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5.1 This test method establishes a standard procedure for rapidly (in 1 h or less) determining the chemical resistance of specimens of protective clothing materials. This test method can be used to rank materials as to their suitability for use with liquids of known or unknown composition.5.2 The breakthrough detection time, permeation rate, or cumulative permeation can be used to identify protective clothing materials that are more likely to limit potential exposures to chemicals. Longer breakthrough detection times and lower cumulative amounts permeated and permeation rates are characteristics of materials that are better barriers to the test chemical.5.3 In general this test method is less sensitive than Test Method F739 coupled with sensitive analytical procedures. In cases where the chemical of concern is highly toxic and contact of even a very small amount with the skin may be detrimental to health, the permeation cup method is not recommended. Use Test Method F739.5.4 Upon permeating the clothing material, the chemical must evaporate in order for a weight loss to occur and permeation to be detected. Consequently, the test method may not be applicable for chemicals having low volatility (that is, vapor pressure). The vapor pressure below which this test method is not applicable has not been determined.5.4.1 A procedure for assessing volatility is described in Section 10.5.5 The results of this test method are highly dependent on the test temperature. If the objective is to compare different clothing materials, all tests shall be conducted at the same temperature (±3 °C).1.1 This test method measures the barrier effectiveness of a specimen of protective clothing upon continuous contact with a liquid.1.1.1 Procedure A—For use when a value for the cumulative amount of chemical permeated in 1 h is desired.1.1.2 Procedure B—For use when breakthrough detection time and permeation rate values are desired.1.2 Although not addressed herein, the effect of the test chemical on the clothing material can be determined by comparing the weight or other physical properties of the specimen before and after the permeation test.1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 7.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Flash point and fire point of a liquid are physical properties that may be used to define their flammability hazards. The flash point may be used to classify materials in government regulations.1.1 This test method covers the determination by Tag Open-Cup Apparatus of the flash point and fire point of liquids having flash points between −18 and 165°C (0 and 325°F) and fire points up to 325°F.1.2 This test method, when applied to paints and resin solutions that tend to skin over or that are very viscous, gives less reproducible results than when applied to solvents.NOTE 1: In order to conserve time and sample, the fire point of a material may be determined by the Tag Open-Cup Method by continuing the heating of the specimen to its fire point. Fire points may also be determined by Test Method D92, which should be used for fire points beyond the scope of this test method.1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.1.4 This standard should be used to measure and describe the properties of materials, products, or assemblies in response to heat and flame under controlled laboratory conditions and should not be used to describe or appraise the fire hazard or fire risk of materials, products, or assemblies under actual fire conditions. However, results of this test may be used as elements of a fire risk assessment which takes into account all of the factors pertinent to an assessment of the fire hazard of a particular end use.1.5 Warning—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Safety Data Sheet (SDS) for details and EPA’s website, http://www.epa.gov/mercury/faq.htm, for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This procedure is intended to be used to evaluate the ignitability of liquid wastes.5.2 Flash point measures the response of the subsample to heat and an ignition source under controlled laboratory conditions. It is only one of a number of properties that shall be considered in assessing the overall flammability hazard of a liquid waste material.5.3 Flash point can indicate the possible presence of highly volatile and flammable materials in a relatively nonvolatile or nonflammable material.5.4 This test method uses a small sample volume (2 mL) and short test time (1 min).1.1 This test method covers the procedure for a flash point test, within the range of –20 to 70 °C, of liquid wastes using a small-scale closed cup tester.NOTE 1: Some apparatus are not designed for subambient temperature tests, so the testing range would be between 20 °C and 70 °C.NOTE 2: This test method is not applicable for liquid waste that forms a surface film (see Test Method D8175 for Finite Flash Point Determination of Wastes by Pensky-Martens Closed Cup Tester).1.2 Units—The values stated in SI units are to be regarded as the standard. No other units of measurement are included in this standard.1.3 This standard measures the ignitability properties of liquid wastes (which may be any discarded material), which may include secondary materials, off-specification products, and materials containing free liquids recovered during emergency response actions. Results from this test method may be used as part of a fire risk assessment of the material, but it is the responsibility of the user to perform any additional characterization needed for determination of storage, transport, treatment, or disposal per current regulations.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Warning statements appear throughout. See applicable Safety Data Sheets (SDS) for information about certified reference materials (CRMs) or secondary working standards (SWSs) that may be used in this test method. SDS may also be useful if some components of the waste sample are known.