United States Environmental Protection Agency (EPA) and many state agencies as a hazardous material that can cause central nervous system, kidney, and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury-containing products. See the applicable product Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) for details and the EPA’s website—http://www.epa.gov/mercury/faq.htm—for additional information. Users should be aware that selling mercury, mercury-containing products, or both, in your state may be prohibited by state law.1.4 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the standard.1.5 The text of this standard references notes and footnotes that provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 The principle of measurement is based upon a reversible isothermal change in apparent viscosity with change in rate of shear produced by a change in rotational speed.4.2 Measurement is performed with a rotational viscometer under standardized conditions with rigid control of the time intervals of measurement. Viscosity readings are obtained at the end of 1 min for each rotational speed. Changes from the lowest speed to the highest speed, and return to the lowest speed, are made without stopping the instrument.1.1 This test method covers the measurement of the apparent viscosity of shear-rate-dependent adhesives using a rotational viscometer.1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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