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 This procedure is intended to be used to evaluate the ignitability of liquid wastes.5.2 Flash point measures the response of the subsample to applied heat and an ignition source under controlled laboratory conditions. It is only one of a number of properties that must be considered in assessing the overall flammability hazard of a liquid waste material.5.3 Flash point can indicate the possible presence of highly volatile and flammable materials in a relatively nonvolatile or nonflammable material.1.1 This test method covers the procedure for a finite flash point test, within the range of 20 to 70 °C, of liquid wastes using a manual or automated Pensky-Martens closed cup tester.1.2 This test method contains two procedures and is applicable to liquid waste, liquid phase(s) of multi-phase waste, liquid waste with suspended solids, or liquid waste that tends to form a surface film under test conditions.NOTE 1: If the liquid waste is of a viscosity such that the subsample volume will not be uniformly heated under the test conditions even with the increased stir rate of Procedure B, then use the small-scale method (Test Method D8174 for Finite Flash Point Determination of Liquid Wastes by Small-Scale Closed Cup Tester).1.3 Procedure A is applicable to non-viscous liquids that are without suspended solids. Procedure B is applicable to viscous liquids, liquids with suspended solids, or liquids that form films.NOTE 2: This test method is not applicable for corrosive liquid wastes (see Test Method D8174).1.4 Units—The values given in SI units are to be regarded as the standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Warning statements appear throughout. Also see applicable Safety Data Sheets (SDS) for information about certified reference materials (CRMs) or secondary working standards (SWSs) that may be used in the analysis. SDS may also be useful if some components of the waste sample are known.1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 Flash point measures the response of the test specimen to heat and ignition source under controlled laboratory conditions. It is only one of a number of properties that must be considered in assessing the overall flammability hazard of a material.5.2 Flash point is used in shipping and safety regulations by governmental regulatory agencies to define flammable and combustible materials and to classify them. Consult the particular regulation involved for precise definitions of these classes.5.3 Flash point can indicate the possible presence of highly volatile and flammable impurities or contaminants in a given liquid, such as the presence of residual solvents in solvent-refined drying oils.5.4 These equilibrium flash point test methods use a smaller specimen (2 mL) and a shorter test time (1 min) than traditional non-equilibrium test methods such as Test Method D56 and Test Methods D93.5.5 Test Methods D3828, Test Method D8174, and ISO 3679 are similar test methods and use the same apparatus.1.1 These test methods cover procedures for determining whether a material does or does not flash at a specified temperature (flash/no flash Method A) or for determining the lowest finite temperature at which a material does flash (Method B), when using a small scale closed-cup apparatus. The test methods are applicable to paints, enamels, lacquers, varnishes, solvents, and related products having a flash point between 0 °C and 110 °C (32 °F and 230 °F) and viscosity lower than 15 000 mm2/s (cSt) at 25 °C (77 °F).NOTE 1: Tests at higher or lower temperatures are possible however the precision has not been determined.NOTE 2: More viscous materials can be tested in accordance with Annex A4.NOTE 3: Organic peroxides can be tested in accordance with Annex A5, which describes the applicable safety precautions.NOTE 4: The U.S. Department of Labor (OSHA, Hazard Communications), the U.S. Department of Transportation (RSPA), and the U.S. Environmental Protection Agency (EPA) have specified Test Methods D3278 as one of several acceptable methods for the determination of flash point of liquids in their regulations.1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.3 This standard is used to measure and describe the response of materials, products, or assemblies to heat and flame under controlled conditions, but does not by itself incorporate all factors required for fire hazard or fire risk assessment of the materials, products, or assemblies under actual fire conditions.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The flash point temperature is one measure of the tendency of the test specimen to form a flammable mixture with air under controlled laboratory conditions. It is only one of a number of properties which must be considered in assessing the overall flammability hazard of a material.5.2 Flash point is used in shipping and safety regulations to define flammable and combustible materials and for classification purposes. This definition may vary from regulation to regulation. Consult the particular regulation involved for precise definitions of these classifications.5.3 This test method can be used to measure and describe the properties of materials in response to heat and an ignition source under controlled laboratory conditions and shall not be used to describe or appraise the fire hazard or fire risk of materials under actual fire conditions. However, results of this test method may be used as elements of a fire risk assessment, which takes into account all of the factors which are pertinent to an assessment of the fire hazard of a particular end use.5.4 Flash point can also indicate the possible presence of highly volatile and flammable materials in a relatively nonvolatile or nonflammable material, such as the contamination of lubricating oils by small amounts of diesel fuel or gasoline. This test method was designed to be more sensitive to potential contamination than Test Method D6450.1.1 This test method covers the determination of the flash point of fuels including diesel/biodiesel blends, lube oils, solvents, and other liquids by a continuously closed cup tester utilizing a specimen size of 2 mL, cup size of 7 mL, with a heating rate of 2.5 °C per minute.1.1.1 Apparatus requiring a specimen size of 1 mL, cup size of 4 mL, and a heating rate of 5.5 °C per minute must be run according to Test Method D6450.1.2 This flash point test method is a dynamic method and depends on definite rates of temperature increase. It is one of the many flash point test methods available and every flash point test method, including this one, is an empirical method.NOTE 1: Flash point values are not a constant physical chemical property of materials tested. They are a function of the apparatus design, the condition of the apparatus used, and the operational procedure carried out. Flash point can, therefore, only be defined in terms of a standard test method and no general valid correlation can be guaranteed between results obtained by different test methods or where different test apparatus is specified.1.3 This test method utilizes a closed but unsealed cup with air injected into the test chamber.1.4 The precision of this test method is applicable for testing samples with a flash point from 22.5 °C to 235.5 °C. Determinations below and above this range may be performed; however, the precision has not been established.1.5 If the user’s specification requires a defined flash point method other than this method, neither this method nor any other test method should be substituted for the prescribed test method without obtaining comparative data and an agreement from the specifier.1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. Temperatures are in degrees Celsius, pressure in kilo-Pascals.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 7.2 and 8.5.1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The flash point measures the response of the sample to heat and flame under controlled laboratory conditions. It is only one of a number of properties that must be considered in assessing the overall flammability hazard of a material.5.2 As a result of physical factors inherent in the apparatus and procedure, the closed cup flash point does not necessarily represent the minimum temperature at which a material can evolve flammable vapors, and the absence of a flash point does not guarantee nonflammability (see Appendix X1 and Appendix X2).5.3 Flash point is used in shipping and safety regulations to define flammable and combustible materials. Test Methods D56, D93, and D3278 are specified as test methods for determining the flash point of these materials.5.4 If the process or handling conditions dictate the usage of a flammable material at temperatures ranging upward from 5 to 10°C below the closed-cup flash point, then a flammable vapor might be present above the liquid. In such cases, it may be more appropriate to use the temperature limit of flammability (as determined by Test Method E1232) instead of flash point.5.5 For single component samples, small-scale methods involving equilibrium procedures and only one flame pass per specimen are preferred.5.6 For mixtures containing small concentrations of volatile components, special procedures are needed to minimize the loss of volatiles, with consequent elevation of the flash point, while the sample is being heated. (See X2.5.)5.7 In cases where errors caused by loss of volatiles, downwards flame direction and quenching are unacceptable, the “lower temperature limit of flammability” can be determined instead using Test Method E1232. The temperature limit of flammability test chamber is sufficiently large to overcome flame quenching effects in most cases of practical importance, thus, usually indicating the presence of vapor-phase flammability if it does exist.1.1 This test method covers the determination of the flash point of liquid and solid chemical compounds flashing from below −10 to 370°C (16 to 700°F). The procedures and apparatus in Test Methods D56, D93, D3278, D3828, and D3941 are to be used. Modification to these procedures are specified for tests on solids and viscous liquids. The significance of the results obtained is discussed along with possible sources of error and factors that might cause interference.1.2 Suggestions for adapting this procedure to mixtures of chemicals are included (see Appendix X2).1.3 This test method should be used to measure and describe the properties of materials, products, or assemblies in response to heat and flame under controlled laboratory conditions and should not be used to describe or appraise the fire hazard or fire risk of materials or assemblies under actual fire conditions. However, results of this test method may be used as elements of a fire risk assessment that take into account all of the factors that are pertinent to an assessment of the fire hazard of a particular end use.1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.1.5 Warning—Mercury has been designated by the United States Environmental Protection Agency (EPA) and many state agencies as a hazardous material that can cause central nervous system, kidney, and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA’s website — http://www.epa.gov/mercury/faq.htm — for additional information. Users should be aware that selling mercury or mercury-containing products, or both, into your state may be prohibited by state law.1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. See also Section 8.1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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5.1 The jet cup attrition test will provide an estimate of the relative attrition resistance of fluid catalytic cracking (FCC) catalyst, catalyst additives, and catalytic materials.5.2 The test is designed to simulate the attrition a catalyst or additive undergoes in a fluid catalytic cracking unit but at an accelerated rate.5.3 The data from this test can be used to rank catalyst according to attrition rate.5.4 The test requires a relatively small sample size of 5 g [0.175 oz] and a relatively short analysis time of 40 min. This test should be useful to quality control facilities that require fast turnaround time and research and development (R&D) facilities that have limited sample material.1.1 The jet cup attrition test is applicable to fluid catalytic cracking (FCC) catalysts, catalyst additives, and catalytic materials.1.2 Applications for other powdered catalysts have been reported in the literature. The round robin test samples included two FCC catalysts and one powdered alumina.1.3 Units—The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are not necessarily exact equivalents; therefore, to ensure conformance with the standard, each system shall be used independently of the other, and values from the two systems shall not be combined.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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